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| Preparation andperformance of UIO-66modified thin-film nanocomposite membrane for forward osmosis |
| ZHANG Zhe, WANG Lei, HE Miao-lu, CUI Qi, WANG Xu-dong |
| School of Environment and Municipal Engineering, Xi'an University of Architecture and Technology, Research Institute of Membrane Separation Technology of Shaanxi Province, Key Laboratory of Membrane Separation of Shaanxi Province, Key Laboratory of Environmental Engineering of Shaanxi Province, Key Laboratory of Northwest water Resources, Environmental and Ecology, Ministry of Education;Xi'an 710055, China |
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Abstract UIO-66 modified thin-film composite membrane for forward osmosis was fabricated by forming polyamide layer via interfacial polymerization. FI-IR, SEM, AFM, XRD, and contact angle have been utilized to characterize UIO-66 and the thin-film nanocomposite membranes (TFN) for forward osmosis.With DI water as feed solution and a 1mol/L NaCl as draw solution,the water flux of TFN0.04 membrane prepared with dispersing 0.04 wt% of UIO-66, reached from 10.28L/(m2·h) to 13.67L/(m2·h)under FO mode and 17.68L/(m2·h) to 20.41L/(m2·h) under PRO mode. Modified composite membrane has improved permeability and better selection performance. Meanwhile, The pollution experiment found that compared with the pure thin film composite membrane, the modified thin film composite membrane has a slower flux decay tendency and less adhesion to contaminant, which indicated that the modified composite membranes is resistant to pollution.
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Received: 06 November 2019
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| [1] |
Tzahi Y.Cath, Amy E.Childress, Menachem Elimelech.Forward osmosis: Principles, applications, and recent developments [J].Journal of Membrane Science, 2006,81(1/2):70-87.
|
| [2] |
Tai-Shung Chung, Sui Zhang, Kai Yu Wang, et al.Forward osmosis processes: Yesterday, today and tomorrow [J].Desalination, 287(none):78-81.
|
| [3] |
Babu B R, Rastogi N K, Raghavarao K S M S.Effect of process parameters on transmembrane flux during direct osmosis [J].Journal of Membrane Science, 2006,280(1):185-194.
|
| [4] |
Loeb S.Energy production at the Dead Sea by pressure-retarded osmosis: challenge or chimera [J].Desalination, 1998,120(3):247-262.
|
| [5] |
MCGINNIS, Robert L, MCCUTCHEON, et al.A novel ammonia-carbon dioxide osmotic heat engine for power generation [J].Journal of Membrane Science, 2007,305(1):13-19.
|
| [6] |
Chetan A.Nayak, Navin K.Rastogi.Forward osmosis for the concentration of anthocyanin from Garcinia indica Choisy [J].Seperation and Purification Technology, 2010,71:144-151.
|
| [7] |
Lavan D A, Mcguire T, Langer R.Small-scale systems for in vivo drug delivery [J].Nature Biotechnology, 2003,21(10):1184-1191.
|
| [8] |
Obaid M, Tolba G M K, Motlak M, et al.Effective polysulfone-amorphous SiO2NPs electrospun nanofiber membrane for high flux oil/water separation [J].Chemical Engineering Journal, 2015,279: 631-638.
|
| [9] |
Maryam Amini, Mohsen Jahanshahi, Ahmad Rahimpour.Synthesis of novel thin film nanocomposite (TFN) forward osmosis membranes using functionalized multi-walled carbon nanotubes [J].Journal of Membrane Science, 2013,435:233-241.
|
| [10] |
Shen L, Xiong S, Wang Y.Graphene oxide incorporated thin-film composite membranes for forward osmosis applications [J].Chemical Engineering Science, 2016,143:194-205.
|
| [11] |
Panda S R, De S.Preparation, characterization and performance of ZnCl2 incorporated polysulfone (PSF)/polyethylene glycol (PEG) blend low pressure nanofiltration membranes [J].Desalination, 2014, 347(17):52-65.
|
| [12] |
Zirehpour, Alireza, Rahimpour, Ahmad, Seyedpour, Fatemeh, et al.Developing new CTA/CA-based membrane containing hydrophilic nanoparticles to enhance the forward osmosis desalination [J].Desalination, 371:46-57.
|
| [13] |
Ma N, Wei J, Liao R, et al Zeolite-polyamide thin film nanocomposite membranes: Towards enhanced performance for forward osmosis [J].Journal of Membrane Science, 2012,405-406(none):149-157.
