|
|
Cadmium and arsenic removal from sludge by DOM produced from ultrasonic lysis of sludge |
WANG Xiang1,2, LI Xiao-ming1, YANG Qi1, CHEN Can2, ZHONG Zhen-yu2, ZHONG Yu2, CHEN Xun-feng1, CHEN Fei1, ZHAO Qing-yuan1 |
1. College of Environmental Science and Engineering, Hunan University, Changsha 410082, China;
2. Huan Research Academy of Environment Science, Changsha 410004, China |
|
|
Abstract The dissolved organic matter (DOM) released from ultrasonic lysis of sludge was used to remove the heavy metals in the waste activated sludge. The effects of DOM on the removal efficiency of cadmium (Cd) and arsenic (As) were investigated under different DOM concentrations, pH, shaking and washing time. The physicochemical properties of sludge before and after DOM leaching were also taken into comparisons. Moreover, changes of Cd and As speciation of sludge were analyzed by using continuous extraction of Tessier. Under optimal conditions:DOM concentration 1200mg/L, pH 6, leaching time 24h and the ratio of liquid to solid 40:1, the removal efficiencies of Cd and As were 36.12% and 23.75% (single washing) and improved to 62.35% and 39.45%(triple washing), respectively. The contents of organic matter and total nitrogen in the sludge increased, but the contents of total phosphorus, total potassium and pH decreased after triple leaching. The fractions of cadmium and arsenic distribution in sludge was changed before and after triple washing. Moreover, the available contents of Cd and As in sludge was significantly reduced.
|
Received: 27 April 2017
|
|
|
|
|
[1] |
中华人名共和国环境保护部.2015年中国环境状况公报[R]. 2016.
|
[2] |
杨士林.城市污水处理厂污泥处置技术及利用[J]. 山东工业技术, 2016,(12):28-28.
|
[3] |
杨柯敏,张春燕,张燕,等.城市污泥处理处置方式及现状分析[J]. 中国资源综合利用, 2012,(12):28-31.
|
[4] |
师雄.城市污泥处置方法概述[J]. 河北理工学院学报, 2008,30(1):128-132.
|
[5] |
Camargo F P, Tonello P S, Santos A C A D, et al. Removal of toxic metals from sewage sludge through chemical, physical, and biological treatments-a review[J]. Water Air & Soil Pollution, 2016,227(12):433.
|
[6] |
Ko I, Chang Y Y, Lee C H, et al. Assessment of pilot-scale acid washing of soil contaminated with As, Zn and Ni using the BCR three-step sequential extraction[J]. Journal of Hazardous Materials, 2005,127(1):1-13.
|
[7] |
陈玉成,郭颖,魏沙平.螯合剂与表面活性剂复合去除城市污泥中Cd、Cr[J]. 中国环境科学, 2003,23(1):100-104.
|
[8] |
涂剑成,赵庆良,杨倩倩.超声辐射协同草酸-HEDTA浸提污泥中重金属[J]. 中国环境科学, 2011,31(8):1280-1284.
|
[9] |
徐慧.溶解性有机质对土壤中污染物环境行为的影响[J]. 安徽农业科学, 2009,37(3):1315-1316.
|
[10] |
张龙,吴伟,李爱民,等.吸附法处理水体中溶解性有机物的研究进展[J]. 离子交换与吸附, 2009,25(1):91-96.
|
[11] |
Montoneri E, Boffa V, Savarino P, et al. Biosurfactants from urban green waste[J]. Chemsuschem, 2009,2(3):239-247.
|
[12] |
曾希柏,杨佳波,李莲芳,等.溶解性有机物对土壤中铜生物有效性的影响[J]. 农业环境科学学报, 2009,28(5):25-31.
|
[13] |
付美云,周立祥.垃圾渗滤液水溶性有机物对土壤Pb溶出的影响[J]. 环境科学, 2007,28(2):243-248.
|
[14] |
王艮梅,周立祥,黄焕忠.水溶性有机物在土壤中的吸附及对Cu沉淀的抑制作用[J]. 环境科学, 2006,27(4):754-759.
|
[15] |
Wong J W C, Li K L, Zhou L X, et al. The sorption of Cd and Zn by different soils in the presence of dissolved organic matter from sludge[J]. Geoderma, 2007,137(3):310-317.
|
[16] |
Antoniadis V, Alloway B J. The role of dissolved organic carbon in the mobility of Cd, Ni and Zn in sewage sludge-amended soils[J]. Environmental Pollution, 2002,117(3):515-521.
|
[17] |
Borggaard O K, Hansen H C B, Holmpe, et al. Experimental assessment of using soluble humic substances for remediation of heavy metal polluted soils[J]. Soil & Sediment Contamination An International Journal, 2009,18(3):369-382.
|
[18] |
Liu C C, Chen G B. Reclamation of cadmium-contaminated soil using dissolved organic matter solution originating from wine-processing waste sludge[J]. Journal of Hazardous Materials, 2013,244:645-653.
