气相色谱法检测红树林湿地土壤中氯/溴代多环芳烃

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (0 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract A gas chromatography-electron capture detector (GC-ECD) method was established to detect 18homologues of Cl/Br-PAHs in soils sampled from mangrove wetlands in Guangxi. The results indicate that a total Cl/Br-PAH content ranged from 163.24 to 244.45ng/g dw in wetland soils. The detection limits and spiked recovery rates were found to range from 0.21 to 3.75ng/g dry weight and from 64.9% to 106.4%, respectively. Compared to the GC-MS method, the GC-ECD method exhibited similar accuracy and sensitivity for most Cl/Br-PAHs and offered better stability and lower analytical costs. This method is thought to be suitable for both qualitative and quantitative analysis of Cl/Br-PAHs in wetland soils.

Key words： chlorinated and brominated polycyclic aromatic hydrocarbons (Cl/Br-PAHs) gas chromatography-electron capture detector (GC-ECD) soil mangrove wetlands emerging contaminants

Received: 27 June 2023

PACS:

X53

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZUO Zi-cen
	ZHANG Li
	NI Jie
	HE Zhen
	YANG Gui-peng

Cite this article:

ZUO Zi-cen,ZHANG Li,NI Jie等. Determination of chlorinated and brominated polycyclic aromatic hydrocarbons in mangrove wetland soils using gas chromatography[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(1): 261-268.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I1/261

