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Visible light photocatalytic system made by polymer matrix composites 3D printing for virus aerosol removal |
KONG Ya-dong1, SHI Lei1, LIU Meng-meng2, ZHANG Wei1, CHENG Rong1, ZHENG Xiang1 |
1. School of Environment & Natural Resources, Renmin University of China, Beijing 100872, China;
2. Department of Water Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China |
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Abstract Take the advantage of design flexibility of polymer matrix composites 3D printing, the visible light-responsive ZnO/g-C3N4 catalyst was incorporated into ABS plastic to form a photocatalytic system with uniform and stable catalyst distribution. The reactor structure was optimized using Computational Fluid Dynamics simulation and the photocatalytic reactor was used to treat virus aerosols in relatively closed indoor areas. Results showed that viruses were more resistant than bacteria, and the addition of spiral baffles can increase the removal rate of virus aerosols, due to the significant improvement in the mass transfer performance of photocatalytic system. The spiral photocatalytic system can efficiently remove high-concentration virus (MS2, PhiX174phage) and bacterial (E. coli) aerosols with the help of commercial LED lights. Furthermore, photocatalytic system can remove virus aerosols and bacterial aerosols at a residence time of 3.75min.
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Received: 12 March 2020
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[1] |
吕文洲,乔宇祥,刘英.纳米TiO2-光催化灭活水中噬菌体MS2[J]. 中国环境科学, 2015,35(8):2532-2538. Lu W Z, Qiao Y X, Liu Y. Inactivation of bacteriophage MS2 in water by TiO2 nanoparticles coupled with light[J]. China Environmental Science, 2015,35(8):2532-2538.
|
[2] |
刘炫圻,冯萃敏,汪长征,等.紫外线-茶多酚联用对供水管网的消毒效果[J]. 中国环境科学, 2020,40(4):1563-1569. Liu X Q, Feng C M, Wang C Z, et al. Effect of combined disinfection using ultraviolet and tea polyphenols in network[J]. China Environmental Science, 2020,40(4):1563-1569.
|
[3] |
柳文菁,董志勇,杨杰,等.三角孔多孔板水力空化杀灭原水中病原微生物[J]. 中国环境科学, 2018,38(8):3011-3017. Liu W Q, Dong Y Z, Yang J, et al. Killing pathogenic microorganism by hydrodynamic cavitation due to triangular multi-orifice plates[J]. China Environmental Science, 2018,38(8):3011-3017.
|
[4] |
王丽,黄君礼,孙荣芳,等.二氧化氯对水中流感病毒的消毒效果[J]. 中国环境科学, 2001,21(3):256-258. Wang L, Huang, J L, Sun R F, et al. Inactivation effect of chlorine dioxide on influenza viruses in water[J]. China Environmental Science, 2001,21(3):256-258.
|
[5] |
Haas C N, Rose J B, Gerba C P. Quantitative Microbial Risk Assessment[M]. Hoboken, New Jersey:John Wiley & Sons, 2014.
|
[6] |
王艳秋,孙利群,刘晓杰,等.二氧化氯气体用于生物安全三级实验室消毒效果的评价[J]. 中国消毒学杂志, 2015,32(1):13-15. Wang Y Q, Sun L Q, Liu X J, et al. Evaluation of disinfection effect of chlorine dioxide gas on biosafety levels-Ⅲ laboratory[J]. Chinese Journal of Disinfection, 2015,32(1):13-15.
|
[7] |
Lin C Y, Li C S. Control effectiveness of ultraviolet germicidal irradiation on bioaerosols[J]. Aerosol Science and Technology, 2002, 36(4):474-478.
|
[8] |
Chen F, Yang X, Mak H K C, et al. Photocatalytic oxidation for antimicrobial control in built environment:a brief literature overview[J]. Building and Environment, 2010,45(8):1747-1754.
|
[9] |
Devahasdin S, Fan C, Li K, et al. TiO2photocatalytic oxidation of nitric oxide:transient behavior and reaction kinetics[J]. Journal of Photochemistry and Photobiology A:Chemistry, 2003,156(1-3):161-170.
|
[10] |
Zhao X, Lv L, Pan B, et al. Polymer-supported nanocomposites for environmental application:a review[J]. Chemical Engineering Journal, 2011,170(2):381-394.
|
[11] |
Su C, Tong Y, Zhang M, et al. TiO2nanoparticles immobilized on polyacrylonitrile nanofibers mats:a flexible and recyclable photocatalyst for phenol degradation[J]. RSC Advances, 2013,3(20):7503-7512.
|
[12] |
Im J S, Kim M I, Lee Y S. Preparation of PAN-based electrospun nanofiber webs containing TiO2 for photocatalytic degradation[J]. Materials Letters, 2008,62(21/22):3652-3655.
|
[13] |
Wang X, Jiang M, Zhou Z, et al. 3D printing of polymer matrix composites:A review and prospective[J]. Composites Part B:Engineering, 2017,110:442-458.