|
| [14] |
况武,康国栋,等.有机/无机杂化TiO2纳米粒子掺杂改性复合正渗透膜活性分离层的研究[J].膜科学与技术, 2016,(6):25-31. Kuang W, Kang G D, et al.Modification of thin-film composite forward osmosis membrane active layer using organic-inorganic hybrid TiO2 nanoparticles [J].Membrane Science and Technology, 2016,(6):25-31.
|
| [15] |
Yaghi O M, Li Guangming, Li Hailian.Selective binding and removal of guests in a microporous metal-organic framework [J].Nature, 378(6558):703-706.
|
| [16] |
Yaghi O M, Li Hailian.Hydrothermal synthesis of a metal-organic framework containing large rectangular channels [J].Journal of the American Chemical Society, 117(41):10401-10402.
|
| [17] |
Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro.Functional porous coordination polymers [J].Angewandte Chemie, 43(18):2334-2375.
|
| [18] |
Dhakshinamoorthy A, Garcia H.Cascade reactions catalyzed by metal organic frameworks.[J].Chemsuschem, 2015,45(49):2392-2410.
|
| [19] |
Jared DeCoste B, Gregory Peterson W, Himanshu Jasuja.Stability anddegradation mechanisms of metal-organic frameworks containing the Zr6O4(OH)4 secondary building unit [J].Journal of Materials Chemistry A, 1(18):5642.
|
| [20] |
Hu Zhigang, Zhao Dan.De facto methodologies toward the synthesis and scale-up production of UiO-66-type metal-organic frameworks and membrane materials [J].Dalton Transactions, 44(44):10.1039.
|
| [21] |
王薇,张倩,殷艳艳.UIO-66改性PVDF超滤膜的制备及亲水性[J].天津工业大学学报, 2019,(4):18-23. Wang W, Zhang Q, Yin Y Y.Preparation and hydrophilicity of UiO-66modified PVDF ultrafiltration membrane [J].Journal of Tianjin Polytechnic University, 2019,(4):18-23.
|
| [22] |
Cavka J H, Jakobsen S, Olsbye U, et al.A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability.[J].Journal of the American Chemical Society, 2008,130(42): 13850-13851.
|
| [23] |
Cavka, Hafizovic J, Jakobsen, et al.A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability [J].Journal of the American Chemical Society, 2008,130(42): 13850-1.
|
| [24] |
Ma Dangchen, Peh Shing Bo, Han Gang, et al.Thin-film nanocomposite (TFN) membranes incorporated with super-hydrophilic metal-organic framework (MOF) UiO-66: Toward enhancement of water flux and salt rejectio [J].ACS Appl.Mater.Interfaces, 2017,9:7523-7534.
|
| [25] |
Jr E R N.Phenomenological theory of ion solvation.Effective radii of hydrated ions [J].Biochimica Et Biophysica Acta, 1959,63(9): 566-567.
|
| [26] |
朱振亚,白成玲,王磊,等.磺化氧化石墨烯/聚砜复合膜的制备及抗污染性能[J].复合材料学报, 2019,36(11):2515-2521. Zhu Z Y, Bai C L, Wang L, et al.Preparation and antifouling analysis of sulfonated graphene oxide/polysulfone composite membrane [J].Acta Materiae Compositae Sinica, 2019,36(11): 2515-2521.
|
| [27] |
张高旗,刘海宁,张凯松.正渗透处理生活污水过程中的膜污染研究[J].中国环境科学, 2013,33(12):2170-2175. Zhang G Q, Liu H N, Zhang K S.Characterization of membrane fouling in forward osmosis treating municipal wastewater [J].China Environmental Science, 2013,33(12):2170-2175.
|
| [28] |
Ma D, Peh S B, Han G, et al.Thin-Film Nanocomposite (TFN) Membranes Incorporated with Super-Hydrophilic Metal-Organic Framework (MOF) UiO-66: Toward Enhancement of Water Flux and Salt Rejection [J].ACS Applied Materials & Interfaces, 2017, 9(8):7523-7534.
|
| [29] |
Gordon T.Gray, Jeffrey R.McCutcheon, Menachem Elimelech.Internal concentration polarization in forward osmosis: role of membrane orientation [J].Desalination, 197(1-3):1-8.
|
| [30] |
苗瑞,王磊,田丽,等.海藻酸及腐殖酸共存对PVDF超滤膜的污染行为[J].中国环境科学, 2014,34(10):2568-2574. Miao R, Wang L, Tian L, et al.Investigating fouling behaviouro PVDF ultrafiltration membranes for alginate/humic acid mixtures [J].China Environmental Science, 2014,34(10):2568-2574.
|
|
|
|
