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| Correlation analysis between concentrations of heavy metal species and organic carbon in dustfall with different particle size |
| HUO Ting-ting1, DONG Fa-qin1, LIU Meng-qing1, JIANG Lu-man1, LUO Zhao-pei1, LI Dong-kun1, DENG Yue-quan2, HE Xiao-chun2 |
1. School of Environment and Resource, Southwest University of Science and Technology, Mianyang 621010, China;
2. School of Materials Science and Engineering, Southwest University of Science and Technology, Mianyang 621010, China |
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Abstract In order to evaluate the correlations between concentrations of heavy metal species and organic carbon in dustfall, dust samples were collected in Yuncheng city, Shanxi province, and then they were separated into three particle sizes. In this study, the chemical species of As, Pb, Cd, Cr, total organic carbon (TOC) and water-soluble organic carbon (WSOC) were measured, and their correlations were analyzed. In addition, enrichment factors of heavy metals and their bioavailability were determined. Results showed that the total metal concentrations decreased in the following order:As > Cr > Pb > Cd, and the accumulation of all heavy metals increased with increasing particle size, while little difference was found in the chemical species of heavy metals among different particle sizes. The concentrations of WSOC and TOC in dust decreased with the decreases of particle size. The concentrations of TOC and WSOC in dust showed good correlations with some chemical species of Pb, Cd and Cr but a poor correlation with As. The enrichment factor (EF) of heavy metals decreased as follows:Cd > As > Pb > Cr, where Cr and As were relatively stable with little ecological risk, while Pb and Cd exhibited potential health risks. There were significant differences in the behavior of organic compounds and heavy metals, as well as the environmental risks of dust particles in different particle sizes from diverse sources.
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Received: 15 May 2019
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| [1] |
杨丽萍,陈发虎.兰州市大气降尘污染物来源研究[J]. 环境科学学报, 2002,22(4):499-502. Yang L P, Chen F H. Study on the source apportionment of atmospheric dust pollutants in Lanzhou[J]. Acta Scientiae Circumstantiae, 2002,22(4):499-502.
|
| [2] |
Chirenje T, Ma L Q, Lu L. Retention of Cd, Cu, Pb and Zn by wood ash, lime and fume dust[J]. Water, Air & Soil Pollution. 2006, 171(1-4):301-314.
|
| [3] |
Huber M, Welker A, Helmreich B. Critical review of heavy metal pollution of traffic area runoff:Occurrence, influencing factors, and partitioning[J]. Science of the Total Environment, 2016,541:895-919.
|
| [4] |
丁海霞,陶雪梅,李丹丹.兰州市大气降尘中有机物的污染特征[J]. 环境研究与监测, 2018,31(1):1-4. Ding H X, Tao X M, Li D D. Pollution characteristics of organism in dustfall of Lanzhou city[J]. Environmental Study and Monitoring, 2018,31(1):1-4.
|
| [5] |
Men C, Liu R M, Xu L B, et al. Source-specific ecological risk analysis and critical source identification of heavy metals in road dust in Beijing, China[J]. Journal of Hazardous Materials, 2019, Article 121763. in press.
|
| [6] |
Cui X T, Wang X Q, Liu B. The characteristics of heavy metal pollution in surface dust in Tangshan, a heavily industrialized city in North China, and an assessment of associated health risks[J]. Journal of Geochemical Exploration, 2019,106432. in press.
|
| [7] |
Benoit G. Variability in the Properties of Dissolved Organic Matter and its Influence on Speciation of Heavy Metals (Cd, Cu, Pb)[R]. United States Environmental Protection Agency, 2018.
|
| [8] |
孙小燕,杨萍果,敖红,等.山西省2015年细颗粒物的污染状况和空间分布[J]. 地球环境学报, 2017,8(5):459-468. Sun X Y, Yang P G, Ao H, et al. Spatial distribution and pollution variation of fine particulate matter at urban area from Shanxi Province in 2015[J]. Journal of Earth Environment, 2017,8(5):459-468.
|
| [9] |
Miao Y, Liu S, Guo J, et al. Impacts of meteorological conditions on wintertime PM2.5 pollution in Taiyuan, North China[J]. Environmental Science and Pollution Research, 2018,25(22):21855-21866.
|
| [10] |
GB/T14506.28-2010硅酸盐岩石化学分析方法第28部分:16个主次成分量测定[S]. GB/T14506.28-2010 Method for chemical analysis of silicate rocks, Part 28:Measurement of 16 primary and secondary components[S]. China National Standard.
|
| [11] |
GB/T14506.14-2010硅酸盐岩石化学分析方法第14部分:氧化亚铁量测定[S]. GB/T14506.14-2010 Method for chemical analysis of silicate rocks, Part 14:Measurement of ferrous oxide[S]. China National Standard.