|
[19] |
Kulikowska D, Gusiatin Z M, Kierklo K. Humic substances from sewage sludge compost as washing agent effectively remove Cu and Cd from soil[J]. Chemosphere, 2015,136:42-49.
|
[20] |
Chen Y M, Lin W H, Lin Y A, et al. Remediation of lead-contaminated soil using dissolved organic carbon solutions prepared by wine-processing waste sludge[J]. Geoderma, 2014, 235:233-239.
|
[21] |
Chiang P N, Tong O Y, Chiou C S, et al. Reclamation of zinc-contaminated soil using a dissolved organic carbon solution prepared using liquid fertilizer from food-waste composting[J]. Journal of Hazardous Materials, 2015,301:100-105.
|
[22] |
王峰,黄清辉,肖宜华.不同来源溶解有机质与Cd和锑的相互作用[J]. 中国环境科学, 2012,32(5):829-36.
|
[23] |
张志,朱维琴,单监利,等.畜粪蚯蚓处理后DOM变化及其与Cu(Ⅱ)的配合特性[J]. 中国环境科学, 2012,32(7):1319-1325.
|
[24] |
Gusiatin Z M, Klimiuk E. Metal (Cu, Cd and Zn) removal and stabilization during multiple soil washing by saponin[J]. Chemosphere, 2012,86(4):383-391.
|
[25] |
CJ/T 51-2004城市污水水质检验方法标准[S].
|
[26] |
GB/T 22105.2-2008土壤中总砷的测定[S].
|
[27] |
Tessier A, Campbell P G C, Bisson M. Sequential extraction procedure for the speciation of particulate trace metals[J]. Analytical Chemistry, 1979,51(7):844-851.
|
[28] |
RiffaldiI R, Leviminzi R, Saviozzi A, et al. Sorption and release of cadmium by some sewage sludges[J]. Journal of Environmental Quality, 1983,12(2):253-256.
|
[29] |
涂剑成.污水厂污泥中重金属脱除技术及污泥特性变化的研究[D]. 哈尔滨:哈尔滨工业大学, 2011.
|
[30] |
Claret F, Schafer T, Bauer A, et al. Generation of humic and fulvic acid from Callovo-Oxfordian clay under high alkaline conditions[J]. Science of the Total Environment, 2003,317(1):189-200.
|
[31] |
Wang X H, Song R H, Teng S X, et al. Characteristics and mechanisms of Cu(Ⅱ) biosorption by disintegrated aerobic granules[J]. Journal of Hazardous Materials, 2010,179(1):431-437.
|
[32] |
Baker A. Fluorescence properties of some farm wastes:implications for water quality monitoring[J]. Water Research, 2002,36(1):189-195.
|
[33] |
Wu F, Tanoue E. Molecular mass distribution and fluorescence characteristics of dissolved organic ligands for copper(Ⅱ) in Lake Biwa, Japan[J]. Organic Geochemistry, 2001,32(1):11-20.
|
[34] |
Mayer L M, Schick L L, Loder T C. Dissolved protein fluorescence in two Maine estuaries[J]. Marine Chemistry, 1999,64(3):171-179.
|
[35] |
查甫更,张建树,姚多喜,等.超声对垃圾渗滤液中溶解性有机物的影响[J]. 环境科学与技术, 2016,(11):138-143.
|
[36] |
Tsang D C W, Yip T C M, Lo I M C. Kinetic interactions of EDDS with soils. 2. Metal-EDDS complexes in uncontaminated and metal contaminated soils[J]. Environmental Science & Technology, 2009,43(3):837-842.
|
[37] |
Ko I, Kim J Y, Kim K W. Arsenic speciation and sorption kinetics in the As-hematite-humic acid system[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2004,234(1):43-50.
|
[38] |
Jonge L W D, Kjaergaard C, Moldrup P. Colloids and colloid-facilitated transport of contaminants in soils[J]. Vadose Zone Journal, 2004,3(2):321-325.
|
[39] |
Ko I, Davis A P, Kim J Y, et al. Effect of contact order on the adsorption of inorganic arsenic species onto hematite in the presence of humic acid[J]. Journal of Hazardous Materials, 2007,141(1):53-60.
|
[40] |
朱清清,邵超英,侯书雅,等.烷基糖苷对土壤中重金属的去除研究[J]. 环境科学与技术, 2011,34(8):120-123.
|
[41] |
Yang J S, Juyoung L, Kitae B, et al. Extraction behavior of As, Pb, and Zn from mine tailings with acid and base solutions[J]. Journal of Hazardous Materials, 2009,171(1):443-451
|
[42] |
GB4284-84农用污泥中污染物控制标准[S].
|
[43] |
NY525-2002有机肥料标准[S].
|
[1] |
SU Pin-jie, WANG Jing, CHU Kuo, LUO Yi-fu, SUN Qi-qi, DONG Xin, ZHANG Hong-cui, CUI Bo, YAN Zhuo-jun, BU Nai-shun. Preparation of conjugated porous organic polymers and its capture of iodine from nuclear waste[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(2): 568-575. |
|
|
|
|