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New process for phosphorus removal with the combination of biological medium addition and calcium hydroxyphosphate crystallization |
WANG Dong-hao1,2, ZHENG Ping1, QIU Lin1, DENG Zheng-dong2 |
1. Department of Environmental Engineering, Zhejiang University, Hangzhou 310058, China;
2. College of Defense Engineering, The Army Engineering University of PLA. & Tech, Nanjing 210007, China |
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Abstract Anaerobic granular sludge was introduced to phosphorus removal system, creating a new process for phosphorus removal with the combination of biological medium addition and calcium hydroxyphosphate crystallization. The effects of pH, Ca/P ratio, HRT on the performance of new process were investigated to optimize process parameters. The results demonstrated that the optimal parameters were pH=12, Ca/P=3.34 (mole ratio), HRT=60min for synthetic wastewater with phosphorus concentration of 30mg/L. Under the optimal condition, phosphorus removal efficiency was 99.81% and the effluent phosphorus concentration was 0.057mg/L. The new process was operated for the phosphorus removal from piggery wastewater, which phosphorus removal efficiency was 85.85% and the effluent phosphorus concentration was 4.67mg/L.The phosphorus was enriched in the product, especially in the top and central part of reactor. The phosphorus of product mainly existed in the form of hydroxyapatite and its content by P2O5 was 37. 68% and 36.57% respectively, which has reached the standard of high quality phosphate rock and has a high value for phosphorus reuse.
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Received: 05 April 2017
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[1] |
Paterson M J, Schindler D W, Hecky R E, et al. Comment:Lake 227shows clearly that controlling inputs of nitrogen will not reduce or prevent eutrophication of lakes[J]. Limnol. Oceanogr, 2011,56(4):1545-1547.
|
[2] |
郝晓地.可持续污水-废物处理技术[M]. 北京:中国建筑工业出版社, 2006:27-32.
|
[3] |
张军晓,李绪录,肖志建.深圳湾及邻近水域总溶解磷的来源和时空分布[J]. 中国环境科学, 2015,35(3):871-878.
|
[4] |
王雪蕾,王新新,朱利,等.巢湖流域氮磷面源污染与水华空间分布遥感解析[J]. 中国环境科学, 2015,35(5):1511-1519.
|
[5] |
Chowdhury R B, Moore G A, Weatherley A J, et al. A review of recent substance flow analyses of phosphorus to identify priority management areas at different geographical scales[J]. Resources Conservation and Recycling, 2014,83:213-228.
|
[6] |
Clark T. Stephenson T. Development of a jar testing protocol for chemical phosphorus removal in activated sludge using statistical experimental design[J]. Water Research, 1999,33(7):1730-1734.
|
[7] |
Banu J R, Do K U, Yeom I T. Effect of ferrous sulphate on nitrification during simultaneous phosphorus removal from domestic wastewater using a laboratory scale anoxic/oxic reactor[J]. World J. Microbiol. Biotechnol., 2008,24:2981-2986.
|
[8] |
候红勋,王淑荣,王亚宜等.A2/O型氧化沟的旁侧化学除磷试验研究[J]. 中国给水排水, 2006,22(7):30-33.
|
[9] |
吴海林,杨开,土红宇,等.废水除磷技术的研究和发展[J]. 环境污染治理技术与设备, 2003,4(1):53-54.
|
[10] |
陈小光,张萌,厉帅,等.磷酸钙盐结晶除磷工艺性能研究[J]. 环境工程学报, 2013,7(7):2552-2556.
|
[11] |
Song Y H, Dietfried D, Ute B Seed selections for crystallization of calcium phosphorus recovery[J]. Journal of Environmental Science, 2007,19(5):591-595.
|
[12] |
Song Y H, Hahn H H, Erhard H E Effects of solution conditions on the precipitation of phosphate for recovery:A thermodynamics evaluation[J]. Chemosphere, 2002,48(10):1029-1034.
|
[13] |
Song Y H, Weidler P G, Berg U, et al. Calciteseeded crystallization of calcium phosphate for phosphorus recovery[J]. Chemosphere, 2006,63(2):236-243.
