基于硫酸盐硫同位素的伊洛河流域河水溶解性重金属来源

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Abstract

Sulfur isotopic values of riverine sulfate and dissolved heavy metal (DHM) contents were adopt to illustrate the effect of different human activities on the DHM contents in the Yiluo River (YLR). The results indicated that dissolved components in the upstream of YRB were heavily affected by the sulfide minerals exploration. In the upstream of Luo River, high average SO₄^2- content of (173±108)mg/L (n=8) and low average δ³⁴S_SO4 value of (3.1±2.1)‰ (n=8) were detected in the river water, and heavy metals as Co, Fe, Mn, Ni, Zn, Mo, Cd, Pb and U had high concentrations in this reach. While in the upstream of Yi River, high mean SO₄^2- content of (169±89) mg/L (n=6) and low mean δ³⁴S_SO4 value of (3.7±1.2) ‰ (n=6) were also detected, and heavy metals as Cr, Co, Fe, Ni, Zn, Mo, Cd, W, Hg, Pb and U had relatively high contents. Dissolved contents in the downstream of YRB were primarily affected by sewage and industrial wastewater. Average SO₄^2- content of (121±30) mg/L and δ³⁴S_SO4 value of (9.4±0.8) ‰ (n=4) were monitored in the downstream of Luo River along with the increasing concentrations of V, Cr, Ni, As, W and Hg. Correspondingly, in the downstream of Yi River, average SO₄^2- content of (122±22) mg/L and δ³⁴S_SO4 value of (10.5±2.4) ‰ (n=3) with the increasing concentrations of V, U, Ni, and As were found. Dissolved components in the source water of YLR were mainly derived from atmospheric deposition, and the river water was characterized with low level of DHMs and moderate δ³⁴S values ranging from 6.7‰ to 8.2‰. The contents of DHMs and δ³⁴S_SO4 values in YRB had the same spatial variations, so that the δ³⁴S_SO4 can well interpret the sources of dissolved heavy metals and sulfate in the river water.

Key words： Yiluo River catchment dissolved heavy metal dissolved sulfate sulfur isotope source apportionment

Received: 29 November 2018

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X522

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	ZHANG Dong
	YANG Jin-mei
	HUANG Xing-yu
	LIU Song-tao
	ZHANG Zhong-yi

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ZHANG Dong,YANG Jin-mei,HUANG Xing-yu等. Sources of dissolved heavy metals in river water of the Yiluo River basin based on sulfur isotope of sulfate[J]. CHINA ENVIRONMENTAL SCIENCECE, 2019, 39(6): 2549-2559.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2019/V39/I6/2549

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