掺氮石油焦基活性炭常温催化氧化硫化氢研究

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (2529 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract A novel nitrogen-doped porous carbon was successfully prepared using petroleum coke as the carbon source and the solid waste from melamine production as the nitrogen source. The catalyst exhibited excellent H₂S catalytic oxidation capacity in room temperature with a breakthrough sulfur capacity of 398.4mg/g. Three process parameters, namely, the amount of activator, nitrogen doping temperature and nitrogen source, changed the specific surface, N configuration and N content of the catalysts, respectively, during the preparation process. By optimizing the process conditions, the highest reactive center, pyridine N, could be achieved at 2.88at.%. Compared with the catalyst prepared using traditional raw material, it achieves waste utilization and green preparation. The results of this paper provide a new approach for the preparation of porous carbon materials with low cost and high breakthrough sulfur capacity.

Key words： hydrogen sulfide nitrogen doping activated carbon catalytic oxidation petroleum coke

Received: 22 February 2023

PACS:

X701

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHENG Hao-ming
	ZHU Wen-fu
	LUO Ying-hong
	WANG Zi-kun
	LIU Mei-yin
	HUANG Hao-min
	YE Dai-qi
	LI Hong-xiang
	WU Jun-liang

Cite this article:

ZHENG Hao-ming,ZHU Wen-fu,LUO Ying-hong等. Preparation of nitrogen-doped petroleum coke based activated carbon and its performance in catalytic oxidation of hydrogen sulfide at room temperature[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(9): 4550-4560.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/I9/4550

