NTA-Fe@PDA/H<sub>2</sub>O<sub>2</sub>氧化去除废水中盐酸土霉素

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Abstract In this paper, polydopamine (PDA) grafted with nitrilotriacetic acid(NTA)and Fe³⁺ were chelated to form Fenton catalyst. Advanced oxidation process of NTA-Fe@PDA activated H₂O₂ was used to remove oxytetracyclin hydrochloride (OTC) from wastewater. The material characterization analysis showed that NTA-Fe@PDA was a typical mesoporous structure, Fe successfully chelated with organic ligand, and the polymerization effect of PDA was good. The effects of H₂O₂ dosage, NTA-Fe@PDA dosage and initial pH value on the degradation of OTC were investigated. Experimental results indicated that the degradation rate of 20mg/L OTC reached 96.23% after reaction for 60min, under the conditions of 5mmol/L H₂O₂, 200mg/L NTA-Fe@PDA and initial pH 4.85. Free radical quenching experiments confirmed that ·OH was the main free radical for OTC degradation. The possible degradation path of OTC was inferred by LC-MS analysis. The degradation rate of OTC was still above 86.80% after NTA-Fe@PDA was reused for 8times. Fenton oxidation process of NTA-Fe@PDA provided a new idea and technical reference for the treatment of antibiotic wastewater.

Key words： polydopamine (PDA) Fe³⁺chelating agent Fenton oxidation oxytetracycline hydrochloride (OTC) degradation mechanism

Received: 13 October 2023

PACS:

X703.5

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	Articles by authors
	LIN Jia-wei
	SU Bing-qin
	LI Xing-fa
	WEI Yue-xing
	ZHENG Xiao-xiao
	ZHANG Xia-ling
	SONG Xin-tong
	ZHAO Wen-bo

Cite this article:

LIN Jia-wei,SU Bing-qin,LI Xing-fa等. NTA-Fe@PDA/H₂O₂ oxidation for removal of oxytetracycline hydrochloride from wastewater[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(5): 2680-2692.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I5/2680

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