寒旱区草原湖泊沉积物重金属地球化学基线构建——以达里诺尔湖为例

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (732 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract In order to scientifically identify the accumulation of heavy metals in the sediments of Dalinuoer Lake, a typical grassland-type lake in cold-arid regions, the content of heavy metals in surface and core sediments were investigated, the geochemical baselines of heavy metals in the sediments were constructed by various statistical methods, and different baseline results were comparatively analyzed from many aspects. The results showed that: the 8 metals including Cr, Ni, Cu, Zn, As, Cd, Hg, and Pb were distributed normally or log-normally in the surface and core sediments of Dalinuoer Lake, and the metal distributions in the core sediments were more concentrated than those in the surface sediments. The vertical distributions of As, Cd, Hg showed obvious increasing trends in the near surface layer, indicating a certain degree of enrichment. Three statistical methods including the reference element method, the relative cumulative frequency method and the iterative 2times standard deviation method were used to calculated the heavy metal baselines and there were no significant differences (P<0.05) among the baselines obtained by the above methods both in surface sediment and in core sediment. Considering scientificity,applicability, simplicity, and personal error, the iterative 2 times standard deviation method could be preferred to construct element baselines. The constructed geochemical baselines of heavy metals in Dalinuoer Lake sediments were different from the soil background values of heavy metals in large-scale regions, and the heavy metal baselines in surface sediment were also different from those in core sediment. Considering few human interference in Dalinuoer Lake Basin, the metal baselines of surface sediment were more useful for scientific and accurate identification in the current accumulation and ecological risks of heavy metals in the lake. The results could provide the important theoretical basis in constructing the metal baselines in similar grassland-type lake sediments in cold-arid regions.

Key words： statistics sediment heavy metal geochemical baseline value

Received: 25 May 2022

PACS:

X524

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	LI He
	JIANG Xia
	WANG Shu-hang
	CHE Fei-fei

Cite this article:

LI He,JIANG Xia,WANG Shu-hang等. Geochemical baseline establishment in grassland-type lake sediments in cold-arid regions: A case study in Dalinuoer Lake, China[J]. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(12): 5803-5813.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2022/V42/I12/5803

