|
|
Effects of carbonization intensity on dewatering performance of municipal sludge and characteristics of lysate——based on Ruyter model |
KONG Xin1, HOU Yun2, GUO Yan-feng3, LI Rui-yun4, BAI Heng4, YUAN Jin1 |
1. School of Environmental Science and Engineering, Taiyuan University of Technology, Jinzhong 030600, China; 2. Taiyuan Water Supply Group Co. Ltd., Taiyuan 030009, China; 3. Beijing Branch, North China Municipal Engineering Design & Research Institute Co. Ltd., Beijing 100044, China; 4. Shanxi Lipu Innovation Technology Co. Ltd., Jinzhong 030600, China |
|
|
Abstract The study used Ruyter model and proposes index of ‘carbonization intensity’. On the basis of the index, the coupling effects of both carbonization temperature and carbonization time on dewaterability of sludge and physicochemical characteristics of produced lysate were analyzed. Furthermore, the mechanism of dewatering performance improvement by hydrothermal carbonization was illustrated as well. Results show that in the lab condition, at the carbonization intensity of higher than 0.12, the water content of treated sludge reduced to 55% after suction filtration, which reached to the level of self-sustaining combustion. The reason for good dewatering performance was due to a series of reactions of macromolecular substances (eg. protein or polysaccharide) under a certain carbonization intensity, such as hydrolysis, polycondensation, decarboxylation. However, in an excessive high carbonization intensity condition (0.21), the degree of aromatization was deepened, which resulted in worse biodegradability of lysate.
|
Received: 13 April 2023
|
|
|
|
|
[1] |
Schnell M, Horst T, Quicker P. Thermal treatment of sewage sludge in Germany:A review [J]. Journal of Environmental Management, 2020, 263:110367.
|
[2] |
陈思思,杨殿海,庞维海,等.我国剩余污泥厌氧转化的主要影响因素及影响机制研究进展[J]. 化工进展, 2020,39(4):1511-1520. Chen S S, Yang D H, Pang W H, et al. Main influencing factors and mechanisms of anaerobic transformation of excess sludge in China [J]. Chemical Industry and Engineering Progress, 2020,39(4):1511-1520.
|
[3] |
郝晓地,于文波,时琛,等.污泥焚烧灰分磷回收潜力分析及其市场前景[J]. 中国给水排水, 2021,37(4):5-10. Hao X D, Yu W B, Shi C, et al. Potential analysis and market prospects of phosphorus recovery from the bottom ashes of sludge incineration [J]. China Water & Wastewater, 2021,37(4):5-10.
|
[4] |
戴晓虎,张辰,章林伟,等.碳中和背景下污泥处理处置与资源化发展方向思考[J]. 给水排水, 2021,57(3):1-5. Dai X H, Zhang C, Zhang L W, et al. Thoughts on the development direction of sludge treatment and resource recovery under the background of carbon neutrality [J]. Water &Wastewater Engineering, 2021,57(3):1-5.
|
[5] |
Wang Z, Zhai Y, Wang T, et al. Effect of temperature on the sulfur fate during hydrothermal carbonization of sewage sludge [J]. Environmental Pollution, 2020,260:114067.
|
[6] |
许劲,徐军,吕秋颖,等.水热碳化技术用于污泥处理处置前景分析[J]. 中国给水排水, 2020,36(16):54-59. Xu J, Xu J, Lv Q Y, et al. Perspectives on hydrothermal carbonization technology for municipal sludge treatment and disposal [J]. China Water & Wastewater, 2020,36(16):54-59.
|
[7] |
Wang L, Chang Y, Li A. Hydrothermal carbonization for energy-efficient processing of sewage sludge:A review [J]. Renewable and Sustainable Energy Reviews, 2019,108:423-440.
|
[8] |
Shi Y, Luo G, Rao Y, et al. Hydrothermal conversion of dewatered sewage sludge:Focusing on the transformation mechanism and recovery of phosphorus [J]. Chemosphere, 2019,228:619-628.
|
[9] |
宋宪强,叶泽鹏,周锡武.低温水热处理改善城市污泥理化性质及脱水性能[J]. 中国给水排水, 2019,35(17):26-30. Song X Q, Ye Z P, Zhou X W. Improving physical-chemical properties and dewaterability of municipal sludge by low temperature hydrothermal treatment [J]. China Water & Wastewater, 2019,35(17):26-30.
