氮掺杂还原氧化石墨烯泡沫吸附/活化过硫酸盐协同去除双酚A的研究

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Abstract The nitrogen doped reduced graphene oxide foam (N-RGF) was prepared by hydrothermal method followed freeze-drying treatment using graphene oxide and ammonia as starting materials. The structure and surface physical-chemical properties of as-prepared catalysts were investigated and analysed by SEM, XRD, XPS, FT-IR, BET and TG techniques. The N-RGF was used to activate peroxydisulfate (PDS) for BPA removal via adsorption/degradation synergistically. The results showed that the N-RGF catalyst was a three-dimensional structure with average pore size(1~5μm). Its optimal preparation conditions were 6% nitrogen doping amount and hydrothermal treatment at 180℃ for 20h. The degradation rate constant of BPA over N-RGF activated PDS was 4.88 times than that over RGF activated PDS. Active species capture experiment and electron paramagnetic resonance (EPR) results showed that singlet oxygen (¹O₂) was the main contributor for BPA abatement. The four possible degradation intermediates were confirmed by ultra-high-performance liquid chromatography-mass spectrometry, and possible degradation pathway was proposed. The estrogenic activity of treated solution was reduced by MCF-7cell viability evaluation.

Key words： bisphenol A nitrogen-doped reduced graphene oxide foam peroxydisulfate activation adsorption

Received: 25 August 2022

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X703

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	Articles by authors
	HE Li-jin
	LONG Jun-hong
	JIN Hua-lei
	ZUO Yi-dan
	SONG Jie
	XIA Li-hong
	SHI Miao
	LUO Li-jun
	DAI Jian-hui

Cite this article:

HE Li-jin,LONG Jun-hong,JIN Hua-lei等. Removal of bisphenol A by nitrogen-doped reduced graphene oxide foam via adsorption/peroxydisulfate activation[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(3): 1107-1121.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I3/1107

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