基于OMI数据的京津冀及周边地区O<sub>3</sub>生成敏感性

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Abstract

The chemical sensitivity of O₃ production was assessed using HCHO and NO₂ vertical column densities (VCDs) in BTH and its surrounding areas during the period of June to September from 2005~2016, since HCHO/NO₂ serves as a proxy for the sensitivity. The results showed that VOCs-limited was mainly concentrated in the central areas in the industrial cities, e.g. Beijing, Taiyuan, Shijiazhuang, etc. NO_x -limited regime concentrated in north of Beijing, Hebei Province, most areas of Henan Province, and the coastal cities in Shandong Province. The proportion of VOCs-limited conditions of O₃ production increased first and then reduced to 3% in BTH and its surrounding areas in 2016. At the same time, NO_x -limited regime showed a trend of increase after the first reduce, and the areas accounted for 65% in 2016. The main reason was that the NO_x emission control during "12^th five-year plan" was remarkably effective. The results showed VOCs-limited regimes increased significantly in September, with transitions in regimes of NO_x -limited into mixed NO_x -VOCs-limited, and mixed NO_x -VOCs-limited regimes into VOCs-limited regimes compared with June-August.

Key words： OMI O₃ sensitivity HCHO NO₂

Received: 01 September 2017

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	WU Wei-ling
	XUE Wen-bo
	LEI Yu
	WANG Jin-nan

Cite this article:

WU Wei-ling,XUE Wen-bo,LEI Yu等. Sensitivity analysis of ozone in Beijing-Tianjin-Hebei (BTH) and its surrounding area using OMI satellite remote sensing data[J]. CHINA ENVIRONMENTAL SCIENCECE, 2018, 38(4): 1201-1208.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2018/V38/I4/1201

[1]	2016年中国环境状况公报, http://www.zhb.gov.cn/gkml/hbb/qt/201706/t20170605_415442.htm.
[2]	唐孝炎.奥运运动员的"天敌"——臭氧和细颗粒物[J]. 环境, 2008,(7):26-27.
[3]	王占山,李云婷,陈添,等.北京城区臭氧日变化特征及与前体物的相关性分析[J]. 中国环境科学, 2014,34(12):3001-3008.
[4]	梁永贤,尹魁浩,胡泳涛,等.深圳地区臭氧污染来源的敏感性分析[J]. 中国环境科学, 2014,34(6):1390-1396.
[5]	聂滕,李璇,王雪松,等.北京市夏季臭氧前体物控制区的分布特征[J]. 北京大学学报(自然科学版), 2014,50(3):557-564.
[6]	王雪松,李金龙,张远航,等.北京地区臭氧污染的来源分析[J]. 中国科学(B辑:化学), 2009,39(6):548-559.
[7]	Sillman S. The use of NOy, H2O2, and HNO3 as indicators for ozone-NOx-hydrocarbon sensitivity in urban locations[J]. Journal of Geophysical Research:Atmospheres, 1995,100:14175-14188.
[8]	Sillman S, He D. Some theoretical results concerning O3-NOx-VOC chemistry and NOx-VOC indicators[J]. Journal of Geophysical Research, 2002, 107(D22), 4659, doi:10.1029/2001JD001123.
[9]	Tonnesen G S, Dennis R L. Analysis of radical propagation efficiency to assess ozone sensitivity to hydrocarbons and NOx:1. Local indicators of instantaneous odd oxygen production sensitivity[J]. Journal of Geophysical Research, 2000,105(D7):9213-9225.
[10]	Tonnesen G S, Dennis R L. Analysis of radical propagation efficiency to assess ozone sensitivity to hydrocarbons and NOx:2. Long-lived species as indicators of ozone concentration sensitivity[J]. Journal of Geophysical Research, 2000,105(105):9227-9241.
[11]	Duncan B N, Youshida Y, Olson J R, et al. Application of OMI observations to a space-based indicator of NOx and VOC controls on surface ozone formation[J]. Atmospheric Environment, 2010, 44(18):2213-2223.
[12]	Martin, R. V., A. M. Foire, A. Van Donkelaar, Space-based diagnosis of surface ozone sensitivity to anthropogenic emissions[J]. Geophysical. Research. Letters, 2004b, doi:10.1029/2004GL019416.
[13]	Witte J C, Duncan B N, Douglass A R, et al. The unique OMI HCHO/NO2 feature during the 2008 Beijing Olympics:Implications for ozone production sensitivity[J]. Atmospheric Environment, 2011,45(18):3103-3111.
[14]	单源源,李莉,刘琼,等.基于OMI数据的中国中东部臭氧及前体物的时空分布[J]. 环境科学研究, 2016,29(8):1128-1136.
[15]	李霄阳,李思杰,刘鹏飞,等.2016年中国城市臭氧浓度的时空变化规律[J/OL]. 环境科学学报, 1-17[2018-02-06]. https://doi.org/10.13671/j.hjkxxb.2017.0399.
[16]	Boersma K F, Eskes H J, Dirksen R. J, et al. An improved retrieval of tropospheric NO2 columns from the Ozone Monitoring Instrument, Atmospheric. Measurement. Techniques[J], 2011,4:1905-1928.
[17]	Celarier E A, Brinksma E J, Gleason J F, et al. Validation of Ozone Monitoring Instrument nitrogen dioxide columns[J]. Journal of Geophysical Research, 2008,113:D15S15.
[18]	Baek K H, Kim J H, Park R J, et al. Validation of OMI HCHO data and its analysis over Asia[J]. Science of the Total Environment, 2014,490:93-105.
[19]	Choi Y, Souri A H. Seasonal behavior and long-term trends of tropospheric ozone, its precursors and chemical conditions over Iran:a view from space[J]. Atmospheric Environment, 2015,106:232-240.
[20]	高晋徽,朱彬,王言哲,等.2005~2013年中国地区对流层二氧化氮分布及变化趋势[J]. 中国环境科学, 2015,35(8):2307-2318.
[21]	余环,王普才,宗雪梅,等.奥运期间北京地区卫星监测NO2柱浓度的变化[J]. 科学通报, 2009,54:299-304.
[22]	FU T M, Jacob D J, Palmer P I, et al. Space-based formaldehyde measurements as constraints on volatile organic compound emissions in East and South Asia[J]. Journal of Geophysical Research, 2007,112:6312-6347.
[23]	Palmer P I, Jacob D J, Flore R V, et al. Mapping isoprene emissions over North America using formaldehyde column observations from space[J]. Journal of Geophysical Research, 2003,108:4018-4065.
[24]	Abbot D S, Palmer P I, Martin R V, et al. Seasonal and interannual variability of North American isoprene emissions as determined by formaldehyde column measurements from space[J]. Geophysical Research Letters, 2003,30(17):339-346.
[25]	国务院,关于推进大气污染联防联控工作改善区域空气质量的指导意见[EB/OL]. http://zfs.mep.gov.cn/fg/gwyw/201005/t20100514_189497.htm, 2010-05-14.
[26]	国务院.大气污染防治行动计划[EB/OL]. http://www.gov.cn/zwgk/2013-09/12/content_2486773.htm, 2013-09-12.
[27]	毛红梅,张凯山,第宝锋.四川省天然源VOCs排放量的估算和时空分布[J]. 中国环境科学, 2016,36(5):1289-1296.