|
[10] |
薛香玉,陈德珍,戴晓虎,等.污泥水热反应产物特性与水热温度选择[J]. 中国电机工程学报, 2016,36(19):5254-5262. Xue X Y, Chen D Z, Dai X X, et al. Properties of products from sewage sludge hydrothermal processes and product oriented temperature choice [J]. Proceedings of the CSEE, 2016,36(19):5254-5262.
|
[11] |
Donoso-Bravo A, Pérez-Elvira S, Aymerich E, et al. Assessment of the influence of thermal pre-treatment time on the macromolecular composition and anaerobic biodegradability of sewage sludge [J]. Bioresource Technology, 2011,102(2):660-666.
|
[12] |
Ahmed M, Andreottola G, Elagroudy S, et al. Coupling hydrothermal carbonization and anaerobic digestion for sewage digestate management:Influence of hydrothermal treatment time on dewaterability and bio-methane production [J]. Journal of Environmental Management, 2021, 281:111910.
|
[13] |
Chen R, Sheng Q, Chen S, et al. The three-stage effect of hydrothermal treatment on sludge physical-chemical properties:Evolution of polymeric substances and their interaction with physicochemical properties [J]. Water Research, 2022,211:118043.
|
[14] |
Danso-Boateng E, Shama G, Wheatley A D, et al. Hydrothermal carbonisation of sewage sludge:Effect of process conditions on product characteristics and methane production [J]. Bioresource Technology, 2015,177:318-327.
|
[15] |
Ruyter H P. Coalification model [J]. Fuel, 1982,61:1182-1187.
|
[16] |
Ward B J, Nguyen M T, Sam S B, et al. Particle size as a driver of dewatering performance and its relationship to stabilization in fecal sludge [J]. Journal of Environmental Management, 2023,326:116801.
|
[17] |
Reza M T, Yan W, Uddin M H, et al. Reaction kinetics of hydrothermal carbonization of loblolly pine [J]. Bioresource Technology, 2013,139:161-169.
|
[18] |
Wang L, Li A, Chang Y. Relationship between enhanced dewaterability and structural properties of hydrothermal sludge after hydrothermal treatment of excess sludge [J]. Water Research, 2017,112:72-82.
|
[19] |
Mursito A T, Hirajima T, Sasaki K. Upgrading and dewatering of raw tropical peat by hydrothermal treatment [J]. Fuel, 2010,89(3):635-641.
|
[20] |
Feng G, Tan W, Zhong N, et al. Effects of thermal treatment on physical and expression dewatering characteristics of municipal sludge [J]. Chemical Engineering Journal, 2014,247:223-230.
|
[21] |
Zhang Y, Zhang S, Li H, et al. Treatment of municipal sludge by hydrothermal oxidation process with H2O2 [J]. Chemosphere, 2020, 257:127140.
|
[22] |
谭煜,付丽亚,周鉴,等.胞外聚合物(EPS)对污水处理影响的研究进展[J]. 环境工程技术学报, 2021,11(2):307-313. Tan Y, Fu L Y, Zhou J, et al. Research progress of the effects of extracellular polymeric substances (EPS) on wastewater treatment system [J]. Journal of Environmental Engineering Technology, 2021, 11(2):307-313.
|
[23] |
Yan M, He L, Prabowo B, et al. Effect of pressure and atmosphere during hydrothermal treatment on the properties of sewage sludge-derived solid fuel [J]. Journal of Material Cycles and Waste Management, 2018,20(3):1594-1604.
|
[24] |
Niu M, Zhang W, Wang D, et al. Correlation of physicochemical properties and sludge dewaterability under chemical conditioning using inorganic coagulants [J]. Bioresource Technology, 2013,144:337-343.
|
[25] |
蒋勗欣,李军,马挺,等.好氧污泥颗粒化中胞外聚合物(EPS)的动态变化[J]. 环境科学学报, 2014,34(5):1192-1198. Jiang X X, Li J, Ma T, et al. Dynamic changes of EPS in aerobic sludge granulation [J]. Acta Scientiae Circumstantiae, 2014,34(5):1192-1198.
|
[26] |
成珊,罗睿,田红,等.水热碳化温度对污泥有机氮固液相迁移转化路径影响研究[J]. 化工学报, 2022,73(11):5220-5229. Cheng S, Luo R, Tian H, et al. Effect of hydrothermal carbonization temperature on transformation path of organic nitrogen in sludge [J]. CIESC Journal, 2022,73(11):5220-5229.
|
|
|
|