[1]	Yan R, Chin T, Ng Y L, et al. Influence of surface properties on the mechanism of H2S removal by alkaline activated carbons[J]. Environmental Science & Technology, 2004,38(1):316-323.
[2]	Yang C, Wang Y, Fan H, et al. Bifunctional ZnO-MgO/activated carbon adsorbents boost H2S room temperature adsorption and catalytic oxidation[J]. Applied Catalysis B:Environmental, 2020,266.
[3]	庄荣玉,王磊刚,李美燕,等.异养菌与新型填料成膜性及BTF处理屠宰H2S废气[J]. 中国环境科学, 2020,40(3):1106-1115. Zhuang Y Y, Wang L G, Li M Y, et al. Biofilm formation of a heterotrophic bacterium on the novel packing material and the removal of hydrogen sulfide produced in a slaughtering process by biotrickling filter[J]. China Environmental Science, 2020,40:1106-1115.
[4]	Beauchamp R O, Bus J S, Popp J A, et al. A critical review of the literature on hydrogen sulfide toxicity[J]. Critical Reviews In Toxicology, 1984,13(1):25-97.
[5]	王亘,翟增秀,耿静,等.40种典型恶臭物质嗅阈值测定[J]. 安全与环境学报, 2015,15(6):348-351. Wang G, Zhai Z H, Geng J, et al. Testing and determination of the olfactory thresholds of the 40kinds of typical malodorous substances[J]. Journal of Safety and Environment, 2015,15:348-351.
[6]	Masi A d, Ascenzi P. H2S:a "double face" molecule in health and disease[J]. Biofactors, 2013,39(2):186-196.
[7]	Garcia-Arriaga V, Alvarez-Ramirez J, Amaya M, et al. H2S and O2 influence on the corrosion of carbon steel immersed in a solution containing 3M diethanolamine[J]. Corrosion Science, 2010,52(7):2268-2279.
[8]	Xu Z Y, Zhao W B, Xie X H, et al. Liquid-liquid phase-change absorption of hydrogen sulfide by superbase 1,8-diazabicyclo[5.4.0] undec-7-ene and its chemical regeneration[J]. Separation and Purification Technology, 2020,250:117244.
[9]	Gu J, Shao P, Luo L, et al. Microporous triazine-based ionic hyper-crosslinked polymers for efficient and selective separation of H2S/CH4/N2[J]. Separation and Purification Technology, 2022,285:120377.
[10]	Hao J, Rice P A, Stem S A. Upgrading low-quality natural gas with H2S and CO2selective polymer membranes Part I. Process design and economics of membrane stages without recycle streams[J]. Journal of Membrane Science, 2002,209(1):177-206.
[11]	Dobslaw D, Ortlinghaus O. Biological waste air and waste gas treatment:Overview, challenges, operational efficiency, and current trends[J]. Sustainability, 2020,12(20):8577.
[12]	Yang C, Yang S, Fan H L, et al. A sustainable design of ZnO-based adsorbent for robust H2S uptake and secondary utilization as hydrogenation catalyst[J]. Chemical Engineering Journal, 2020,382.
[13]	Zheng X H, Li Y L, Zheng Y, et al. Highly efficient porous FexCe1-xO2-delta with three-dimensional hierarchical nanoflower morphology for H2S-selective oxidation[J]. ACS Catalysis, 2020, 10(7):3968-3983.
[14]	Khabazipour M, Anbia M. Removal of hydrogen sulfide from gas streams using porous materials:A review[J]. Industrial & Engineering Chemistry Research, 2019,58(49):22133-22164.
[15]	Adib F, Bagreev A, Bandosz T J. Effect of surface characteristics of wood-based activated carbons on adsorption of hydrogen sulfide[J]. Journal of Colloid and Interface Science, 1999,214(2):407-415.
[16]	Adib F, Bagreev A, Bandosz T J. Adsorption/oxidation of hydrogen sulfide on nitrogen-containing activated carbons[J]. Langmuir, 1999, 16(4):1980-1986.
[17]	Adib F, Bagreev A, Bandosz T J. Analysis of the relationship between H2S removal capacity and surface properties of unimpregnated activated carbons[J]. Environmental Science & Technology, 2000, 34(4):686-692.
[18]	Zhang Z X, Wang J T, Li W C, et al. Millimeter-sized mesoporous carbon spheres for highly efficient catalytic oxidation of hydrogen sulfide at room temperature[J]. Carbon, 2016,96:608-615.
[19]	Yang C, Yang S, Fan H, et al. Tuning the ZnO-activated carbon interaction through nitrogen modification for enhancing the H(2)S removal capacity[J]. Journal of Colloid and Interface Science, 2019, 555:548-557.
[20]	Yu Z F, Wang X Z, Song X D, et al. Molten salt synthesis of nitrogen-doped porous carbons for hydrogen sulfide adsorptive removal[J]. Carbon, 2015,95:852-860.
[21]	Sun F G, Liu J, Chen H C, et al. Nitrogen-rich mesoporous carbons:highly efficient, regenerable metal-free catalysts for low-temperature oxidation of H2S[J]. ACS Catalysis, 2013,3(5):862-870.