|
| [12] |
Wang M, Deng Y, Dong F, et al. Speciation analysis of cadmium in dust fall about northern China towns[J]. Asian Journal of Chemistry, 2013,25(13):7522.
|
| [13] |
史崇文,赵玲芝,郭新波,等.山西土壤元素背景值及其特征[J]. 华北地质矿产杂志, 1994,9(2):188-196. Shi C W, Zhao L Z, Guo X B, et al. Background values of soil elements in shanxi and their distribution feature[J]. Journal of Geology & Mineral Resources North China, 1994,9(2):188-196.
|
| [14] |
Liu Q T, Diamond M L, Gingrich S E, et al. Accumulation of metals, trace elements and semi-volatile organic compounds on exterior window surfaces in Baltimore[J]. Environmental Pollution, 2003, 122(1):51-61.
|
| [15] |
Takahashi Y, Miyoshi T, Yabuki S, et al. Observation of transformation of calcite to gypsum in mineral aerosols by Ca K-edge X-ray absorption near-edge structure (XANES)[J]. Atmospheric Environment, 2008,42(26):6535-6541.
|
| [16] |
刘春华,岑况.北京市街道灰尘粒度特征及其来源探析[J]. 环境科学学报, 2007,27(6):1006-1012. Chen C H, Cen K. Particle size characteristics and possible sources of street dust in Beijing[J]. Acta Scientiae Circum Stantiae, 2007,27(6):1006-1012.
|
| [17] |
Yang Y, Liu L, Xiong Y, et al. A comparative study on physicochemical characteristics of household dust from a metropolitan city and a remote village in China[J]. Atmospheric Pollution Research, 2016,7(6):1090-1100.
|
| [18] |
Nicholson K W. A review of particle resuspension[J]. Atmospheric Environment (1967), 1988,22(12):2639-2651.
|
| [19] |
Sehmel G A. Particle Resuspension:A Review[J]. Environment International, 1980,4(2):107-127.
|
| [20] |
Sánchez-Rodas D, Campa A M S D L, Alsioufi L. Analytical approaches for arsenic determination in air:A critical review[J]. Analytica Chimica Acta, 2015,898:1-18.
|
| [21] |
郝社锋,陈素兰,朱佰万.城市环境大气降尘重金属研究进展[J]. 地质学刊, 2012,36(4):418-422. Hao S F, Chen S L, Zhu B W. Review on progress of heavy metal elements in atmospheric deposition in urban environment[J]. Journal of Geology, 2012,36(4):418-422.
|
| [22] |
代革联.西安市大气沉积颗粒中铅的赋存状态及环境效应[J]. 桂林理工大学学报, 2004,24(3):377-380. Dai G L. Mode of occurrence and environmental effect of Pb in the atmosphere particulates of Xi'an[J]. Journal of Guilin Institute of Technology, 2004,24(3):377-380.
|
| [23] |
谢华林,张萍,贺惠,等.大气颗粒物中重金属元素在不同粒径上的形态分布[J]. 环境工程, 2002,20(6):55-57. Xie H L, Zhang P, He H, et al. Distribution of heavy metal elements in the different diametral atmospheric particulate matters[J]. Environmental Engineering, 2002,20(6):55-57.
|
| [24] |
Sakata K, Sakaguchi A, Tanimizu M, et al. Identification of sources of lead in the atmosphere by chemical speciation using X-ray absorption near-edge structure (XANES) spectroscopy[J]. Journal of Environmental Sciences, 2014,26(2):343-352.
|
| [25] |
Xing W Q, Zhao Q, Kirk G. Scheckelb, et al. Inhalation bioaccessibility of Cd, Cu, Pb and Zn and speciation of Pb in particulate matter fractions from areas with different pollution characteristics in Henan province, China[J]. Ecotoxicology and Environmental Safety, 2019,175:192-200.
|
| [26] |
高杨,范必威.大气降尘与土壤中重金属铬的形态分布规律[J]. 生态环境学报, 2008,17(4):1438-1441. Gao Y, Fan B W. The modality distribution of the chromium in the atmospheric dustfall and soil[J]. Ecology and Environment, 2008, 17(4):1438-1441.
|
| [27] |
方文稳,张丽,叶生霞,等.安庆市降尘重金属的污染评价与健康风险评价[J]. 中国环境科学, 2015,35(12):277-285. Fang W W, Zhang L, Ye S X, et al. Pollution evaluation and health risk assessment of heavy metals from atmospheric deposition in Anqing[J]. China Environmental Science, 2015,35(12):277-285.
