深圳市土壤砷的背景含量及其影响因素研究

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Abstract In order to find out the soil background content of arsenic in Shenzhen, 450 soil surface sample points and 50 typical soil profile sample points were set up in the area of basic ecological control line which was not or rarely affected by human activities. 500 surface samples and 100 deep samples were collected by multi-point incremental sampling method. The results showed that the background content of arsenic in the surface soil was 0.07~202mg/kg, the arithmetic average value was 11.3mg/kg, and the 95% fraction value was 55.9mg/kg, which was significantly higher than the 95% fraction value (35.4mg/kg) of Shenzhen soil environmental background survey during the seventh five-year plan. The arithmetic average values of background content of arsenic in lateritic red soil, red soil and yellow soil were similar in different soil types, and the order of 95% fraction values were red soil > lateritic red soil > yellow soil. The order of arithmetic average of arsenic in different parent rocks were grey limestone > gravel shale > tuff lava > metamorphic rock > granite > gneiss, and the order of 95% fraction values were grey limestone > gravel shale > tuff lava > metamorphic rock > gneiss > granite. The average and 95% fraction values of arsenic in different section layers were quite different. The order of arsenic content were bottom layer> middle layer > surface layer. With the increase of depth, the soil background content of arsenic gradually increased. Soil pH and sand content were negatively correlated with background content of arsenic, while clay and silt content were positively correlated with background content of arsenic. Soil parent rock and mechanical composition were the main factors that affected the soil background content of arsenic in Shenzhen. The results could be provide reference for the study of soil environmental background value of arsenic in typical regions of South China.

Key words： soil arsenic background content influence factors

Received: 19 December 2019

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	Articles by authors
	ZHAO Shu-hua
	LUO Fei
	XI Xiu-ping
	YANG Kun
	LIAO Man
	ZHAO Yan
	WU Jing-ya

Cite this article:

ZHAO Shu-hua,LUO Fei,XI Xiu-ping等. Study of soil background content of arsenic and its impact factors in Shenzhen[J]. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(7): 3061-3069.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2020/V40/I7/3061