[22]	Wang X T, Ouyang T, Wang L, et al. Surface reorganization on electrochemically-induced Zn-Ni-Co spinel oxides for enhanced oxygen electrocatalysis[J]. Angewandte Chemie International Edition, 2020,59(16):6492-6499.
[23]	Ren J T, Wan C Y, Pei T Y, et al. Promotion of electrocatalytic nitrogen reduction reaction on N-doped porous carbon with secondary heteroatoms[J]. Applied Catalysis B:Environmental, 2020,266.
[24]	Dlamini M W, Phaahlamohlaka T N, Kumi D O, et al. Post doped nitrogen-decorated hollow carbon spheres as a support for Co Fischer-Tropsch catalysts[J]. Catalysis Today, 2020,342:99-110.
[25]	王莹,魏成耀,黄天寅,等.氮掺杂碳纳米管活化过一硫酸盐降解酸性橙AO7[J]. 中国环境科学, 2017,37(7):2583-2590. Wang Y, Wei C Y, Huang T Y, et al. Activation of peroxymonosulfate by nitrogen-doped carbon nanotubes to decolorize acid orange 7[J]. China Environmental Science, 2017,37:2583-2590.
[26]	陈爱侠,关娟娟,卫潇,等.同步活化氮掺杂海藻酸钠基多孔碳制备及对双酚A的高效吸附[J]. 中国环境科学, 2002,42(1):160-171. Chen A X, Guan J J, Wei X, et al. Efficient adsorption of BPA by alginate-based porous carbon with the preparation of synchronous activation and nitrogen doping[J]. China Environmental Science, 2002,42:160-171.
[27]	Wu J, Chen W, Chen L, et al. Super-high N-doping promoted formation of sulfur radicals for continuous catalytic oxidation of H2S over biomass derived activated carbon[J]. Journal of Hazardous Materials, 2022,424(Pt D):127648.
[28]	Chen W H, Zhang G C, Li D, et al. Preparation of nitrogen-doped porous carbon from waste polyurethane Foam by hydrothermal carbonization for H2S adsorption[J]. Industrial & Engineering Chemistry Research, 2020,59(16):7447-7456.
[29]	Xiao Y, Pudasainee D, Gupta R, et al. Bromination of petroleum coke for elemental mercury capture[J]. Journal of Hazardous Materials, 2017,336:232-239.
[30]	Wu J, Montes V, Virla L D, et al. Impacts of amount of chemical agent and addition of steam for activation of petroleum coke with KOH or NaOH[J]. Fuel Processing Technology, 2018,181:53-60.
[31]	钟悦之,宋晓晖,王彦超,等.中国平板玻璃行业大气污染物排放特征研究[J]. 中国环境科学, 2018,38(12):4451-4459. Zhong Y Z, Song X H, Wang Y C, et al. Emission characteristics from flat-glass industry in China[J]. China Environmental Science, 2018, 38(12):4451-4459.
[32]	Yang M L, Guo L P, Hu G S, et al. Adsorption of CO2 by petroleum coke nitrogen-doped porous carbons synthesized by combining ammoxidation with KOH activation[J]. Industrial & Engineering Chemistry Research, 2016,55(3):757-765.
[33]	Yang J, Yue L M, Lin B B, et al. CO2 adsorption of nitrogen-doped carbons prepared from nitric acid preoxidized petroleum Coke[J]. Energy & Fuels, 2017,31(10):11060-11068.
[34]	Zhu W, Wang Y, Yao F, et al. One-pot synthesis of N-doped petroleum coke-based microporous carbon for high-performance CO2 adsorption and supercapacitors[J]. Journal of Environmental Sciences, 2024, 139:93-104.
[35]	Chen L, Yuan J, Li T, et al. A regenerable N-rich hierarchical porous carbon synthesized from waste biomass for H2S removal at room temperature[J]. Science of the Total Environment, 2021,768:144452.
[36]	Kazmierczak-Razna J, Gralak-Podemska B, Nowicki P, et al. The use of microwave radiation for obtaining activated carbons from sawdust and their potential application in removal of NO2 and H2S[J]. Chemical Engineering Journal, 2015,269:352-358.
[37]	Chen L, Jiang X, Chen W, et al. H2O2-assisted self-template synthesis of N-doped biochar with interconnected mesopore for efficient H2S removal[J]. Separation and Purification Technology, 2022.
[38]	Surra E, Costa Nogueira M, Bernardo M, et al. New adsorbents from maize cob wastes and anaerobic digestate for H2S removal from biogas[J]. Waste Management, 2019,94:136-145.
[39]	Sun M, Wang X, Li Y, et al. Integration of desulfurization and lithium-sulfur batteries enabled by amino-functionalized porous carbon nanofibers[J]. Energy & Environmental Materials, 2023,6(2):e12349.
[40]	Klein J, Henning K-D. Catalytic oxidation of hydrogen sulphide on activated carbons[J]. Fuel, 1984,63(8):1064-1067.
[41]	Le Leuch L M, Subrenat A, Le Cloirec P. Hydrogen sulfide adsorption and oxidation onto activated carbon cloths:Applications to odorous gaseous emission treatments[J]. Langmuir, 2003,19(26):10869-10877.
