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Multi-field coupling simulation of LNAPL migration in cold regions |
FU Xiao-qin, SHI Xiao-qing, JIANG Jian-guo, WU Ji-chun |
Key Laboratory of Surficial Geochemistry of Ministry of Education, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, China |
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Abstract A multi-field coupling model of temperature, flow and chemical fields including water, gas, NAPL, and solid (ice) phases was established to quantitatively simulate the migration and distribution of LNAPL under freezing condition during LNAPL leakage. By comparing the LNAPL flow model under non-freezing conditions, the simulated results found that LNAPL would undergo different migration behavior due to the formed ice under freezing conditions. The formed ice prevented LNAPL from infiltrating and generated freezing potential to make LNAPL migrate to the surface. The difference of LNAPL mass flux was -51.1% when the LNAPL infiltration reached stable under freezing/non-freezing conditions. Under freezing conditions, the speed of LNAPL plume in the horizontal direction was greater than that under non-freezing conditions. The maximum predicted error of LNAPL dissolved and volatilized components during the infiltration process was 2.4% and -24.9%, respectively, if freezing condition was not considered. However, the freezing condition had little effect on the dissolved and volatilized components of LNAPL when the LNAPL infiltration reached stable, and only the volatilized component had an error of 1.8%. But the adsorbed component was reduced, and the error was -6.6%.
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Received: 06 August 2021
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[1] |
李国玉,马巍,李兴柏,等.多年冻土区石油污染物迁移过程研究回顾与展望[J].冰川冻土, 2011,33(4):947-952. Li G Y, Ma W, Li X B, et al. Migration of the petroleum pollutants in permafrost regions:Review and prospect[J]. Journal of Glaciology and Geocryology, 2011,33(4):947-952.
|
[2] |
施小清,吴吉春,刘德朋,等.饱和介质中重非水相液体运移的数值模拟及敏感性分析[J].南京大学学报(自然科学版), 2011,47(3):299-307. Shi X Q, Wu J C, Liu D P, et al. Numerical simulation of transportation of dense nonaqueous phase liquids in the subsurface environment[J]. Journal of Nanjing University (Natural Sciences), 2011,47(3):299-307.
|
[3] |
Yang Z B, Zandin H, Niemi A, et al. The role of geological heterogeneity and variability in water infiltration on non-aqueous phase liquid migration[J]. Environmental Earth Sciences, 2013,68(7):2085-2097.
|
[4] |
王涵,卢文喜,李久辉,等.地下水DNAPLs污染多相流的随机模拟及其不确定性分析[J].中国环境科学, 2018,38(7):2572-2579. Wang H, Lu W X, Li J H, et al. Stochastic simulation and uncertainty analysis of multi-phase flow of groundwater polluted by DNAPLs[J]. China Environmental Science, 2018,38(7):2572-2579.
|
[5] |
郑菲,高燕维,施小清,等.地下水流速及介质非均质性对重非水相流体运移的影响[J].水利学报, 2015,46(8):925-933. Zheng F, Gao Y W, Shi X Q, et al. Influence of groundwater flow velocity and geological heterogeneity on DNAPL migration in saturated porous media[J]. Journal of Hydraulic Engineering, 2015,46(8):925-933.
|
[6] |
Van Genuchten M T. A closed-form equation for predicting the hydraulic conductivity of unsaturated soils[J]. Soil Science Society of America Journal, 1980,44(5):892-898.
|
[7] |
Brooks R H, Corey A T. Properties of porous media affecting fluid flow[J]. Journal of the Irrigation and Drainage Division, 1966,92(2):61-90.
|
[8] |
Falta R W, Pruess K, Javandel I, et al. Numerical modeling of steam injection for the removal of nonaqueous phase liquids from the subsurface:1. Numerical formulation[J]. Water Resource Research, 1992,28(2):433-449.
|
[9] |
Adenekan A E, Patzek T W, Pruess K. Modeling of multi-phase transport of multicomponent organic contaminants and heat in the subsurface:Numerical model formulation[J]. Water Resource Research, 1993,29(11):3727-3740.
|
[10] |
White M D, Oostrom M, Lenhard R J. Modeling fluid flow and transport in variably saturated porous media with the STOMP simulator. 1. Nonvolatile three-phase model description[J]. Advances in Water Resources, 1995,18(6):353-364.
|
[11] |
阮冬梅,卞建民,王倩,等.低渗透介质中轻非水相流体迁移转化规律[J].中国环境科学, 2021,41(4):1815-1823. Ruan D M, Bian J M, Wang Q, et al. The migration and transformation of light non-aqueous fluid in silty clay[J]. China Environmental Science, 2021,41(4):1815-1823.
|
[12] |
Hofstee C, Lenhard R J, et al. Flow behavior and residual saturation formation of liquid carbon tetrachloride in unsaturated heterogeneous porous media[J]. Journal of Contaminant Hydrology, 2003,64(1):93-112.
|
[13] |
Lo I M, Hu L M, Meegoda J N. Centrifuge modeling of light nonaqueous phase liquids transport in unsaturated soils[J]. Journal of Geotechnical and Geoenvironmental Engineering, 2004,130(5):535-539.