[1]	李圣发,王宏镔.土壤砷污染及其修复技术的研究进展[J]. 水土保持研究, 2011,18(4):248-253. Li S F, Wang H B. Advances in the study of srsenic-contaminated soil and its remediation technology[J]. Research of Soil and Water Conservation, 2011,18(4):248-253.
[2]	Matschullat J. Arsenic in the geosphere:a review[J]. Science of the Total Environment, 2000,249:297-312.
[3]	夏增禄,李森照,李廷芳,等土壤元素背景值及其研究方法[M]. 北京:气象出版社, 1987. Xia Z L, Li S Z, Li F T, et al. Background value of soil elements and its research method[M]. Beijing:China Meteorological Press, 1987
[4]	中国环境监测总站.中国土壤元素背景值[M]. 北京:中国环境科学出版社, 1990. China Nation Environmental Monitoring Centre. Background values of soil elements in China[M]. Beijing:China Environmental Science Press, 1990.
[5]	李淑媛,刘国贤,苗丰民.渤海沉积物中重金属分布及环境背景值[J]. 中国环境科学, 1994,14(5):370-376. Liu S Y, Liu G X, Miao F M. The distribution and environmental background values of the heavy metals in sediment of the Bohai Sea[J]. China Environmental Science, 1994,14(5):370-376.
[6]	唐将,钟远平,王力.三峡库区土壤重金属背景值研究[J]. 中国生态农业学报, 2008,16(4):848-852. Tang J, Zhong Y P, Wang L. Background value of soil heavy metal in the Three Gorges Reservoir District[J]. Chinese Journal of Eco-Agriculture, 2008,16(4):848-852.
[7]	王佛鹏,宋波,周浪,等.广西西江流域土壤重金属背景值再研究[J]. 环境科学学报, 2018,38(9):3695-3702. Wang F P, Song B, Zhou L, et al. Redistribution of heavy metal background in soil of Xijiang River Basin in Guangxi[J]. Acta Science Circumstantiae, 2018,38(9):3695-3702.
[8]	Wang B, Mao R Z, Cao J W, et al. Spatial variability of the heavy metal contents in cropland of the low Hai River Plain-A case study in Feixiang county of Hebei Province[J]. Acta Ecologica Sinica, 2006, 26(12):4082-4090.
[9]	王春松,盛奇,裴瑞亮.河南商丘地区土壤元素基准值与背景值研究[J]. 安徽农业科学, 2019,47(12):1-5. Wang C S, Sheng Q, Pei R L. Study on soil element reference value and background value in Shangqiu region of Henan province[J]. Journal of Anhui Agricultural Sciences, 2019,47(12):1-5.
[10]	Gerla P J, Sharif M U, Korom S F. Geochemical processes controlling the spatial distribution of selenium in soil and water, west central South Dakota, USA[J]. Environmental Earth Sciences, 2011,62(7):1551-1560.
[11]	Blaser P, Zimmermanna S, Luster J, et al. Critical examination of trace element enrichments and depletions in soils:As, Cr, Cu, Ni, Pb and Zn in Swiss forest soils[J]. The Science of the Total Environment, 2000, 249:257-280.
[12]	黄亚楠,潘少明,张威,等.中国大陆土壤中239+240Pu的来源与背景值研究[J]. 中国环境科学, 2018,38(12):4608-4616. Huang Y N, Pan S M, Zhang W, et al. The source and reference inventory of 239+240Pu in the soil of China[J]. China Environmental Science, 2018,38(12):4608-4616.
[13]	Chen M, Ma L Q, Hoogeweg C G, et al. Arsenic background concentrations in Florida USA surface soils:determination and interpretation[J]. Environmental Forensics, 2001,2:117-126.
[14]	庞绪贵,代杰瑞,陈磊,等.山东省17市土壤地球化学背景值[J]. 山东国土资源, 2019,35(1):46-56. Pang X G, Dai J R, Chen L, et al. Soil geochemical background value of 17cities in Shandong Province[J]. Shandong Land and Resources, 2019,35(1):46-56.
[15]	Galina Y, Monika P, Mariana H, et al. Establishment of geochemical background and threshold values for 8potential toxic elements in the Bulgarian soil quality monitoring network[J]. Science of the Total Environment, 2018,6:1297-1303.
[16]	王佛鹏,宋波,黄宇妃,等.广西西江流域土壤中铬空间分布与背景值再研究[J]. 土壤学报, 2018,55(4):889-899. Wang F P, Song B, Huang Y F, et al. Further study on spatial distribution and background value of chromium in soil in Xijiang River Basin, Guangxi, China[J]. Acta Pedologica Sinica, 2018,55(4):889-899.
[17]	HJ/T 166-2004土壤环境监测技术规范[S]. HJ/T 166-2004 The technical specification for soil environmental monitoring[S].
[18]	Roger B, John P, Marvin H. A Critical Review of Discrete Soil Sample Data Reliability:Part 1-Field Study Results[J]. Soil and Sediment Contamination:An International Journal, 2017,1:1-22.
[19]	GB/T 22105.2-2008土壤质量总汞、总砷、总铅的测定原子荧光法第2部分土壤中总砷的测定[S]. GB/T 22105.2-2008 Soil quality-analysis of total mercury, arsenic and lead contents atomic fluorescence spectrometry part 2:analysis of total arsenic contents in soils[S].
[20]	王帅,王红旗,周庆涛,等.基于稳健统计的土壤环境背景值研究及应用[J]. 环境科学研究, 2009,22(8):944-949. Wang S, Wang H Q, Zhou Q T, et al. Determination and application of soil environmental background concentrations based on robust statistics[J]. Research of Environmental Sciences, 2009,22(8):944-949.
