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| Photocatalytic degradation of imidacloprid in water by Ag/AgCl/ZnO/ATP |
| WANG Yang-yang, YANG Jia-wei, SUN Lei, WANG Jia-ning, YE Jing-yi, BAO Jia-hua, YANG Liu |
| Key Laboratory of Yellow River Water Environment of Gansu Province, College of Environmental and Municipal Engineering, Lanzhou Jiaotong University, Lanzhou 730070, China |
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Abstract Ag/AgCl/ZnO/ATP heterojunction composite photocatalysts were successfully prepared by hydrothermal and precipitation-photoreduction methods. Due to its high efficient photocatalytic activity, the Ag/AgCl/ZnO/ATP was investigated the photodegradation performance and mechanism of imidacloprid (IMI) in water. And it exhibited excellent photocatalytic performance under visible light irradiation, and the removal ability for IMI within 30min. The degradation process conformed to the quasi-primary kinetic model, and its reaction rate constant was 7.2 times higher than that of AgCl. The photodegradation of the IMI well executed within the pH range of 5~11. Both SO42- and NO3- have a certain promotion effect on the degradation of IMI in the water, and the efficient photocatalytic performance and stability can still be maintained after 5 cycles of reuse. Combined with the characterization and experimental validation, it can be seen that the composition of the AgCl/ZnO heterojunction effectively inhibits the complexation of electron-hole pairs. Which allows IMI to undergo nitroxide removal, dechlorination, and ring-opening of pyridine and imidazole under the action of the active substances (h+, ·O2-, and ·OH), and ultimately realizes the efficient degradation of IMI.
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Received: 09 March 2024
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[1] Ma Y, Zhai S, Mao S Y, et al. Co-metabolic transformation of the neonicotinoid insecticide imidacloprid by the new soil isolate Pseudoxanthomonas indica CGMCC 6648[J]. Journal of Environmental Science and Health, Part B, 2014,49(9):661-670.
[2] Jeschke P, Nauen R, Schindler M, et al. Overview of the status and global strategy for neonicotinoids [J]. Journal of Agricultural and Food Chemistry, 2011,59(7):2897-2908.
[3] Gautam P, Dubey S K. Biodegradation of imidacloprid: Molecular and kinetic analysis [J]. Bioresource Technology, 2022,350:126915.
[4] Phugare S S, Kalyani D C, Gaikwad Y B, et al. Microbial degradation of imidacloprid and toxicological analysis of its biodegradation metabolites in silkworm (Bombyx mori) [J]. Chemical Engineering Journal, 2013,230:27-35.
[5] 陆萍萍,漆知非,陆滢琦,等.生物炭土地渗滤系统对吡虫啉废水处理的研究[J]. 水处理技术, 2024,50(1):61-66. Lu P P, Qi Z F, Lu Y Q, et al. Research on the treatment of imidacloprid wastewater by biochar land infiltration system [J]. Water Treatment Technology, 2024,50(1):61-66.
[6] Targhan H, Rezaei A, Aliabadi A, et al. Adsorptive and photocatalytic degradation of imidacloprid pesticide from wastewater via the fabrication of ZIF-CdS/Tpy quantum dots [J]. Chemical Engineering Journal, 2024,482:148983.
[7] 何欢,马启程,邓弘宇,等.Ag/TiO2光电催化降解染料及出水有机质影响机制[J]. 中国环境科学, 2021,41(4):1689-1696. He H, Ma Q C, Deng H Y, et al. Photoelectrocatalytic degradation of dyestuffs by Ag/TiO2 and the influence mechanism of organic matter in effluent [J]. China Environmental Science, 2021,41(4):1689-1696.
[8] Kusumah A D, Yulizar Y, Apriandanu D O B, et al. Fabrication of ZnO and ZnO/CuMoO4 for the improvement of photocatalytic performance [J]. Vacuum, 2024:113034.
[9] Xian T, Ma X, Sun X, et al. Construction of pn type AgCl/BiFeO3 heterojunction with promising photocatalytic and piezo-photocatalytic water purification [J]. Optical Materials, 2024,149:115054.
