土壤中多环芳烃衍生物污染特征及迁移转化

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Abstract In this paper, the contamination levels and occurrence forms of chlorinated polycyclic aromatic hydrocarbons (ClPAHs) and nitrated polycyclic aromatic hydrocarbons (NPAHs) were reviewed in different regions and different utilization types of soils. The properties of ClPAHs and NPAHs, such as polarity, soil adsorption coefficient, bioconcentration factors, and energy level orbit were obtained by EPI Suite software and density functional theory calculation. The effects of the type, quantity and location of substituent groups on the properties and environmental trend of PAHs derivatives were also analyzed. Meanwhile, the migration behaviors of ClPAHs and NPAHs in soils, such as adsorption-desorption, photodegradation, redox and biodegradation, were summarized emphatically. Finally, the currently existing problems and trends of PAHs derivatives were also discussed. It is necessary to further optimize the detection method, establish the soil PAHs derivatives contaminant database, and explore the transformation data and mechanism, in order to provide more comprehensive information for soil PAHs derivatives contamination characteristics and migration.

Key words： chlorinated polycyclic aromatic hydrocarbons nitrated polycyclic aromatic hydrocarbons soil contamination characteristics migration

Received: 03 August 2023

PACS:

X13

Corresponding Authors: 高彦征,教授,gaoyanzheng@njau.edu.cn E-mail: gaoyanzheng@njau.edu.cn

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	CHENG Peng-fei
	WANG Ze-ming
	ZHAO Xu-qiang
	GAO Yan-zheng

Cite this article:

CHENG Peng-fei,WANG Ze-ming,ZHAO Xu-qiang等. Contamination characteristics and migration of PAHs derivatives in soils[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(3): 1562-1574.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I3/1562

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