[1]	He Y, Guo C, Lv J, et al. Predicting trace metal bioavailability to chironomids in sediments by diffusive gradients in thin films[J]. Science of the Total Environment, 2018,636:134-141.
[2]	Hu C, Yang X, Dong J, et al. Heavy metal concentrations and chemical fractions in sediment from Swan Lagoon, China:Their relation to the physiochemical properties of sediment[J]. Chemosphere, 2018,209:848-856.
[3]	Lenoble V, Omanovic D, Garnier C, et al. Distribution and chemical speciation of arsenic and heavy metals in highly contaminated waters used for health care purposes (Srebrenica, Bosnia and Herzegovina)[J]. Science of the Total Environment, 2013,443:420-428.
[4]	He Y, Men B, Yang X, et al. Investigation of heavy metals release from sediment with bioturbation/bioirrigation[J]. Chemosphere, 2017, 184:235-243.
[5]	Merhaby D, Net S, Halwani J, et al. Organic pollution in surficial sediments of Tripoli harbour, Lebanon[J]. Marine Pollution Bulletin, 2015,93(1/2):284-293.
[6]	Merhaby D, Ouddane B, Net S, et al. Assessment of trace metals contamination in surficial sediments along Lebanese coastal zone[J]. Marine Pollution Bulletin, 2018,133:881-890.
[7]	Xiong C, Wang D, Tam N F, et al. Enhancement of active thin-layer capping with natural zeolite to simultaneously inhibit nutrient and heavy metal release from sediments[J]. Ecological Engineering, 2018, 119:64-72.
[8]	Fang T, Lu W, Cui K, et al. Distribution, bioaccumulation and trophic transfer of trace metals in the food web of Chaohu Lake, Anhui, China[J]. Chemosphere, 2019,218:1122-1130.
[9]	Wang M, Liu J, Lai J. Metals pollution and ecological risk assessment of sediments in the Poyang Lake, China[J]. Bulletin of Environmental Contamination and Toxicology, 2019,102(4):511-518.
[10]	赵艳民,秦延文,曹伟,等.洞庭湖表层沉积物重金属赋存形态及生态风险评价[J]. 环境科学研究, 2020,33(3):572-580. Zhao Y M, Qin Y W, Cao W, et al. Speciation and ecological risk of heavy metals in surface sediments of Dongting Lake[J]. Research of Environmental Sciences, 2020,33(3):572-580.
[11]	Roca-Perez L, Gil C, Cervera M L, et al. Selenium and heavy metals content in some Mediterranean soils[J]. Journal of Geochemical Exploration, 2010,107(2):110-116.
[12]	李敏,成杭新,李括.中国淡水湖泊沉积物地球化学背景与环境质量基准建立的思考[J]. 地学前缘, 2018,25(4):276-284. Li M, Cheng H X, Li K. Geochemical background of freshwater lake sediments:a constraint on the establishmentof sediment quality guidelines in China[J]. Earth Science Frontiers, 2018,25(4):276-282.
[13]	Salminen R, Gregorauskiene V. Considerations regarding the definition of a geochemical baseline of elements in the surficial materials in areas differing in basic geology[J]. Applied Geochemistry, 2000,15(5):647-653.
[14]	Reimann C, Fabian K, Birke M, et al. GEMAS:Establishing geochemical background and threshold for 53chemical elements in European agricultural soil[J]. Applied Geochemistry, 2018,88:302-318.
[15]	Tian K, Huang B, Xing Z, et al. Geochemical baseline establishment and ecological risk evaluation of heavy metals in greenhouse soils from Dongtai, China[J]. Ecological Indicators, 2017,72:510-520.
[16]	赵超,王琦,戴金平.山东省土壤重金属背景值调查与分析[J]. 环境保护科学, 2021,47(4):117-121. Zhao C, Wang Q, Dai J P. Investigation and analysis of background value of heavy metals in soil of Shandong Province Environmental[J]. Protection Science, 2021,47(4):117-121.
[17]	Hernandez-Crespo C, Martin M. Determination of background levels and pollution assessment for seven metals (Cd, Cu, Ni, Pb, Zn, Fe, Mn) in sediments of a Mediterranean coastal lagoon[J]. Catena, 2015,133:206-214.
[18]	Wang S H, Wang W W, Chen J Y, et al. Geochemical baseline establishment and pollution source determination of heavy metals in lake sediments:A case study in Lihu Lake, China[J]. Science of the Total Environment, 2019,657:978-986.
[19]	Wei C, Wen H. Geochemical baselines of heavy metals in the sediments of two large freshwater lakes in China:implications for contamination character and history[J]. Environmental Geochemistry and Health, 2012,34(6):737-748.
[20]	Chen L, Zhao J, Zhang Z, et al. Lake eutrophication in northeast China induced by the recession of the East Asian summer monsoon[J]. Quaternary Science Reviews, 2022,281.
[21]	赵胜男,史小红,崔英,等.内蒙古达里诺尔湖湖泊水体与入湖河水水化学特征及控制因素[J]. 环境化学, 2016,35(9):1865-1875. Zhao S N, Shi X H, Cui Y, et al. Hydrochemical properties and controlling factors of the Dali Lake and its inflow river water in Inner Mongolia[J] Environmental Chemistry, 2016,35(9):1865-1875.
[22]	春兰,秦福莹,包玉海.3个时期达里诺尔国家级湿地自然保护区土地利用动态研究[J]. 中国农学通报, 2018,34(13):100-105. Chun L, Qin F Y, Bao Y H. National wetland nature reserve in 3periods:land use dynamics[J]. Chinese Agricultural Science Bulletin, 2018,34(13):100-105.
[23]	任丽敏,何江,吕昌伟,等.达里诺尔湖生物有效态重金属的形态分布及生态风险评价[J]. 农业环境科学学报, 2013,32(2):338-346. Ren L M, He J, Lv W C, et al. Speciation distribution and ecological risk assessment of the bio-available heavy metals in Lake Dalinouer, China[J]. 2013,32(2):338-346.
[24]	Xu M, Sun W, Wang R. Spatial distribution and ecological risk assessment of potentially harmful trace elements in surface sediments from Lake Dali, North China[J]. Water, 2019,11(12).
