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Effects of high temperature thermal hydrolysis process on changes of phosphorus forms in high-solid sewage sludge |
ZHOU Si-qi, DAI Xiao-hu, DAI Ling-ling, PENG Xing-zi, LIU Zhi-gang |
State Key Laboratory of Pollution Control and Resource Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China |
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Abstract Orthogonal experiment, single factor experiment (i.e. temperature), and standards, measurements, and testing (SMT) were used to explore changes of phosphorus forms in high-solid sewage sludge after high temperature thermal hydrolysis process (HTTHP). The experimental results showed that more than 14.80% of organic phosphorus (OP) was transformed into inorganic phosphorus (IP) in high-solid sewage sludge by the HTTHP at 120℃~160℃, and the order of influencing factors on IP/total phosphorus (TP) was as follows:temperature of HTTHP > time of HTTHP > oxidant content > pH. With the increase of temperature, IP/TP in high-solid sewage sludge increased from 79.13% to 95.87%. Further study indicated that under 160℃ and 40min of HTTHP conditions, the IP and the IP/TP increased respectively from 18.30mg/g to 20.49mg/g and 80.83% to 96.97%. These findings, however, established foundation to realize the phosphorus recovery, and also provided an important reference for the optimization of high-solid anaerobic digestion of sewage sludge with HTTHP pretreatment.
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Received: 11 September 2017
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