柠檬酸行业废石膏与CO<sub>2</sub>的协同矿化与工艺模拟

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (1900 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract To achieve efficient synergy in carbon capture and utilization of waste gypsum in the citric acid industry, this study was based on the CO₂ emission characteristics of citric acid production process, and conducted a study on the process conditions of using ammonium chloride leaching waste gypsum solution to absorb CO₂. Aspen Plus was also used to simulate the synergistic mineralization process. The results showed that approximately 20L of waste gas containing 80% CO₂ (V/V) was generated from 1L of citric acid fermentation broth. When the initial concentration of ammonium chloride was 2mol/L and the waste gypsum was leached for 100minutes, the Ca²⁺ concentration could reach 0.062mol/L. Based on the optimized absorption process conditions, mineralization of 33% CO₂ can be achieved and approximately 192g CaCO₃/kg anhydrous citric acid can be produced. The simulation results of the fully mixed reactor process using Aspen Plus showed that when the CO₂ inlet flow rate was controlled to be 0.6kmol/h and the appropriate ammonia and gypsum inlet flow rates were controlled, a mineralization rate of 96.4% for CO₂ and 100% for gypsum conversion can be achieved, and the synergistic mineralization effect was the best.

Key words： citric acid industry waste gypsum CO₂ synergistic mineralization Aspen process simulation

Received: 15 April 2024

PACS:

X703.5

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	HUANG Yan
	ZHU Zi-han
	ZHOU Zi-an
	SUN Xiao-ting
	DONG Li-ming
	YU Su-ping

Cite this article:

HUANG Yan,ZHU Zi-han,ZHOU Zi-an等. Collaborative mineralization and simulation study of waste gypsum and CO₂ in citric acid industry[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(11): 6241-6249.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I11/6241