[21]	许炼烽,刘腾辉.广东土壤环境背景值和临界含量的地带性分异[J]. 华南农业大学学报, 1996,17(4):58-62. Xu L F, Liu T H. The zonal differentiation of soil environmental background values and critical contents in Guangdong[J]. Journal of South China Agricultural University, 1996,17(4):58-62.
[22]	Michael K, Ales V, Vojtech E. Chemical stabilization of metals and arsenic in contaminated soils using oxides-a review[J]. Environmental Pollution, 2013,172:9-22.
[23]	张毅.广州地区赤红壤和植物的砷背景值状况研究[J]. 中国环境监测, 1992,8(3):121-125. Zhang Y. Study on arsenic background of red soil and plants in Guangzhou[J]. Environmental Monitoring in China, 1992,8(3):121-125.
[24]	杨萍如,刘腾辉.广东赤红壤的特征及其开发利用[J]. 自然资源学报, 1994,9(2):112-122. Yang P R, Liu T H. Characteristics of lateritic and red earth in Guangdong province and its exploitation and utilization[J]. Journal of Nature Resources, 1994,9(2):112-122.
[25]	陈振金,陈春秀,刘用清,等.福建省土壤环境背景值研究[J]. 环境科学, 1992,13(4):70-73. Chen Z J, Chen C X, Liu Y Q, et al. Study on soil environmental background values in Fujian province[J]. Environmental Science, 1992,13(4):70-73.
[26]	魏显有,王秀敏,刘云惠,等.土壤中砷的吸附行为及其形态分布研究[J]. 河北农业大学学报, 1999,22(3):28-30,55. Wei X Y, Wang X M, Liu Y H, et al. The study of the adsorptive behavior of Arsenic in soil and its form distribution[J]. Journal of Agriculture University of Hebei, 1999,22(3):28-30,55.
[27]	张山岭,杨国义,罗薇,等.广东省土壤无机元素背景值的变化趋势研究[J]. 土壤, 2012,44(6):100-1014. Zhang S L, Yang G Y, Luo W, et al. Changes of background values of inorganic elements in soils of Guangdong province[J]. Soil, 2012, 44(6):100-1014.
[28]	陶春军,贾十军,陈永宁,等.滁州地区土壤地球化学基准值与背景值研究[J]. 安徽地质, 2013,23(4):286-291. Tao C J, Jia S J, Chen Y N, et al. A study on geochemical baseline value and environmental background value of soils in the Chuzhou area[J]. Geology of Anhui, 2013,23(4):286-291.
[29]	刘爱华.土壤环境中As、Cd、Hg、Pb地球化学背景及通量研究[D]. 北京:中国地质大学, 2005. Liu A H. Research on geochemical background and flux for arsenic, cadmium, mercury and lead in soil environment[D]. Beijing:China University of Geosciences for Doctoral Degree, 2005.
[30]	王新.大连市土壤环境背景值影响因素分析[J]. 环境科学, 1992, 13(3):86-88. Wang X. Analysis of factors affecting background values of Hg in soils of Dalian[J]. Environmental Science, 1992,13(3):86-88.
[31]	唐诵六.土壤重金属地球化学背景值影响因素的研究[J]. 环境科学学报, 1986,7(3):245-252. Tang S L. Factors effecting the geochemical background contents of heavy metals in different soils of China[J]. Acta Science Circumstantiae, 1986,7(3):245-252.
[32]	李丽辉,汤沛,杨天仪,等.云南省滇池-抚仙湖地区土壤地球化学背景及元素分布特征[J]. 云南大学学报(自然科学版), 2017,39(S2):357-370. Li L H, Tang P, Yang T Y, et al. The soil geochemical background and the elements distribution characteristics in Dianchi Lake-Fuxian Lake area Yunnan province[J]. Journal of Yunnan University, 2017,39(S2):357-370.
[33]	杜俊平.太白山自然保护区土壤、植物和水体化学元素背景值及其分布特征的研究[D]. 杨凌:西北农林科技大学, 2007. Du J P. Environmental background values of chemical elements in soils, plants and waters of Taibaishan nature reserve[D]. Yangling:Northwest A&F University, 2007.
[34]	陈兴仁,陈富荣,贾十军,等.安徽省江淮流域土壤地球化学基准值与背景值研究[J]. 中国地质, 2012,39(2):302-310. Chen X R, Chen F R, Jia S J, et al. Soil geochemical baseline and background in Yangtze River-Huaihe River basin of Anhui Province[J]. Geology in China, 2012,39(2):302-310.
[35]	方元,吴志峰,杨春林.广东省土壤铜环境背景值空间变异研究[J]. 土壤通报, 2008,39(3):647-651. Fang Y, Wu Z F, Yang C L. Spatial distribution and vertical variation of soil Cu environmental background value in Guangdong[J]. Chinese Journal of Soil Science, 2008,39(3):647-651.
[36]	王平,曹军骥,吴枫.青海湖流域表层土壤环境背景值及其影响因素[J]. 地球环境学报, 2010,1(3):189-200. Wang P, Cao J J, Wu F. Environmental background values and its impact factors of topsoil within the Lake Qinghai catchment, Northeast Tibetan Plateau, China[J]. Journal of Earth Environment, 2010,1(3):189-200.
[37]	罗思亮.广东省阳江-茂名地区土壤地球化学背景值与基准值分析[J]. 云南化工, 2018,45(6):89-92. Luo S L. Analysis of soil geochemical background values and reference values in Yangjiang Maoming area of Guangdong Province[J]. Yunnan Chemical Technology, 2018,45(6):89-92.
[38]	吴丹,李薇.湖北省土壤砷的背景值及分布特征[J]. 华中农业大学学报, 1993,12(5):455-463. Wu D, Li W. A research on background values and distribution of as in soils of Hubei province[J]. Journal of Huazhong Agricultural University, 1993,12(5):455-463.