[10] 庞族族,丁宁,刘宏.银基光催化剂W-Ag3PO4的制备及其可见光降解抗生素左氧氟沙星[J]. 中国环境科学, 2023,43(9):4606-4615. Pang Z Z, Ding N, Liu H. Preparation of silver-based photocatalyst W-Ag3PO4 and its visible light degradation of antibiotic levofloxacin [J]. China Environmental Science, 2023,43(9):4606-4615.
[11] Nguyen N T T, Nguyen L M, Nguyen T T T, et al. Recent advances on botanical biosynthesis of nanoparticles for catalytic, water treatment and agricultural applications: A review [J]. Science of the Total Environment, 2022,827:154160.
[12] Pan L, Muhammad T, Ma L, et al. MOF-derived C-doped ZnO prepared via a two-step calcination for efficient photocatalysis [J]. Applied Catalysis B: Environmental, 2016,189:181-191.
[13] Krishnakumar B, Subash B, Swaminathan M. AgBr-ZnO-An efficient nano-photocatalyst for the mineralization of Acid Black 1with UV light [J]. Separation and Purification Technology, 2012,85:35-44.
[14] Lamba R, Umar A, Mehta S K, et al. Visible-light-driven photocatalytic properties of self assembled cauliflower-like AgCl/ZnO hierarchical nanostructures [J]. Journal of Molecular Catalysis A: Chemical, 2015,408:189-201.
[15] Meng A, Xing J, Li Z, et al. Ag/AgCl/ZnO nano-networks: Preparation, characterization, mechanism and photocatalytic activity [J]. Journal of Molecular Catalysis A: Chemical, 2016,411:290-298.
[16] Svoboda L, Bednář J, Dvorský R, et al. Novel synthesis of Ag@ AgCl/ZnO by different radiation sources including radioactive isotope 60Co: Physicochemical and antimicrobial study [J]. Applied Surface Science, 2020,529:147098.
[17] Singh R, Choudhary R B. Ag/AgCl sensitized n-type ZnO and p-type PANI composite as an active layer for hybrid solar cell application [J]. Optik, 2021,225:165766.
[18] McEvoy J G, Zhang Z. Antimicrobial and photocatalytic disinfection mechanisms in silver-modified photocatalysts under dark and light conditions [J]. Journal of Photochemistry and Photobiology C: Photochemistry Reviews, 2014,19:62-75.
[19] Zheng J, Zhu Z, Gao G, et al. Construction of spindle structured CeO2 modified with rod-like attapulgite as a high-performance photocatalyst for CO2 reduction [J]. Catalysis Science & Technology, 2019,9(14): 3788-3799.
[20] Mu B, Ying X, Petropoulos E, et al. Preparation of AgCl/ZnO nano-composite for effective antimicrobial protection of stone-made building elements [J]. Materials Letters, 2021,285:129143.
[21] Zhang H, Jin Z H, Xu M D, et al. Enhanced isopropanol sensing performance of the CdS nanoparticle decorated ZnO porous nanosheets-based gas sensors [J]. IEEE Sensors Journal, 2021,21(12): 13041-13047.
[22] Faisal M, Ahmed J, Rashed M A, et al. Ag nanoparticles polypyrrole carbon black/mesoporous TiO2 novel nanocomposite as ultrafast visible-light-driven photocatalyst [J]. Ceramics International, 2022, 48(12):16997-17008.
[23] Cao A, Bai X, Yang C, et al. Sphere-rod-like Ag/AgCl@Fe2O3Z- scheme heterojunction as photocatalysts for efficient degradation of tetracycline under visible light irradiation [J]. Chemosphere, 2024,346: 140674.
[24] Borjigin B, Ding L, Li H, et al. A solar light-induced photo-thermal catalytic decontamination of gaseous benzene by using Ag/Ag3PO4/CeO2 heterojunction [J]. Chemical Engineering Journal, 2020,402: 126070.
[25] Ding C, Zhu Q, Yang B, et al. Efficient photocatalysis of tetracycline hydrochloride (TC-HCl) from pharmaceutical wastewater using AgCl/ZnO/g-C3N4 composite under visible light: Process and mechanisms [J]. Journal of Environmental Sciences, 2023,126:249- 262.
[26] Wei Y L, Zheng L X, Li L Y, et al. Facile construction of Ag/AgCl/WO3 ternary plasmonic nanocomposite with promoted photocatalytic property [J]. Materials Research Bulletin, 2024,169:112501.
