水葫芦生物炭联合高碘酸盐高效去除水中磺胺嘧啶

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Abstract Water hyacinth biochar (EBC), derived from the invasive plant water hyacinth, exhibited remarkable capabilities in activating periodate (PI) and facilitating the degradation of sulfadiazine (SD). Notably, EBC outperformed Alligator weed BC and Canadian goldenrod BC in this regard. Among various pyrolysis temperatures, EBC prepared at 500℃(EBC500) demonstrated superior PI activation, effectively removing SD within a mere 20 minutes using a lower PI dose (0.15mmol/L). As the dosage of EBC500 and PI increased, the removal rate of SD also increased accordingly. Comprehensive analyses, including bursting experiments and electron paramagnetic resonance analysis, revealed that iodine radicals (×IO₃, ×IO₄), superoxide radicals (O₂^•−), and singlet oxygen (¹O₂) served as the primary reactive species responsible for the degradation of SD in the EBC500/PI system. Meanwhile, under the conditions of EBC500 and PI dosages of 0.15g/L and 0.15mmol/L, respectively, SD can be completely removed across a wide range of initial pH values (5~9). Coexisting substances such as common anions (including Cl⁻, SO₄²⁻, and NO₃⁻) had minimal impact on the degradation of SD in the EBC500/PI system. However, HCO₃⁻ and HA exhibited inhibitory effects on the removal of SD. Moreover, the EBC500/PI system demonstrates robust applicability for the degradation of SD in natural water matrixes, and good application potential for degradation of other typical sulfonamide antibiotics as well. Additionally, EBC500 demonstrated favorable reusability. Based on the identification of six intermediates, potential degradation pathways of SD were proposed. Ecotoxicity analysis and plant seed germination tests confirmed that the treatment with the EBC500/PI system significantly reduced the biological toxicity of SD, underscoring its promising application prospects.

Key words： advanced oxidation techniques periodate biochar sulfadiazine degradation

Received: 26 November 2023

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X703

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	ZHANG Yue
	YUAN Yu-long
	YAN Cai-xia
	JIANG Yi-han
	SU Mei-qi
	DING Ming-jun
	WANG Peng
	NIE Ming-hua

Cite this article:

ZHANG Yue,YUAN Yu-long,YAN Cai-xia等. Efficient removal of sulfadiazine by water hyacinth[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(7): 3767-3779.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I7/3767

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