微量铜离子联合碳酸氢盐类芬顿体系降解水中双酚A

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Abstract Higher Cu²⁺ dosage is typically needed for Fenton-like systems based on copper ions (Cu²⁺), which could result in secondary pollution. In the current study, an effective system for degrading bisphenol A(BPA) was built using bicarbonate-activated hydrogen peroxide and trace copper ions (Cu²⁺/H₂O₂/HCO₃^-). According to the findings, increasing the Cu²⁺ dosage boosted the removal efficiency of BPA, while increasing the H₂O₂ or HCO₃^- dosage caused the trend to grow initially before declining. BPA can be effectively removed within the range of the initial pH value of solution 5.06~11.02, and the degradation efficiency was improved with increased temperature. The presence of Cl^-、HPO₄^2- and humic acid (HA) were found to delayed the elimination of BPA, while other anions like NO₃^- and SO₄^2- had no obvious effects. Quenching and trapping experiments showed that the identified single oxygen and Cu³⁺ were the predominant reactive species responsible for BPA degradation. CuCO₃(aq) was the major complex with a high reactivity for H₂O₂ activation to form reactive oxygen species (ROS) and Cu³⁺. At the same time, there is a good removal effect of BPA in the natural water matrix of the Cu²⁺/H₂O₂/HCO₃^- system. In addition, the mechanism of possible degradation of BPA in Cu²⁺/H₂O₂/HCO₃^- has been proposed from the five identified intermediates.

Key words： bisphenol A trace copper bicarbonate hydrogen peroxide degradation

Received: 07 July 2022

PACS:

X703.1

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	Articles by authors
	XIN Li-hong
	YAN Cai-xia
	NIE Ming-hua
	ZHANG Yi-min
	YUAN Yu-long
	DING Ming-jun
	WANG Peng

Cite this article:

XIN Li-hong,YAN Cai-xia,NIE Ming-hua等. Degradation of bisphenol A by Fenton-like system using trace copper ions combined with bicarbonate in water[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(3): 1186-1196.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I3/1186

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