|
[14] |
Jo W, Yoon B J, Lee H, et al. 3D printed hierarchical gyroid structure with embedded photocatalyst TiO2 nanoparticles[J]. 3D Printing And Additive Manufacturing, 2017,4(11):33-42.
|
[15] |
Arango M A T, Kwakye-Ackah D, Agarwal S, et al. Environmentally friendly engineering and three-dimensional printing of TiO2 hierarchical mesoporous cellular architectures[J]. ACS Sustainable Chemistry & Engineering, 2017,5(11):10421-10429.
|
[16] |
Elkoro A, Casanova I. 3D printing of structured nanotitania catalysts:a novel binder-free and low-temperature chemical sintering method[J]. 3D Printing and Additive Manufacturing, 2018,5(3):1-8.
|
[17] |
Son S, Jung P H, Park J, et al. Customizable 3D-printed architecture with ZnO-based hierarchical structures for enhanced photocatalytic performance[J]. Nanoscale, 2018,10(46):21696-21703.
|
[18] |
Viskadourakis Z, Sevastaki M, Kenanakis G. 3D structured nanocomposites by FDM process:a novel approach for large-scale photocatalytic applications[J]. Applied Physics A, 2018,124(585):584-592.
|
[19] |
Hreiz R, Gentric C, Midoux N. Numerical investigation of swirling flow in cylindrical cyclones[J]. Chemical Engineering Research and Design, 2011,89(12):2521-2539.
|
[20] |
Dong F, Wu L W, Sun Y J, et al. Efficient synthesis of polymeric g-C3N4 layered materials as novel efficient visible light driven photocatalysts[J]. Journal of Materials Chemistry, 2011,21:15171-15174.
|
[21] |
Yang C, Xue Z, Qin J, et al. Heterogeneous structural defects to prompt charge shuttle in g-C3N4 plane for boosting visible-light photocatalytic activity[J]. Applied Catalysis B:Environmental, 2019, 259:118094.
|
[22] |
Gong Y, Li H K, Jiao C, et al. Effective hydrogenation of g-C3N4 for enhanced photocatalytic performance revealed by molecular structure dynamics[J]. Applied Catalysis B:Environmental, 2019,250:63-70.
|
[23] |
Zhang C, Yuan X G, Luo Y Q, et al. Prediction of species concentration distribution using a rigorous turbulent mass diffusivity model for bubble column reactor simulation Part I:Application to chemisorption process of CO2 into NaOH solution[J]. Chemical Engineering Science, 2018,184:167-171.
|
[24] |
Cho M, Kim J, Kim J Y, et al. Mechanisms of Escherichia coli inactivation by several disinfectants[J]. Water Research, 2010,44(11):3410-3418.
|
[25] |
Tseng C C, Li C S. Ozone for inactivation of aerosolized bacteriophages[J]. Aerosol Science & Technology, 40(9):683-689.
|
[26] |
代小英,许欣,陈昭斌,等.纳米银水溶液对噬菌体和细菌杀灭效果的观察[J]. 中国消毒学杂志, 2008,25(3):242-244. Dai X X, Xu X, Chen Z B, et al. Observation on microbicidal efficacy of silver nanoparticles aqueous solution to bacteriophages and bacteria[J]. Chinese Journal of Disinfection, 2008,25(3):242-244.
|
[27] |
Sudharsanam S, Swaminathan S, Ramalingam A, et al. Characterization of indoor bioaerosols from a hospital ward in a tropical setting[J]. African Health Sciences, 2012,12(2):217-225.
|
[28] |
Godini H, Azimi F, Kamarehie B, et al. Bio-aerosols concentrations in different wards of Khorramabad Hospital, Iran, 2013[J]. International Journal of Environmental Health Engineering, 2015,4:23.
|
[29] |
Li Y, Huang X, Yu I T, et al. Role of air distribution in SARS transmission during the largest nosocomial outbreak in Hong Kong[J]. Indoor Air, 2005,15(2):83-95.
|
[30] |
Sornboot J, Aekplakorn W, Ramasoota P, et al. Assessment of bioaerosols in tuberculosis high-risk areas of health care facilities in central Thailand[J]. Asian Biomedicine, 2019,12(2):55-63.
|
[31] |
Lee B U, Hong I G, Lee D H, et al. Bacterial Bioaerosol Concentrations in Public Restroom Environments[J]. Aerosol and Air Quality Research, 2012,12(2):251-255.
|
[32] |
Thorne P S, Ansley A C, Perry, S S. Concentrations of bioaerosols, odors, and hydrogen sulfide inside and downwind from two types of swine livestock operations[J]. Journal of Occupational and Environmental Hygiene, 2009,6(4):211-220.
|
[33] |
Pascual L, Pérez-Luz S, Yáñez M A, et al. Bioaerosol emission from wastewater treatment plants[J]. Aerobiologia, 2003,19:261-270.
|
[34] |
GB 37488-2019公共场所卫生指标及限值要求[S]. GB 37488-2019 Health index and limit requirements of public places[S].
|
|
|
|