|
[14] |
Kechavarzi C, Soga K, Lllangasekare T H. Two-dimensional laboratory simulation of LNAPL infiltration and redistribution in the vadose zone[J]. Journal of Contaminant Hydrology, 2005,76(3/4):211-233.
|
[15] |
Lenhard R J, Rayner J L, Davis G B. A practical tool for estimating subsurface LNAPL distributions and transmissivity using current and historical fluid levels in ground water wells:Effects of entrapped and residual LNAPL[J]. Journal of Contaminant Hydrology, 2017,205:1-11.
|
[16] |
Kacem M, Esrael D, Boeije C S, et al. Multiphase Flow Model for NAPL Infiltration in Both the Unsaturated and Saturated Zones[J]. Journal of Environmental Engineering, 2019,145(11):04019072.
|
[17] |
Biggar K W. Site investigations of fuel spill migration into permafrost[J]. Journal of Cold Regions Engineering, 1998,12(2):84-104.
|
[18] |
Chuvilin E M, Naletova N S, Miklyaeva E C, et al. Factors affecting spreadability and transportation of oil in regions of frozen ground[J]. Polar Record, 2001,37(202):229-238.
|
[19] |
Barnes D L, Wolfe S M. Influence of Ice on the Infiltration of Petroleum into Frozen Coarse-grained Soil[J]. Petroleum Science and Technology, 2008,26(7/8):856-867.
|
[20] |
Singh K, Niven R K. Non-aqueous Phase Liquid Spills in Freezing and Thawing Soils:Critical Analysis of Pore-Scale Processes[J]. Critical Reviews in Environmental Science and Technology, 2013, 43(6):551-597.
|
[21] |
徐树林,那平山,武俊英.关于冻结滞水的探讨[J].内蒙古林学院报, 1994,(2):46-51. Xu S L, Na P S, Wu J Y. An approach to frozen perched groundwater[J]. Journal of inner Mongolia forestry college, 1994,(2):46-51.
|
[22] |
李兴柏,李国玉.温度梯度对多年冻土区石油迁移影响的研究[J].甘肃科学学报, 2013,25(1):73-76. Li X B, Li G Y. Experimental study on the influence of temperature gradient on the migrating process of oil contaminants in permafrost regions[J]. Journal of Gansu Sciences, 2013,25(1):73-76.
|
[23] |
吴国忠,赵文浩,吕妍,等.多孔介质内油、水介质迁移对比低温实验[J].当代化工, 2016,45(6):1108-1111. Wu G Z, Zhao W H, Lv Y, et al. Comparison of the migration of oil and water in porous medium with cryogenic experiment[J]. Contemporary Chemical Industry, 2016,45(6):1108-1111.
|
[24] |
Zhang M L, Wen Z, Xue K, et al. A coupled model for liquid water, water vapor and heat transport of saturated-unsaturated soil in cold regions:model formulation and verification[J]. Environmental Earth Sciences, 2016,75(8):1-19.
|
[25] |
胡黎明,邢巍巍,吴照群.多孔介质中非水相流体运移的数值模拟[J].岩土力学, 2007,28(5):951-955. Hu N M, Xin W W, Wu Z Q. Numerical simulation of non-aqueous phase liquids migration in porous media[J]. Rock and Soil Mechanics, 2007,28(5):951-955.
|
[26] |
Kacem M, Benadda B. Mathematical model for multiphase extraction simulation[J]. Journal of Environmental Engineering, 2018,144(6):04018040.
|
[27] |
高彦斌,张松波,李韬,等.饱和黏性土中重质非水相有机污染物纵向迁移数值模拟[J].同济大学学报(自然科学版), 2020,48(1):24-32. Gao Y B, Zhang S B, Li T, et al. Numerical analysis of vertical migration of dense nonaqueous-phase liquids in saturated clay[J]. Journal of Tongji University (Natural Science), 2020,48(1):24-32.
|
[28] |
Parker J C, Lenhard R J, Kuppusamy T. A parametric model for constitutive properties governing multiphase flow in porous media[J]. Water Resource Research, 1987,23(4):618-624.
|
[29] |
Peng X, Yu B. Developing a new form of permeability and Kozeny-Carman constant for homogeneous porous media by means of fractal geometry[J]. Advances in Water Resources, 2008,31(1):74-81.
|
[30] |
白青波,李旭,田亚护,等.冻土水热耦合方程及数值模拟研究[J].岩土工程学报, 2015,37(S2):131-136. Bai Q B, Li X, Tian Y H, et al. Equations and numerical simulation for coupled water and heat transfer in frozen soil[J]. Chinese Journal of Geotechnical Engineering, 2015,37(S2):131-136.
|
[31] |
刘伟,范爱武,黄晓明.多孔介质传热传质理论与应用[M].北京:科学出版社, 2006:28-30. Liu W, Fang A W, Huang X M. Theory and Application of Heat and Mass Transfer in Porous Media[M]. Beijing:Science Press, 2006:28-30.
|
[32] |
Millington R J. Gas Diffusion in Porous Media[J]. Science, 1959,130(3367):100-102.
|
[33] |
Kim J, Corapcioglu M Y. Modeling dissolution and volatilization of LNAPL sources migrating on the groundwater table[J]. Journal of Contaminant Hydrology, 2003,65(1):137-158.
|
|
|
|