长江下游典型城市江段有机氮磷识别及传输路径

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Abstract The study investigated water samples from eight sampling sites along the main urban river path, tributaries, and the merger of ditch gates of the lower course of the Yangtze basin. The profiles, sources and transport pathways of nitrogen, phosphorus, and related organic pollutants in the selected part of the river were analyzed using high-throughput non-targeted screening technology combined with multivariate statistical analysis. A total of sixty organic pollutants were identified in the research area including eleven organic nitrogen compounds, such as aminomethanesulphonic acid, carbamide, and benzonitrile, and two organic phosphorus compounds, 4-hydroxyphenylphosphonic acid and trimethyl thiophosphate. Most of the discharges were from the production of pharmaceuticals and pesticides, the daily use of pharmaceuticals and personal care products, and the manufacturing of raw and auxiliary materials. The chemicals travelled down the watershed via three routes, dominated by inorganic phosphorus transport with certain amount of organonitrogen involved, dominated by organonitrogen transport with certain amount of organophosphorus involved, or dominated by the transport of organonitrogen in combine with organophosphorus compounds. The inflow of the screened organics was predominantly influenced by hydrological factors and consistent with the water flow direction. The source apportionment from upstream inflow and regional input needs to be considered as well.

Key words： organic fingerprinting non-targeted screening gas chromatography-mass spectrometer traceability of organic nitrogen and phosphorus pollutions

Received: 28 November 2022

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X522

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	Articles by authors
	YU Ming-xing
	SU Hai
	LI Ming-yang
	WU Xiao-jian
	ZHANG Kai
	MA Pan
	MA Yu-ning
	HU Guan-jiu

Cite this article:

YU Ming-xing,SU Hai,LI Ming-yang等. Analysis of recognition and transmission path for organic nitrogen and phosphorus pollutants in representative cities section of lower Yangtze River[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(7): 3604-3615.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I7/3604