|
| [28] |
李萍,薛粟尹,王胜利,等.兰州市大气降尘重金属污染评价及健康风险评价[J]. 环境科学, 2014,35(3):1021-1028. Li P, Xue S Y, Wang S L. Pollution evaluation and health risk assessment of heavy metals from atmospheric deposition in Lanzhou[J]. Environmental Science, 2014,35(3):1021-1028.
|
| [29] |
杨弘.太原市大气颗粒物中重金属的污染特征及来源解析[D]. 太原:山西大学, 2014. Yang H. Pollution characteristics and source analysis of heavy metals in particulate matters in Taiyuan[D]. Taiyuan:Shanxi University, 2014.
|
| [30] |
Al-Rajhi M A, Al-Shayeb S M, Seaward M R D, et al. Particle size effect for metal pollution analysis of atmospherically deposited dust[J]. Atmospheric Environment, 1996,30(1):145-153.
|
| [31] |
高连存,冯素萍,何桂华,等.不同粒径降尘中痕量金属元素Cu,Pb, Zn,Cr的形态分析[J]. 环境科学研究, 1995,8(4):35-39. Gao L C, Feng S P, He G H, et al. Specification of Cu, Pb, Zn, Cr in dust of different diameters[J]. Research of Environmental Sciences, 1995,8(4):35-39.
|
| [32] |
Parkpain P, Sirisukhodom S, Carbonell-Barrachina A. Heavy metals and nutrients chemistry in sewage sludge amended Thai soils[J]. Journal of Environmental Science & Health Part A. 1998,33(4):573-597.
|
| [33] |
Dao L, Morrison L, Kiely G, et al. Spatial distribution of potentially bioavailable metals in surface soils of a contaminated sports ground in Galway, Ireland[J]. Environmental Geochemistry and Health, 2013,35(2):227-238.
|
| [34] |
Lamsal R P, Beauchemin D. Estimation of the bio-accessible fraction of Cr, As, Cd and Pb in locally available bread using on-line continuous leaching method coupled to inductively coupled plasma mass spectrometry[J]. Analytica Chimica Acta, 2015,867:9-17.
|
| [35] |
周盼,秦伟,郭硕,等.石家庄冬季道路积尘PM2.5与PM10碳组分污染特征分析[J]. 环境化学, 2018,37(1):123-129. Zhou P, Qin W, Guo S, et al. Pollution characteristics of carbonaceous components in PM2.5 and PM10 of paved road dust in Shijiazhuang during winter[J]. Environmental Chemistry, 2018,37(1):123-129.
|
| [36] |
Chalbot M G, Brown J, Chitranshi P, et al. Functional chara-cterization of the water-soluble organic carbon of size-fractionated aerosol in the southern Mississippi Valley[J]. Atmospheric Chemistry and Physics, 2014,14(12):6075-6088.
|
| [37] |
Kumar P, Kumar S, Yadav S. Seasonal variations in size distribution, water-soluble ions, and carbon content of size-segregated aerosols over New Delhi[J]. Environmental Science & Pollution Research International, 2018,25(6):6061-6078.
|
| [38] |
Guo Z, Jiang W, Chen S, et al. Stable isotopic compositions of elemental carbon in PM1.1 in north suburb of Nanjing Region, China[J]. Atmospheric Research, 2016,168:105-111.
|
| [39] |
何公理,曹守仁.砷在大气可吸入颗粒物中的分布[J]. 环境与健康杂志, 1989,5:5-8. He G L, Cao S R. Distribution of arsenic in particulate matter in the atmosphere[J]. Journal of Environment and Health, 1989,5:5-8.
|
| [40] |
Bradl H B. Adsorption of heavy metal ions on soils and soils constituents[J]. Journal of Colloid & Interface Science, 2004,277(1):1-18.
|
| [41] |
Khaledian Y, Pereira P, Brevik E C, et al. The influence of organic carbon and pH on heavy metals, potassium, and magnesium levels in Lithuanian Podzols[J]. Land Degradation & Development, 2017,28(1):345-354.
|
| [42] |
王浩,章明奎.污染土壤中有机质和重金属互相作用的模拟研究[J]. 浙江大学学报(农业与生命科学版), 2009,35(4):460-466. Wang H, Zhang M K. Simulated study on interactions between heavy metals and organic matter in contaminated soil[J]. Journal of Zhejiang University, 2009,35(4):460-466.
|
| [43] |
任理想.土壤重金属形态与溶解性有机物的环境行为[J]. 环境科学与技术, 2008,31(7):69-73. Ren L X, Heavy metal species in soil and environment behavior of dissolved organic matter[J]. Environmental Science & Technology, 2008,31(7):69-73.
|
|
|
|