|
[14] |
Song Y H, Hahn H H, Erhard HE. Effect of humic substances on the precipitation of calcium phosphate[J]. Journal of Environmental Science, 2006,18(5):852-857.
|
[15] |
高英,叶荣,宋永会,等.溶液条件对磷酸钙沉淀法回收磷的影响[J]. 安全与环境学报, 2007,7(3):58-62.
|
[16] |
Desmidt E, Ghyselbrecht K, Zhang Y, et al. Global phosphorus scarcity and full-scale P-recovery techniques:a review. Critical Reviews in Environmental Science and Technology, 2015,45(4):336-384.
|
[17] |
Bellier N, Chazarenc F, Comeau Y. Phosphorus removal from wastewater by mineral apatite[J]. Water Research, 2006,40(15):2965-2971.
|
[18] |
Song Y H, Weidler P G, Berg U, et al. Calcite-seeded crystallization of calcium phosphate for phosphorus recovery[J]. Chemosphere, 2006,63(2):236-243.
|
[19] |
Kim E H., Yim S B., Jung H C., et al. Hydroxyapatite crystallization from a highly concentrated phosphate solution using powdered converter slag as a seed material[J]. Journal of Hazardous Matarial, 2006,136(3):690-697.
|
[20] |
胡怡,宋永会,钱锋,等.赤泥诱导磷酸钙结晶法回收废水中的磷[J]. 环境工程技术学报, 2014,4(1):60-66.
|
[21] |
张林生,叶峰,吴海锁,等.多孔陶粒结晶床除磷试验研究[J]. 东南大学学报,自然科学版, 2003,33(5):664-667.
|
[22] |
张蓓蓓.以合成雪硅钙石为晶种回收含磷废水中的磷[D]. 北京:中国地质大学, 2007.
|
[23] |
张红梅.以合成雪硅钙石为晶种回收含磷废水中的磷[D]. 北京:中国地质大学, 2007.
|
[24] |
GB 11893-1989钼酸铵分光光度法[S]. 北京:中国标准出版社, 2003.
|
[25] |
魏复盛.水和废水监测分析方法[M]. 北京:中国环境科学出版社, 2002:243-248.
|
[26] |
GB 6920-86玻璃电极法[S]. 北京:中国标准出版社, 2004.
|
[27] |
GB8978-1996污水综合排放标准[S]. 北京:中国标准出版社, 2004.
|
[28] |
Ohlinger K N, Young T M, Schroeder E D. Predicting struvite formation in digestion[J]. Wat. Res., 1998,32(12):3607-3614.
|
[29] |
葛杰,钱锋,宋永会,等.白云石石灰流化结晶污水除磷工艺[J]. 环境科学学报, 2014,34(6):1480-1488.
|
[30] |
王铸,杜兵,刘寅.轻基磷酸钙结晶除磷研究进展[J]. 环境工程, 2015,11(4):16-20.
|
[31] |
赵亚丽,宋永会,等.不同Ca/P比下碳酸根对磷酸钙沉淀反应回收磷的影响[J]. 环境工程学报, 2014,8(5):1756-1760.
|
[32] |
杨树成,贺延龄,张鹏翔,等.不同底物条件下UASB反应器中碳酸钙的沉淀[J]. 环境科学, 2009,30(3):822-826.
|
[33] |
杨万万.碳酸钙沉淀诱导期影响因素的研究[J]. 四川化工, 2008,11(4):5-7.
|
[34] |
薛华,李隆弟,郁鉴源,等.分析化学[M]. 北京:清华大学出版社, 1994.
|
[35] |
宋永会,钱锋,向连城.磷酸钙沉淀法去除猪场废水中磷的实验研究[J]. 环境科学, 2011,32(6):1679-1686.
|
[36] |
GB 18596-2001畜禽养殖业污染物排放标准[S]. 北京:中国标准出版社, 2004.
|
[37] |
GB/T 1868-1995磷矿石和磷精矿采样与样品制备方法[S]. 北京:中国标准出版社, 2004
|
|
|
|