[1]	GB 3838-2002 地表水环境质量标准 [S]. GB 3838-2002 Environmental quality standard for surface water [S].
[2]	陈善荣,何立环,张凤英,等.2016~2019年长江流域水质时空分布特征 [J]. 环境科学研究, 2020,33(5):1100-1108. Chen X R, He L H, Zhang F Y, et al. Spatiotemporal characteristics of surface water quality of the Yangtze River Basin during 2016~2019 [J]. Research of Environmental Sciences, 33(5):1100-1108.
[3]	朱岩,曹莹,张亚辉,等.有机磷农药对锯齿新米虾的毒性及敏感性分析 [J]. 中国环境科学, 2017,37(2):745-753. Zhu Y, Cao Y, Zhang Y H, et al. Toxicity of organophosphorus pesticides to neocaridina denticulate and species sensitivity analysis [J]. China Environmental Science, 2017,37(2):745-753.
[4]	吴丰昌,金相灿,张润宇,等.论有机氮磷在湖泊水环境中的作用和重要性 [J]. 湖泊科学, 2010,22(1):1-7. Wu F C, Jin X C, Zhang R Y, et al. Effects and significance of organic and phosphorous in the lake aquatic environment [J]. Journal of Lake Science, 2010,22(1):1-7.
[5]	Chuang Y, Lin A Y, Wang X, et al．The contribution of dissolved organic nitrogen and chloramines to nitrogenous disinfection byproduct formation from natural organic matter [J]. Water Reasch, 2013,47(3):1308-1316.
[6]	曾佳敏,钟仕花,钱伟,等.水环境中有机磷酸酯的污染现状及其生物毒性 [J]. 中国环境科学, 2021,41(9):4388-4401. Ceng J M, Zhong S H, Qian W, et al, Pollution status and ecotoxicity of organophosphate esters (OPEs) in aquatic environment [J]. China Environmental Science, 2021,41(9):4388-4401.
[7]	卢宁,刘茵.长江口原水中溶解性有机氮类化合物分析 [J]. 人民长江, 2013,44(21):104-107. Lu N, Liu Y. Analysis on dissolved organic nitrogen (DON) in the raw water of Yangtze River Estuary [J]. Yangtze River, 2013,44(21):104-107.
[8]	魏俊峰,陈洪涛,刘鹏霞,等.长江悬浮颗粒物中磷的赋存形态 [J]. 水科学进展, 2010,21(1):107-112. Wei J F, Chen H T, Liu P X, et al. Phosphorus forms in suspended particulate matter of the Yangtze River [J]. Advance in Water Science, 2010,21(1):107-112.
[9]	李敏慧,荆立,朱彦君,等.基于改进型遗传算法的水质溯源问题 [J]. 河海大学学报(自然科学版), 2018,46(5):402-407. Li M H, Jin L, Zhu Y J, et al. Research on the water source identification based on an improved genetic algorithm [J]. Journal of Hohai University ( Natural Sciences), 2018,46(5):402-407.
[10]	姜继平,董芙嘉,刘仁涛,等.基于河流示踪实验的Bayes污染溯源:算法参数、影响因素及频率法对比 [J]. 中国环境科学, 2017,37(10): 3813-3825. Jiang J P, Dong F J, Liu R T, et al. Applicability of Bayesian inference approach for pollution source identification of river chemical spills: a tracer experiment based analysis of algorithmic parameters, impacts and comparison with Frequentist approaches [J]. China Environmental Science, 2017,37(10):3813-3825.
[11]	王家鑫,张明军,张宇,等.基于稳定同位素示踪的黄河兰州段河漫滩土壤水特征分析 [J]. 干旱区地理, 2021,44(5):1449-1458. Wang J X, Zhang M J, Zhang Y, et al. Soil water characteristics analysis of floodplain in the Yellow River reach of Lanzhou based on stable isotopes tracing [J]. Arid Land Geography, 2021,44(5):1449-1458.
[12]	傅雪梅,孙源媛,苏婧等.基于水化学和氮氧双同位素的地下水硝酸盐源解析 [J]. 中国环境科学, 2019,39(9):3951-3958. Fu X M, Sun Y Y, Su J, et al. Source of nitrate in groundwater based on hydrochemical and dual stable isotopes [J]. China Environmental Science, 2019,39(9):3951-3958.
[13]	智国铮.三维荧光光谱技术在水环境中的研究与应用进展 [J]. 四川环境, 2021,40(5):257-261. Zhi G Z. Research progress and application of three dimensional fluorescence spectra technique in water environment [J]. Sichuan Environment, 2021,40(5):257-261.
[14]	Viviano G, Valsecchi S, Polesello S, et al. Combined use of caffeine and turbidity to evaluate the impact of CSOs on river water quality. Water Air Soil Pollution, 2017,228(9):330.
[15]	Yang Y Y, Zhao J L, Liu Y S, et al. Pharmaceuticals and personal care products (PPCPs) and artificial sweeteners (ASs) in surface and ground waters and their application as indication of wastewater contamination [J]. Science of the Total Environment, 2017,616-671: 816-823.
[16]	Du B W, Price A E, Scott W C, et al. Comparison of contaminants of emerging concern removal, discharge, and water quality hazards among centralized and on-site wastewater treatment system effluents receiving common wastewater influent [J]. Science of the Total Environemnt, 2014,466-467(1):976-984.