[25]	郝世祺,张生,李文宝,等.达里诺尔湖近2400年以来Hg元素含量变化及环境意义[J]. 环境科学学报, 2017,37(8):2889-2896. Hao S Q, Zhang S, Li W B, et al. Characteristics and environment implications of Hg in sediment of Dali-Nor Lake during 2400 cal.a BP[J]. Acta Scientiae Circumstantiae, 2017,37(8):2889-2896.
[26]	王璐,赵茜,王晓,等.达里诺尔湖水质污染物空间分布特征及来源解析[J]. 环境污染与防治, 2021,43(5):601-605. Wang L, Zhao Q, Wang X, et al. Spatial distribution characteristics and source analysis of water pollutants in Dalinuoer lake[J]. Environmental Pollution & Control, 2021,43(5):601-605.
[27]	姜霞,王书航.沉积物质量调查评估手册[M]. 北京:科学出版社, 2012.
[28]	Chen C, Zheng B, Jiang X, et al. Spatial distribution and pollution assessment of mercury in sediments of Lake Taihu, China[J]. Journal of Environmental Sciences, 2013,25(2):316-325.
[29]	Holmgren G G S, Meyer M W, Chaney R L, et al. Cadmium, Lead, Zinc, Copper, and Nicke in agricultural soils of the United-States-of-America[J]. Journal of Environment Quality, 1993,22(2):335-348.
[30]	赵丽,王雯雯,姜霞,等.丹江口水库沉积物重金属背景值的确定及潜在生态风险评估[J]. 环境科学, 2016,37(6):2113-2120. Zhao L, Wang W W, Jiang X, et al. Determination of background value and potential ecological risk assessment of heavy metals in sediments of the Danjiangkou Reservoir[J]. Environmental Science, 2016,37(6):2113-2120.
[31]	Coakley J P, Poulton D J. Source-related classification of St-lawrencen estuary sediments based on spatial distribution of adsorbed contaminants[J]. Estuaries, 1993,16(4):873-886.
[32]	Wu Y, Hou X, Cheng X, et al. Combining geochemical and statistical methods to distinguish anthropogenic source of metals in lacustrine sediment:a case study in Dongjiu Lake, Taihu Lake catchment, China[J]. Environmental Geology, 2007,52(8):1467-1474.
[33]	Schropp S J, Lewis F G, Windom H L, et al. Interpretation of metal concentrations in estuarine sediments of Florida using aluminum as a reference element[J]. Estuaries, 1990,13(3):227-235.
[34]	Tam N, Yao M. Normalisation and heavy metal contamination in mangrove sediments[J]. Science of the Total Environment, 1998,216(1/2):33-39.
[35]	Matschullat J, Ottenstein R, Reimann C. Geochemical background-can we calculate it?[J]. Environmental Geology, 2000,39(9):990-1000.
[36]	Selvaggi R, Damianic B, Goretti E, et al. Evaluation of geochemical baselines and metal enrichment factor values through high ecological quality reference points:a novel methodological approach[J]. Environmental Science and Pollution Research, 2020,27(1):930-940.
[37]	范俊楠,贺小敏,杜维,等.基于标准化方法和统计分析法的土壤重金属环境基线值分析比较[J]. 华中农业大学学报, 2021,40(1):160-167. Fan J N, He X M, Du W, etal.Analyzing and comparing environmental baseline values of heavy metals in soil based on standardized method and statistical method[J]. Journal of Huazhong Agricultural University (Natural Science Edition), 2021,40(1):160-167.
[38]	温海龙.太湖与滇池表层沉积物重金属环境地球化学基线的厘定[D]. 南昌:南昌大学, 2011. Wen H L. The determination of environmental geochemical baseline of heavy metals in surface sediments of Lake Taihu and Lake Dianchi[D]. Nanchang:Nanchang University, 2011.
[39]	郁通.黄、东海陆架沉积物中重金属污染的长期记录与评价[D]. 青岛:青岛科技大学, 2014. Yu T. Yellow and East China sea shelf sediments of heavy metal pollution record and evaluation for A long time[D]. Qingdao:Qingdao University of Science & Technology, 2014.
[40]	Che F, Chen J, Zhang B, et al. Distribution, risk and bioavailability of metals in sediments of Lake Yamdrok Basin on the Tibetan Plateau, China[J]. Journal of Environmental Sciences, 2020,97:169-179.
[41]	楠定其其格.岱海与达里诺尔湖重金属的环境地球化学研究[D]. 呼和浩特:内蒙古大学, 2013. Nandingqiqige. Study on environmental geochemisstry of heavy metals in DAIHAI and Dalinuoer lake[D]. Huhehaote:Inner Mongolia University, 2013.
[42]	中国环境监测总站.中国土壤元素背景值[M]. 北京:中国环境科学出版社, 1990. China National Environmental Monitoring Centre. Background values of soil elements in China[M]. Beijing:China Environmental Press, 1990.
[43]	王云,魏复盛.土壤环境元素化学[M]. 北京:中国环境科学出版社, 1995. Wang Y, Wei F S, Soil environmental element chemistry[M]. Beijing:China Environmental Press, 1995.
[44]	郝世祺,张生,李文宝,等.内蒙古中部达里湖沉积物粒度及营养盐垂直变化特征[J]. 盐湖研究, 2017,25(2):89-95. Hao S Q, Zhang S, Li W B, et al. The vertical variation characteristics of grain size and nutrients of sediments in Dali Lake, Central Inner Mongolia[J]. Journal of Salt Lake Research, 2017,25(2):89-95.
[45]	刘晶晶.近2400年以来达里诺尔湖区域植被系统演变及其关键驱动因子分析[D]. 呼和浩特:内蒙古农业大学, 2019. Li J J. Vegetation system evolution and snalysis of key drivers in Dali-nor Lake region since 2400 cal.a BP[D]. Huhehaote:Inner Mongolia Agricultural University, 2019.
[46]	Johnston R B, Singer P C. Solubility of symplesite (ferrous arsenate):Implications for reduced groundwaters and other geochemical environments[J]. Soil Science Society of America Journal, 2007, 71(1):101-107.
[47]	李云飞,何江,吕昌伟,等.达里诺尔湖表层沉积物中Hg、As的形态分布及释放特性[J]. 农业环境科学学报, 2014,33(11):2228-2233. Li Y F, He J, Lv C W, et al. Fractions and releases of mercury and arsenic in sediments of Dalinuoer Lake, China[J]. Journal of Agro-Environment Science, 2014,33(11):2228-2233.
[48]	杨富亿,文波龙,李晓宇,等.达里诺尔湿地水环境和鱼类多样性调查Ⅳ.达里湖水体中的污染物[J]. 湿地科学, 2021,19(2):154-161. Yang F Y, Wen B L, Li X Y, et al. Investigation of water environment and fish diversity in Dalinor wetlands IV. pollutants in the water of Dali Lake[J]. Wetland Science, 2021,19(2):154-161.