[42]	Huang Y, Wang J, Ma S, et al. A confined MoN2@N-rich carbon catalyst derived from β-cyclodextrin encapsulating phosphomolybdic acid for oxidative removal of H2S[J]. Chemical Engineering Journal, 2023,457.
[43]	Bandosz T J. On the adsorption/oxidation of hydrogen sulfide on activated carbons at ambient temperatures[J]. Journal of Colloid and Interface Science, 2002,246(1):1-20.
[44]	Lillo-Rodenas M A, Cazorla-Amoros D, Linares-Solano A. Understanding chemical reactions between carbons and NaOH and KOH:An insight into the chemical activation mechanism[J]. Carbon, 2003,41(2):267-275.
[45]	Lin G, Ma R, Zhou Y, et al. KOH activation of biomass-derived nitrogen-doped carbons for supercapacitor and electrocatalytic oxygen reduction[J]. Electrochimica Acta, 2018,261:49-57.
[46]	Zhu X, Zhang L, Zhang M, et al. Effect of N-doping on NO2 adsorption and reduction over activated carbon:An experimental and computational study[J]. Fuel, 2019,258:116109.
[47]	Li S Y, Liu Y F, Gong H M, et al. N-doped 3D mesoporous carbon/carbon nanotubes monolithic catalyst for H2S selective oxidation[J]. ACS Applied Nano Materials, 2019,2(6):3780-3792.
[48]	Chen Q J, Wang Z, Long D H, et al. Role of pore structure of activated carbon fibers in the catalytic oxidation of H2S[J]. Industrial & Engineering Chemistry Research, 2010,49(7):3152-3159.
[49]	Wang S, Wang Y, Zhang S L, et al. Supporting ultrathin ZnIn2S4 nanosheets on Co/N-doped graphitic carbon Nanocages for efficient photocatalytic H2 generation[J]. Advanced Materials, 2019,31(41):e1903404.
[50]	Wu Y, Cao J P, Zhuang Q Q, et al. Biomass-derived three-dimensional hierarchical porous carbon network for symmetric supercapacitors with ultra-high energy density in ionic liquid electrolyte[J]. Electrochimica Acta, 2021,371.
[51]	Ning H, Guo D L, Wang X S, et al. Efficient CO2 electroreduction over N-doped hieratically porous carbon derived from petroleum pitch[J]. Journal of Energy Chemistry, 2021,56:113-120.
[52]	孙鹏,柳佳鹏,王维大,等.活性炭强化热活化过硫酸盐降解对硝基苯酚[J]. 中国环境科学, 2020,40(11):4779-4785. Sun P, Liu J P, Wang W D, et al. Active carbon enhanced thermal activation of persulfate for degradation of p-nitrophenol[J]. China Environmental Science, 2020,40:4779-4785.
[53]	Zhang W L, Sun H X, Zhu Z Q, et al. N-doped hard carbon nanotubes derived from conjugated microporous polymer for electrocatalytic oxygen reduction reaction[J]. Renewable Energy, 2020,146:2270-2280.
[54]	Li D, Chen W H, Wu J P, et al. The preparation of waste biomass-derived N-doped carbons and their application in acid gas removal:focus on N functional groups[J]. Journal of Materials Chemistry A, 2020,8(47):24977-24995.
[55]	Xiong W, Wang Z N, He S L, et al. Nitrogen-doped carbon nanotubes as a highly active metal-free catalyst for nitrobenzene hydrogenation[J]. Applied Catalysis B:Environmental, 2020,260.
[56]	Leng L, Xu S, Liu R, et al. Nitrogen containing functional groups of biochar:An overview[J]. Bioresource Technology, 2020,298:122286.
[57]	Yu W, Lian F, Cui G, et al. N-doping effectively enhances the adsorption capacity of biochar for heavy metal ions from aqueous solution[J]. Chemosphere, 2018,193:8-16.
[58]	Zhang J, Xia Z, Dai L. Carbon-based electrocatalysts for advanced energy conversion and storage[J]. Science Advances, 2015,1(7):e1500564.
[59]	Guo D, Shibuya R, Akiba C, et al. Active sites of nitrogen-doped carbon materials for oxygen reduction reaction clarified using model catalysts[J]. Science, 2016,351(6271):361-365.
[60]	Li J, Yin S, Dong F, et al. Tailoring active sites via synergy between graphitic and pyridinic N for enhanced catalytic efficiency of a Carbocatalyst[J]. ACS Applied Materials & Interfaces, 2017,9(23):19861-19869.
[61]	Adib F, Bagreev A, Bandosz T J. On the possibility of water regeneration of unimpregnated activated carbons used as hydrogen sulfide adsorbents[J]. Industrial & Engineering Chemistry Research, 2000,39(7):2439-2446.
[62]	Bagreev A, Bandosz T J. H2S adsorption/oxidation on unmodified activated carbons:importance of prehumidification[J]. Carbon, 2001,39(15):2303-2311.
[63]	Tuerhong T, Kuerban Z. Preparation and characterization of cattle manure-based activated carbon for hydrogen sulfide removal at room temperature[J]. Journal of Environmental Chemical Engineering, 2022,10(2):107177.