[1]	Wang Y, Qi A, Wang P, et al.Temporal profiles, source analysis, and health risk assessments of parent polycyclic aromatic hydrocarbons (PPAHs) and their derivatives (NPAHs, OPAHs, ClPAHs, and BrPAHs) in PM2.5 and PM1.0 from the eastern coastal region of China:Urban coastal area versus coastal background area [J].Chemosphere, 2022, 292:133341.
[2]	Shu W B, Zhao Y B, Ni H G, et al.Size-dependent emission characteristics of airborne parent and halogenated PAHs from municipal solid waste incinerators in Shenzhen, China [J].Chemosphere, 2018,192:250-257.
[3]	Liu Q, Xu X, Lin L, et al.Occurrence, health risk assessment and regional impact of parent, halogenated and oxygenated polycyclic aromatic hydrocarbons in tap water [J].Journal of Hazardous Materials, 2021,413:125360.
[4]	Wang Y, Su P, Ge X, et al.Identification of specific halogenated polycyclic aromatic hydrocarbons in surface soils of petrochemical, flame retardant, and electronic waste dismantling industrial parks [J].Journal of Hazardous Materials, 2022,436:129160.
[5]	Nishimura C, Horii Y, Tanaka S, et al.Occurrence, profiles, and toxic equivalents of chlorinated and brominated polycyclic aromatic hydrocarbons in E-waste open burning soils [J].Environmental Pollution, 2017,225:252-260.
[6]	孙建林,倪宏刚,丁超,等.深圳茅洲河表层沉积物卤代多环芳烃污染研究[J].环境科学, 2012,33(9):3089-3096.Sun J L, Ni H G, Ding C, et al.Halogenated polycyclic aromatic hydrocarbons in surface sediments of Maozhou River, Shenzhen [J].Environmental Science, 2012,33(9):3089-3096.
[7]	Horii Y, Ohura T, Yamashita N, et al.Chlorinated polycyclic aromatic hydrocarbons in sediments from industrial areas in Japan and the United States [J].Archives of Environmental Contamination and Toxicology, 2009,57(4):651-660.
[8]	Cai C Y, Yu S Y, Li X Y, et al.Emission characteristics of polycyclic aromatic hydrocarbons from pyrolytic processing during dismantling of electronic wastes [J].Journal of Hazardous Materials, 2018,351:270-276.
[9]	Vuong Q T, Thang P Q, Ohura T, et al.Chlorinated and brominated polycyclic aromatic hydrocarbons in ambient air:Seasonal variation, profiles, potential sources, and size distribution [J].Reviews of Environmental Science and Biotechnology, 2020,19(2):259-273.
[10]	Wang J, Chen S J, Tian M, et al.Inhalation cancer risk associated with exposure to complex polycyclic aromatic hydrocarbon mixtures in an electronic waste and urban area in South China [J].Environmental Science and Technology, 2012,46(17):9745-9752.
[11]	刘明洋,李会茹,宋爱民,等.环境和人体中氯代/溴代多环芳烃的研究进展——污染来源,分析方法和污染特征[J].中国环境科学, 2021, 41(4):1842-1855.Liu M Y, Li H R, Song A M, et al.A review of chlorinated/brominated polycyclic aromatic hydrocarbons in the environment and human:Sources, analysis methods and pollution characteristics [J].China Environmental Science, 2021,41(4):1842-1855.
[12]	Ohura T, Sawada K, Amagai T, et al.Discovery of novel halogenated polycyclic aromatic hydrocarbons in urban particulate matters:occurrence, photostability, and AhR activity [J].Environmental Science and Technology, 2009,43:2269-2275.
[13]	Åberg A, MacLeod M, Wiberg K.Physical-chemical property data for dibenzo-p-dioxin (DD), dibenzofuran (DF), and chlorinated DD/Fs:A critical review and recommended values [J].Journal of Physical and Chemical Reference Data, 2008,37:1997-2008.
[14]	Bhagade A.Bioaccumulation kinetics and bio concentration factors of few polychlorinated biphenyls:a study on freshwater fish Puntius ticto [J].Current World Environment, 2020,15:278-288.
[15]	Ohura T, Morita M, Makino M, et al.Aryl hydrocarbon receptor-mediated effects of chlorinated polycyclic aromatic hydrocarbons [J].Chemical Research in Toxicology, 2007,20:1237-1241.
[16]	Horii Y, Khim J S, Higley E B, et al.Relative potencies of individual chlorinated and brominated polycyclic aromatic hydrocarbons for induction of aryl hydrocarbon receptor-mediated responses [J].Environmental Science and Technology, 2009,43:2159-2165.
[17]	Huang C, Xu X, Wang D, et al.The aryl hydrocarbon receptor (AhR) activity and DNA-damaging effects of chlorinated polycyclic aromatic hydrocarbons (Cl-PAHs) [J].Chemosphere, 2018,211:640-647.
[18]	张信,陈建裕,杨清杰.粤港澳大湾区红树林时空分布演变及现存林龄遥感分析[J].海洋学报, 2023,45(3):113-124.Zhang X, Chen J Y, Yang Q J.Analysis of spatial-temporal distribution evolution and age of existing mangrove forests in Guangdong-Hong Kong-Macao Greater Bay Area using remotely sensed data [J].Acta Oceanologica Sinica, 2023,45(3):113-124.
[19]	褚冠宇.基于风暴潮记录的广西红树林沉积与碳埋藏特征及脆弱性研究[D].南宁:广西大学, 2021:1-62.Chu G Y.Study on sedimentation and carbon burial characteristics and vulnerability of mangroves based on storm surge history in Guangxi [D].Nanning:Guangxi University, 2021.
[20]	罗新正,孟宪伟.基于相对海平面变化的广西茅尾海红树林面积稳定性评估[J].海洋环境科学, 2022,41(6):882-887.Luo X Z, Meng X W.Assessment of mangrove area stability based on relative sea level change in Maowei Sea, Guangxi [J].Marine Environmental Science, 2022,41(6):882-887.
[21]	谢亮亮.基于遥感的广西北部湾红树林演变研究[D].长沙:湖南农业大学, 2020:1-68.Xie L L.Study on mangrove evolution in Guangxi Beibu Gulf based on remote sensing [D].Changsha:Hunan Agricultural University, 2020.
[22]	陈敏,陈莉,黄平.乌鲁木齐地区土壤中有机氯农药残留特征及来源分析[J].中国环境科学, 2014,34(7):1838-1846.Chen M, Chen L, Huang P.Residues and possible sources of organochlorine pesticides in surface soil of Urumqi [J].China Environmental Science, 2014,34(7):1838-1846.
[23]	HJ 834-2017土壤和沉积物半挥发性有机物的测定气相色谱-质谱法[S].HJ 834-2017 Soil and sediment-Determination of semivolatile organic compounds-Gas chromatography/Mass spectrometry [S].
[24]	HJ 911-2017土壤和沉积物有机物的提取超声波萃取法[S].HJ 911-2017 Soil and sediment-Extraction of organic compounds-Ultrasonic extraction [S].
[25]	Ma J, Horii Y, Cheng J, et al.Chlorinated and parent polycyclic aromatic hydrocarbons in environmental samples from an electronic waste recycling facility and a chemical industrial complex in China [J].Environmental Science and Technology, 2009,43(3):643-649.
[26]	鲍士旦.土壤农化分析[M].北京:中国农业出版社, 2008:45-119.Bao S D.Soil and agricultural chemistry analysis [M].Beijing:China agriculture press, 2008:45-119.
[27]	Jin R, Yang L, Zheng M, et al.Source identification and quantification of chlorinated and brominated polycyclic aromatic hydrocarbons from cement kilns co-processing solid wastes [J].Environmental Pollution, 2018,242:1346-52.