[27] Li W, Hua F, Yue J, et al. Ag@AgCl plasmon-induced sensitized ZnO particle for high-efficiency photocatalytic property under visible light [J]. Applied Surface Science, 2013,285:490-497.
[28] Tan C, Yin Y, Zuo J, et al. Preparation of MIT-Ag/ZnO/Bi2WO6 nanocomposites and its application as photocatalyst for cefuroxime sodium degradation [J]. Chemical Physics Letters, 2023,830:140797.
[29] Phongarthit K, Amornpitoksuk P, Suwanboon S. Photocatalytic degradation of rhodamine B, reactive orange, and bisphenol A under visible light irradiation over AgX/ZnO (X= Cl, Br, I) prepared from green approach [J]. Optik, 2020,204:164224.
[30] Yang Y, Ma X, Li Z, et al. ZIF-8 and humic acid modified magnetic corn stalk biochar: An efficient, magnetically stable, and eco-friendly adsorbent for imidacloprid and thiamethoxam removal [J]. Chemical Engineering Journal, 2023,465:142788.
[31] Li Z, Liu Y, Zou S, et al. Removal and adsorption mechanism of tetracycline and cefotaxime contaminants in water by NiFe2O4-COF- chitosan-terephthalaldehyde nanocomposites film [J]. Chemical Engineering Journal, 2020,382:123008.
[32] 孙文杰.AgBr/Ag3PO4@Fe2O3复合半导体光催化剂可见光催化降解典型抗生素的研究[D]. 南京:南京农业大学, 2018. Sun W J. Study on visible photocatalytic degradation of typical antibiotics by AgBr/Ag3PO4@Fe2O3 composite semiconductor photocatalyst [D]. Nanjing: Nanjing Agricultural University, 2018.
[33] Gao X, Guo Q, Tang G, et al. Effects of inorganic ions on the photocatalytic degradation of carbamazepine [J]. Journal of Water Reuse and Desalination, 2019,9(3):301-309.
[34] Heidarpour H, Golizadeh M, Padervand M, et al. In-situ formation and entrapment of Ag/AgCl photocatalyst inside cross-linked carboxymethyl cellulose beads: A novel photoactive hydrogel for visible-light-induced photocatalysis [J]. Journal of Photochemistry and Photobiology A: Chemistry, 2020,398:112559.
[35] Cai A, Guo A, Du L, et al. Leaf-templated synthesis of hierarchical AgCl-Ag-ZnO composites with enhanced visible-light photocatalytic activity [J]. Materials Research Bulletin, 2018,103:225-233.
[36] Jiang J, Li H, Zhang L. New insight into daylight photocatalysis of AgBr@Ag: synergistic effect between semiconductor photocatalysis and plasmonic photocatalysis [J]. Chemistry-A European Journal, 2012,18(20):6360-6369.
[37] Murali A, Sarswat P K, Perez J P L, et al. Synergetic effect of surface plasmon resonance and schottky junction in Ag-AgX-ZnO-rGO (X= Cl & Br) nanocomposite for enhanced visible-light driven photocatalysis [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2020,595:124684.
[38] Yu J, Sun D, Wang T, et al. Fabrication of Ag@AgCl/ZnO submicron wire film catalyst on glass substrate with excellent visible light photocatalytic activity and reusability [J]. Chemical Engineering Journal, 2018,334:225-236.
[39] Li J, Chen J, Ao Y, et al. Prominent dual Z-scheme mechanism on phase junction WO3/CdS for enhanced visible-light-responsive photocatalytic performance on imidacloprid degradation [J]. Separation and Purification Technology, 2022,281:119863.
[40] Babić K, Tomašić V, Gilja V, et al. Photocatalytic degradation of imidacloprid in the flat-plate photoreactor under UVA and simulated solar irradiance conditions—The influence of operating conditions, kinetics and degradation pathway [J]. Journal of Environmental Chemical Engineering, 2021,9(4):105611.
[41] Weng J, Chen J, Xu Y, et al. Engineering highly dispersed AgI nanoparticles on hierarchical In2S3hollow nanotube to construct Z-scheme heterojunction for efficient photodegradation of insecticide imidacloprid [J]. Journal of Colloid and Interface Science, 2023, 652:1367-1380. |
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