[17]	Lin A Y, Tsai Y T. Occurrence of pharmaceuticals in Taiwan's surface waters: impact of waste streams from hospitals and pharmaceutical production facilities [J]. Science of the Total Environment, 2009, 407(12):3793-3802.
[18]	Fairbairn D J, Karpuzcu M E, Arnold W A, et al. Sources and transport of contaminants of emerging concern: a two-year study of occurrence and spatiotemporal variation in a mixed land use watershed [J]. Science of the Total Environment, 2016,551-552(3):605-613.
[19]	余明星,苏海,张凯,等.基于有机物指纹图谱技术的长江南京段水中有机磷溯源研究 [J]. 环境监控与预警, 2022,14(5):100-106. Yu M X, Su H, Zhang K, et al. Research on tracing organophosphorus in Nanjing section of Yangtze River based on fingerprint technology of organic compounds [J]. Environment Monitoring and Forewarning [J]. 2022,14(5):100-106.
[20]	Shrestha S, Kazama F. Assessment of surface water quality using multivariate statistical techniques: a case study of the Fuji River basin, Japan [J]. Environmental Modelling & Software, 2007,22(4):464-475.
[21]	HJ 494-2009 水质采样技术指导 [S]. HJ 494-2009 Water quality-guidance on sampling techniques [S].
[22]	国家环境保护总局《水和废水监测分析方法》编委会.水和废水监测分析方法(第四版) [M]. 北京:中国环境科学出版社, 2002:223-224. Editorial Board of Monitoring and Analysis Methods of Water and Wastewater of State Environmental Protection Administration. Monitoring and analysis methods of water and wastewater (the 4th edition) [M]. Beijing: China Environmental Science Press, 2002:223-224.
[23]	Pokhrel P K, Laucam C A. In vitro and in vivo effects of taurine and structurally related sulfur-containing compounds against phenylhydrazine-induced oxidative damage to erythrocytes [J]. Advances in Experimental Medicine and Biology, 2002,483:503-522.
[24]	巨晓棠,刘学军,张福锁.尿素与DCD和有机物料配施条件下氮素的转化和去向 [J]. 中国农业科学, 2002,(2):181-186. Ju X T, Liu X J, Zhang F S. Nitrogen transformation and fate in soil under the conditions of mixed application of urea with DCD or different organic materials [J]. Scientia Agricultura Sinica, 2002,(2): 181-186.
[25]	徐保明,阮华屹,周云,等.苯甲腈类化合物的合成研究进展 [J]. 化学世界, 2012,53(5):316-320. Xu B M, Ruan H Y, Zhou Y, et al. Research progress on the synthesis of the benzonitrile compounds [J]. Chemical World, 2012,53(5): 316-320.
[26]	王斌,彭乔,刘淑坤. 2-甲基咪唑啉在海水及在海洋大气环境下缓蚀性能的研究[J].全面腐蚀控制, 2004,(2):29-31. Wang B, Peng Q, Liu S K. The study on corrosion inhibiting ability of 2-methylimidazoline in seawater and sea atmosphere [J]. Total Corrosion Control, 2004,(2):29-31.
[27]	谷振超,邬东,陈莉荣. UV/H2O2对化工废水中2,6-二氯吡啶的降解研究 [J]. 湖南大学学报(自然科学版), 2021,48(2):132-140. Gu Z G, Wu D, Chen L R. Study on degradation of 2,6-dichloropyridine in chemical wastewater by UV/H2O2 [J]. Journal of Hunan University (Natural Science), 2021,48(2):132-140.
[28]	Peruga A, Beltrán J, López F, et al. Determination of methylisothiocyanate in soil and water by HS-SPME followed by GC-MS/MS with a triple quadrupole [J]. Analytical and Bioanalytical Chemistry, 2014,406(22):5271-5282.
[29]	余毅,艾秋红,罗和安.相转移催化法合成2,3,5-三氯吡啶的工艺研究 [J]. 化工中间体, 2007,(1):25-28. Yu Y, Ai Q H, Luo H A. Synthesis of 2,3,5-trichloropyridine using phase transfer catalyst [J]. Chemical Intermediate, 2007,(1):25-28.
[30]	刘艳娜.含氯芳香族化合物电化学脱氯机理的原位红外光谱研究 [D]. 浙江:浙江工业大学, 2009. Liu Y N. Study on electrochemical dichlorination of aromatic componds by in situ FTIR spectroscopy [D]. Zhejiang: Zhejiang University of Technology, 2009.
[31]	Chae E J, Jung U, Choi S S. Quantification of tire tread wear particles in microparticles produced on the road using oleamide as a novel marker [J]. Environmental Pollution, 2021,288(1):117811.
[32]	Nizamov I S, Sergeenko G G, Popovich A E, et al. Organic phosphorus-suflur compounds derived from 1,3,2λ5,4λ5-dithiaphosphetane 2,4-disulfides. synthesis and properties [J]. Russian Journal of General Chemistry, 2002,72(9):1356-1366.