[1] 阳平坚,彭栓,王静,等.碳捕集、利用和封存(CCUS)技术发展现状及应用展望 [J]. 中国环境科学, 2024,44(1):404-416. Yang P J, Peng S, Wang J, et al. Carbon capture, utilization and storage (CCUS) technology development status and application prospects [J]. China Environmental Science, 2024,44(1):404-416.
[2] 桂霞,王陈魏,云志,等.燃烧前CO₂捕集技术研究进展 [J]. 化工进展, 2014,33(7):1895-1901. Gui X, Wang C W, Yun Z, et al. Research progress of CO₂ capture technology before combustion [J]. Advances in Chemical industry.
[3] Zhang W F, Xu Y L, Wang Q H. Coupled CO₂ absorption and mineralization with low-concentration monoethanolamine [J]. Energy, 2022,241:122524.
[4] 张云,胡寒,周宏辉,等.云南省优势矿产尾矿砂捕集及矿化封存CO₂潜力分析 [J]. 中国环境科学, 2022,42(9):4351-4361. Zhang Y, Hu H, Zhou H H, et al. Analysis of CO₂ trapping and mineralization storage potential of tailing sand from superior minerals in Yunnan Province [J]. China Environmental Science, 2022,42(9):4351-4361.
[5] Zhu J H, Guo X N, Xie H P, et al.Thermodynamics cognizance of CCS and CCU routes for CO₂ emission reduction[J]. Sichuan Daxue Xuebao, 2013,45(5):1-7.
[6] 张兵兵,王慧敏,曾尚红,等.二氧化碳矿物封存技术现状及展望 [J]. 化工进展, 2012,31(9):2075-2083. Zhang B B, Wang H M, Zeng S H, et al. Current situation and prospect of carbon dioxide mineral storage technology [J]. Advances in Chemical industry, 2012,31(9):2075-2083.
[7] Zhao Q, Chu X, Mei X, et al.Co-treatment of Waste From Steelmaking Processes: Steel Slag-Based Carbon Capture and Storage by Mineralization [J]. Frontiers in Chemistry, 2020,8.
[8] 王秋华,吴嘉帅,张卫风.碱性工业固废矿化封存二氧化碳研究进展 [J]. 化工进展, 2023,42(3):1572-1582. Wang Q H, Wu J S, Zhang W F. Research progress on storage of carbon dioxide by mineralization of alkaline industrial waste [J]. Advances in Chemical Industry, 2023,42(3):1572-1582.
[9] 丁文金,姚金,乔静怡,等.磷石膏矿化CO₂制备高纯CaCO₃及产物调控 [J]. 矿产保护与利用, 2022,42(4):104-112. Ding W J, Yao J, Qiao J Y, et al. Preparation of high-purity CaCO₃ from CO₂ mineralization by phosphorous gypsum and its product control [J]. Protection and Utilization of Mineral Resources.
[10] 刘禄,乔静怡,刘卓齐,等.磷石膏制备高纯CaCO₃的试验研究 [J]. 矿产保护与利用, 2022,42(5):126-131. Liu Lu, Qiao J Y, Liu Z Q et al. Experimental study on preparation of high-purity CaCO₃ from phosphogypsum [J]. Mineral Protection and Utilization, 2022,42(5):126-131.
[11] 乔静怡,陈秋菊,刘卓齐,等.磷石膏矿化CO₂制备球霰石型CaCO₃试验研究 [J]. 化工矿物与加工, 2023,52(9):14-18. Qiao J Y, Chen Q J, Liu Z Q, et al. Experimental study on preparation of spheroaragonite CaCO₃ from CO₂ mineralization with phosphorous paste [J]. Chemical Minerals and Processing, 2023,52(9):14-18.
[12] Mathisen A, Sorensen H, Melaaen M,et al.Investigation into optimal CO₂ concentration for CO₂ capture from aluminium production[C]. International Conference on Greenhouse Gas Control Technologies, 2013,37:7168-7175.
[13] Yu K Z, Yu Y, Zhao H P. The sensitivity analysis of CO₂ recovery & liquefaction flowsheet in the beer fermentation process by aspen plus software [J]. Advanced Materials Research, 2013, 860-863:1049-1052.
[14] Hospital B D, Lemus J, Moya C. Aspen plus supported design of pre-combustion CO₂ capture processes based on ionic liquids [J]. Separation and Purification Technology, 2022,290:120-841
[15] Lars E, Oi. Optimization of Configurations for Amine based CO₂ Absorption Using Aspen HYSYS [J]. Energy Procedia, 2014,51:224-233.
[16] Ines H, Karima H N. Solubility study and valorization of phosphogypsum salt solution [J]. International Journal of Mineral Processing, 2013,123: 87-93.
[17] 梁亚琴,孙红娟,彭同江.氯化铵溶液浸取磷石膏中硫酸钙的实验研究 [J]. 非金属矿, 2014,37(4):69-72. Liang Y Q, Sun H J, Peng T J. Experimental study on leaching calcium sulfate from phosphogypsum with ammonium chloride solution [J]. Nonferrous Metals, 2014,37(4):69-72.
[18] 范开明,于海彬.浅谈柠檬酸石膏的综合利用 [J]. 化学工程师, 2020,34(6):69-70,9. Fan K M, Yu H B. Comprehensive utilization of gypsum citrate [J]. Chemical Engineer, 2020,34(6):69-70,9.
[19] Chen Q, Ding W, Sun H, et al. Utilization of phosphogypsum to prepare high-purity CaCO₃ in the NH₄Cl-NH₄OH-CO₂ system [J]. ACS Sustainable Chemistry & Engineering, 2020,8(31):11649-11657.
[20] 彭雨惠.磷石膏氨法捕集CO₂制备CaCO₃机理研究 [D]. 昆明:昆明理工大学, 2019. Peng Y H. Mechanism of preparation of CaCO₃ by capturing CO₂ by phosphogypsum ammonia method [D]. Kunming: Kunming University of Science and Technology, 2019.
[21] Song K, Kim W, Bang J H, et al. Polymorphs of pure calcium carbonate prepared by the mineral carbonation of flue gas desulfurization gypsum [J]. Materials & Design, 2015,83:308-313.
[22] Commenge J M, Obein T, Genin G, et al. Gas-phase residence time distribution in a falling-film microreactor [J]. Chemical Engineering Science, 2006,61(2):597-604.
[23] Li X, Wang Y, Liu X. Micro interfacial Effect: The stability of catalytic activity under gas-liquid reaction pressure changes [J]. Chemical engineering journal, 2022,440:135-560.
[24] Jiang S, Gruen V, Rosenfeldt S, et al. Virtually Wall-Less Tubular Sponges as Compartmentalized Reaction Containers [J]. Research, 2019,(1):10.
[25] Yang A, Huang Z, Zhu Y, et al. Preparation of nano-sized calcium carbonate in solution mixing process [J]. Journal of Crystal Growth, 2021,571:126247.
[26] 赵红涛,王树民,刘志江,等.磷石膏矿化固定CO₂制备高纯高白CaCO₃ [J]. 材料导报, 2019,33(18):5. Zhao H T, Wang S M, Liu Z J, et al. Preparation of high purity and high white CaCO₃ by phosphorous paste mineralization with fixed CO₂ [J]. Materials Review, 2019,33(18):5.
[27] Fuchigami K, Taguchi Y, Tanaka M. Synthesis of calcium carbonate vaterite crystals and their effect on stabilization of suspension polymerization of MMA [J]. Advanced Powder Technology, 2009,20(1):74-79.
[28] 丁文金,刘卓齐,陈秋菊,等.电石渣矿化CO₂-可控制备碳酸钙的实验研究 [J]. 四川大学学报:自然科学版, 2023,60(4):045001. Ding W J, Liu Z Q, Chen Q J, et al. Experimental study on CO₂-controlled preparation of calcium carbonate from calcium carbide slag mineralization [J]. Journal of Sichuan University: Natural Science Edition, 2023,60(4):045001.
[29] Arifin Z, Zainuri M, Cahyono Y, et al. The Influence of Temperature and Gas Flow Rate on the Formation CaCO₃ Vaterite Phase [C]. 2018,395:012-004.
[30] Watanabe H, Mizuno Y, Endo T, et al. Effect of initial pH on formation of hollow calicium carbonate particles by continuous CO gas bubbling into CaCl₂, aqueous solution [J]. Advanced Powder Technology, 2009,20(1):89-93.
[31] Ferreira A M, Vikulina A, Caveg W V, et al. Vate-ritevectors for the protection, storage and release of silver nanoparticles [J]. Journal of Colloid and Interface Science, 2023,631:165-180.
[32] Ding Y, Liu Y, Ren Y, et al. Controllable synthesis of all the anhydrous CaCO₃ polymorphs with various morphologies in CaCl₂-NH₃-CO₂ aqueous system [J]. Powder Technology, 2018,333:410-420.
[33] Han Y S, Hadiko G, Fu J M, et al. Factors affecting the phase and morphology of CaCO₃ prepared by a bubbling method [J]. Journal of the European Ceramic Society, 2006,26(4/5):843-847.