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| Adsorption/desorption and degradation of bisphenol A in soils from the water-level-fluctuation zone |
| HU Ying1,2,3, SUN Jiao-xia1,2,3, QIN Yan1,2,3 |
1. Hehai College, Chongqing Jiaotong University, Chongqing 400074, China;
2. Environmental Water Conservancy Engineering Laboratory, Chongqing Jiaotong University, Chongqing 400074, China;
3. Inland Waterway Regulation Technology Transportation Industry Key Laboratory, Chongqing Jiaotong University, Chongqing 400074, China |
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Abstract To investigate the environmental behavior of bisphenol A (BPA) in the water-level-fluctuation zone (WLFZ), soil samples were collected at different elevations (SL: 155m, SM: 160m, SH: 165m) from the WLFZ in Qingxi Town, Fulin. Batch adsorption/desorption and simulated degradation experiments were conducted to study the adsorption, desorption, and degradation behaviors of BPA in these soil samples. At temperatures of 15℃, 25℃, and 35℃, the adsorption isotherms of BPA on soils at various elevations conformed to the Freundlich model, exhibiting decreased adsorption capacity with increasing temperature and showing non-linear adsorption characteristics. The adsorption capacity of BPA in soil samples followed a trend consistent with soil organic matter content, increasing as elevation decreased (SL > SM > SH). The values of calculated thermodynamic data ΔG、ΔH and ΔS were all less than zero, indicating that the adsorption of BPA in tested soils was a spontaneous, exothermic process with decreased entropy, dominated by physical adsorption. The desorption hysteresis index HI (0.853-0.981) approached 1, suggesting minimal desorption hysteresis and easy release of BPA from the soils. Under 25℃, the half-life of BPA degradation in soils followed the sequence SL (4.88d) < SM (6.68d) < SH (10.07d), indicating slower degradation rates in soils from long-term exposed areas. At 10℃, the half-life of BPA degradation in soil SH extended to 12.01d, which was 1.19 and 1.20 times longer compared to 25℃ and 35℃, respectively, indicating inhibition of BPA degradation under low-temperature conditions.
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Received: 20 March 2024
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