[33]	钱柯伟,徐芸,邵生富,等.一种副产物硫代磷酸三甲酯分离与提纯的方法:中国, CN102060871A [P]. 2013-07-03. Qian K W, Xu Y, Shao S F, et al. A method of separation and purification of by-product trimethyl thiophosphate: China, CN102060871A [P]. 2013-07-03.
[34]	Klop G, Dijkstra J, Dieho K, et al. Changes in in vitro gas and methane production from rumen fluid from dairy cows during adaptation to feed additives in vivo [J]. Animal, 2017,11(4):591-599.
[35]	李芳芳,陈明华,张婉萍.脂肪酸皂体系的相行为及其稳定性研究 [J]. 日用化学工业, 2015,45(12):661-669. Li F F, Chen M H, Zhang W P, et al. Phase behavior and stability of fatty acid soap systems [J]. China Surfactant Detergent & Cosmetics, 2015,45(12):661-669.
[36]	梅雪冰,隋倩,张紫薇,等.不同特征污染源中指示性药物和个人护理品识别与筛选 [J]. 中国环境科学, 2019,39(3):1173-1180. Mei X B, Sui Q, Zhang Z W, et al. Identification of indicator pharmaceutical and personal care products (PPCPs) in different emission sources [J]. China Environmental Science, 2019,39(3):1173-1180.
[37]	张施慧,王韶旭,李毅妮,等.正十九烷/二氧化硅定形复合相变材料的制备、表征及储热性能 [J]. 大连交通大学学报, 2014,35(S1):156-160. Zhang S H, Wang S X, Li Y N, et al. Preparation characterization and thermal properties of N-Nonadecane/Silicon dioxide composite as shape-stabilized phase change material [J]. Journal of Dalian University, 2014,35(S1):156-160.
[38]	周婷婷.甲基氯硅烷副产低沸物分析和四甲基硅烷提取方法的研究 [D]. 浙江:浙江大学, 2010. Zhou T T. Study on analysis of the low-boiling residues of methylchlorosilanes and extraction of tetramethylsilane [D]. Zhejiang: Zhejiang University, 2010.
[39]	贺玉刚,万烨,常欣,等.高纯四甲基硅烷合成工艺及提纯技术 [J]. 化工新型材料, 2021,49(6):262-264. He Y G, Wan Y, Chang X, et al. Synthesis and purification technology of high-purity tetramethylsilane [J]. New Chemical Materials, 2021, 49(6):262-264.
[40]	刘妙丽.水中苯和甲苯挥发速率的研究 [J]. 四川师范大学学报(自然科学版), 2007,30(5):660-662. Liu M L. Study on the vaporization Velocity of benzene and toluene in water [J]. Journal of Sichuan Normal University (Natural Science), 2007,30(5):660-662.
[41]	叶潇.基于实测的非道路移动源、生物质锅炉污染物排放特征研究 [D]. 广东:华南理工大学, 2018. Ye X. Study on characteristics of pollutants emission from non-road mobile source and biomass boilers on real work conditions [D]. Guangdong: South China University of Technology Guangzhou, China, 2018.
[42]	潘劲松,王玉禄,苏俊杰,等.氨基甲磺酸的高效简便合成 [J]. 山东化工, 2019,48(10):27-28. Pan J S, Wang Y L, Su J J, et al. The Convenient and efficient synthesis of aminomethanesulfonic acid [J]. Shandong Chemical Industry, 2019,48(10):27-28.
[43]	蒋博龙,史顺杰,蒋海林,等.金属有机框架材料吸附处理苯酚污水机理研究进展 [J]. 化工进展, 2021,40(8):4525-4539. Jiang B L, Shi S J, Jiang H L, et al. Research progress in phenol adsorption mechanism over metal-organic framework from wastewater [J]. Chemical Industry and Engineering Progress, 2021, 40(8):4525-4539.
[44]	徐斌,高乃云,芮旻,等.饮用水中内分泌干扰物双酚A的臭氧氧化降解研究 [J]. 环境科学, 2006,272(2):294-299. Xu B, Gao N Y, Rui M, et al. Degradation of endocrine disruotor bisphenol A in drinking water by ozone oxidation [J]. Environmental Science, 2006,272(2):294-299.
[45]	李青倩,袁鹏,杨鹊平,等.长江水系氮磷生态化学计量学空间变化特征及影响因素 [J]. 环境工程技术学报, 2022,12(2):573-580. Li Q Q, Yuan P, Yang Q P, et al. Spatial variation characteristics and influencing factors of nitrogen and phosphorus ecological stoichiometry in the Yangtze River system [J]. Journal of Environmental Engineering Technology, 2022,12(2):573-580.
[46]	王超,贾庆林,裴中平,等.南水北调中线总干渠典型渠段水体自净能力研究 [J]. 南水北调与水利科技(中英文), 2020,18(3):127-141. Wang C, Jia Q X, Pei Z P, et al. Study on water self-purification capacity of a typical section of the main channel in the middle route of South-to-North Water Transfer Project [J]. South-to-North Water Transfers and Water Science & Technology, 2020,18(3):127-141.
[47]	张步云,韩玉洁,杨琳.藻类植物在水体污染中的研究进展 [J]. 资源节约与环保, 2019,(8):118-120. Zhang B Y, Han Y J, Yang L. et al. Research progress of algae plants in water pollution [J]. Resource Conservation and Environmental Protection, 2019,(8):118-120.
[48]	邵海洋.上海市水体和沉积物中半挥发性有机物污染水平、来源分析和风险评估 [D]. 上海:上海大学, 2018. Shao H Y. Distribution, sources, and risk assessment of semi-volatile organic compounds in water and sediment of Shanghai [D]. Shanghai: Shanghai University, 2018.