|
|
Occurrence and removal efficiency of microplastics in the upper Yellow River water supply plants |
MIN Rui1,2, ZHOU Tian-hong1,2, ZHANG Hong-wei1,2, SONG Shang-jian1,2, LIU Xin1,2, ZHANG Guo-zhen1,2 |
1. School of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China; 2. Key Laboratory of Yellow River Water Environment in Gansu Province, Lanzhou 730070, China |
|
|
Abstract The abundance, physical morphology, and composition of microplastics>1μm in a water supply plant were investigated in the upper reaches of the Yellow River. The results showed that the abundance of microplastics in the raw water, coagulation and sedimentation, filtration, UV disinfection and terminal effluent were (1964.5±212.5) microplastics/L, (795±136) microplastics/L, (386±21) microplastics/L, (377±20) microplastics/L, and (374.5±13.5) microplastics/L, with an overall removal rate of 80.97%. Microplastics from raw water to terminal effluent were predominantly in the form of fragments of <10 μm (89.60%~100%), and their removal efficiency was related to shape and size. 15 different polymer types were identified by laser direct infrared spectrometry and Raman spectroscopy with qualitative analysis. Polyethylene terephthalate, polypropylene, polyethylene, and polymethylmethacrylate were mainly manifested. The basis for the presence of microplastics in urban water supplies and the reference for the removal of microplastics during water supply treatment were provided in the experiment.
|
Received: 18 October 2023
|
|
|
|
|
[1] Thompson R C, Olsen Y, Mitchell R P, et al. Lost at sea:where is all the plastic?[J]. Science, 2004,304(5672):838. [2] Expósito N, Rovira J, Sierra J, et al. Microplastics levels, size, morphology and composition in marine water, sediments and sand beaches. Case study of Tarragona coast (western Mediterranean)[J]. Science of the Total Environment, 2021,786:147453. [3] Franco A A, Arellano J M, Albendín G, et al. Microplastic pollution in wastewater treatment plants in the city of Cádiz:Abundance, removal efficiency and presence in receiving water body[J]. Science of the Total Environment, 2021,776:145795. [4] Eerkes-Medrano D, Leslie H A, Quinn B. Microplastics in drinking water:A review and assessment[J]. Current Opinion in Environmental Science&Health, 2019,7:69-75. [5] Kosuth M, Mason S A, Wattenberg E V. Anthropogenic contamination of tap water, beer, and sea salt[J]. PloS one, 2018,13(4):194970. [6] Pivokonsky M, Bubakova P, Pivokonska L, et al. The effect of global velocity gradient on the character and filterability of aggregates formed during the coagulation/flocculation process[J]. Environmental Technology, 2011,32(11/12):1355-1366. [7] Mintenig S M, Löder M G J, Primpke S, et al. Low numbers of m croplastics detected in drinking water from ground water sources[J]. Science of the Total Environment, 2019,648:631-635. [8] Wang Z, Lin T, Chen W. Occurrence and removal of microplastics in an advanced drinking water treatment plant (ADWTP)[J]. Science of the Total Environment, 2020,700:134520. [9] Pivokonský M, Pivokonská L, Novotná K, et al. Occurrence and fate of microplastics at two different drinking water treatment plants within a river catchment[J]. Science of the Total Environment, 2020,741:140236. [10] Koelmans A A, Nor N H M, Hermsen E, et al. Microplastics in freshwaters and drinking water:Critical review and assessment of data quality[J]. Water Research, 2019,155:410-422. [11] Scheurer M, Bigalke M. Microplastics in Swiss floodplain soils[J]. Environmental Science&Technology, 2018,52(6):3591-3598. [12] Oßmann B E, Sarau G, Holtmannspötter H, et al. Small-sized microplastics and pigmented particles in bottled mineral water[J]. Water Research, 2018,141:307-316. [13] Min R, Ma K, Zhang H, et al. Distribution and risk assessment of microplastics in Liujiaxia Reservoir on the upper Yellow River[J]. Chemosphere, 2023,320:138031. [14] Pivokonsky M, Cermakova L, Novotna K, et al. Occurrence of microplastics in raw and treated drinking water[J]. Science of the Total Environment, 2018,643:1644-1651. [15] Schirinzi G F, Pérez-Pomeda I, Sanchís J, et al. Cytotoxic effects of commonly used nanomaterials and microplastics on cerebral and epithelial human cells[J]. Environmental Research, 2017,159:579-587. [16] Bouwmeester H, Hollman P, Peters R. Potential Health Impact of Environmentally Released Micro-and Nanoplastics in the Human Food Production Chain:Experiences from Nanotoxicology[J]. Environmental Science&Technology, 2015,49(15):8932. [17] Katrivesis F K, Karela A D, Papadakis V G, et al. Revisiting of coagulation-flocculation processes in the production of potable water[J]. Journal of Water Process Engineering, 2019,27:193-204. [18] Dronjak L, Exposito N, Rovira J, et al. Screening of microplastics in water and sludge lines of a drinking water treatment plant in Catalonia, Spain[J]. Water Research, 2022,225:119185. [19] Enfrin M, Dumée L F, Lee J. Nano/microplastics in water and wastewater treatment processes-origin, impact and potential solutions[J]. Water Research, 2019,161:621-638. [20] Wright S L, Kelly F J. Plastic and human health:a micro issue?[J]. Environmental Science&Technology, 2017,51(12):6634-6647. [21] Wang Y L, Lee Y H, Chiu I J, et al. Potent impact of plastic nanomaterials and micromaterials on the food chain and human health[J]. International Journal of Molecular Sciences, 2020,21(5):1727. [22] Wang W, Ndungu A W, Li Z, et al. Microplastics pollution in inland freshwaters of China:A case study in urban surface waters of Wuhan, China[J]. Science of the Total Environment, 2017,575:1369-1374. [23] Cheung P K, Fok L. Characterisation of plastic microbeads in facial scrubs and their estimated emissions in Mainland China[J]. Water Research, 2017,122:53-61. [24] Shen M, Zeng Z, Wen X, et al. Presence of microplastics in drinking water from freshwater sources:the investigation in Changsha, China[J]. Environmental Science and Pollution Research, 2021,28:42313-42324. [25] Sarkar D J, Sarkar S D, Das B K, et al. Microplastics removal efficiency of drinking water treatment plant with pulse clarifier[J]. Journal of Hazardous Materials, 2021,413:125347. [26] Wu J, Zhang Y, Tang Y. Fragmentation of microplastics in the drinking water treatment process-A case study in Yangtze River region, China[J]. Science of the Total Environment, 2022,806:150545. [27] Stubbins A, Law K L, Muñoz S E, et al. Plastics in the Earth system[J]. Science, 2021,373(6550):51-55. [28] Al Nahian S, Rakib M R J, Haider S M B, et al. Occurrence, spatial distribution, and risk assessment of microplastics in surface water and sediments of Saint Martin Island in the Bay of Bengal[J]. Marine Pollution Bulletin, 2022,179:113720. [29] Yin K, Wang D, Zhao H, et al. Microplastics pollution and risk assessment in water bodies of two nature reserves in Jilin Province:Correlation analysis with the degree of human activity[J]. Science of the Total Environment, 2021,799:149390. [30] Zhang Q, Liu T, Liu L, et al. Distribution and sedimentation of microplastics in Taihu Lake[J]. Science of the Total Environment, 2021,795:148745. |
|
|
|