重金属絮凝剂DTAPAM去除水中Cu-EDTA的条件优化和机理

张航; 王刚; 周雅琦; 马玉

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中国环境科学 ›› 2023, Vol. 43 ›› Issue (2) : 532-543.

水污染与控制

重金属絮凝剂DTAPAM去除水中Cu-EDTA的条件优化和机理

张航, 王刚, 周雅琦, 马玉

作者信息 +

Condition optimization and mechanism of heavy metal flocculant DTAPAM in the removal of Cu-EDTA from water

ZHANG Hang, WANG Gang, ZHOU Ya-qi, MA Yu

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文章历史 +

摘要

工业含Cu废水中常含有配位剂EDTA,可与Cu (Ⅱ)配位后形成稳定的可溶性配合物Cu-EDTA,致使废水中的Cu (Ⅱ)较难被除去.为了将含Cu-EDTA废水中的Cu (Ⅱ)得以有效去除,采用二硫代羧基化胺甲基聚丙烯酰胺(DTAPAM)作为重金属絮凝剂,以Cu-EDTA为处理对象,研究了絮凝水力条件、DTAPAM投加量、pH值、EDTA浓度、Cu (Ⅱ)初始浓度对DTAPAM去除Cu-EDTA性能的影响,确定了Cu (Ⅱ)的最佳去除条件;并利用紫外-可见吸收光谱、红外光谱、扫描电镜及能谱分析等表征方法探究了DTAPAM去除Cu-EDTA的机理.结果表明,最佳絮凝水力条件为快搅时间2min、快搅速度160r/min、慢搅时间20min、慢搅速度50r/min;当pH值为5.0~7.0时,DTAPAM对Cu (Ⅱ)初始浓度为25mg/L的含Cu-EDTA水样的去除性能均较好,且在pH值为7.0时Cu (Ⅱ)的去除效果最好,最高去除率可达99.07%;当体系中EDTA与Cu (Ⅱ)配位比为1:1时,DTAPAM对不同Cu (Ⅱ)初始浓度的含Cu-EDTA水样均具有理想的去除效果.表征结果显示,DTAPAM高分子链中的二硫代羧基(—CSS^-)与水样中Cu (Ⅱ)发生了螯合反应;pH值为2.0~9.0时,DTAPAM-Cu螯合稳定常数的对数值介于13.09~13.71.DTAPAM处理含Cu-EDTA水样时,DTAPAM先与EDTA发生配位竞争作用,将Cu-EDTA中的Cu (Ⅱ)解络出与之发生螯合反应生成絮体沉淀物,絮体间发生以吸附架桥和网捕卷扫为主的絮凝作用,促进絮体的沉降,提高了Cu (Ⅱ)的去除.

Abstract

The coordination agent EDTA is usually found in industrial wastewater containing copper, and the stable soluble compound Cu-EDTA can be formed between EDTA and Cu(II), which makes it difficult to remove Cu(II) from the wastewater. In order to improve effectively the removal of Cu(II) from Cu-EDTA wastewater, dithiocarboxyl aminomethy-polyacrylamide (DTAPAM) was employed as heavy metal flocculant. The effects of hydraulic conditions, DTAPAM dosage, pH value, EDTA concentration, and initial Cu(II) concentration on the removal performance of Cu-EDTA with DTAPAM were investigated, and the optimal removal conditions for Cu-EDTA in water sample were determined. The removal mechanism of Cu-EDTA with DTAPAM was also explored by using some characterization methods, such as UV, IR, SEM and EDS. The results show that the optimal hydraulic conditions were as follows: the fast stirring time was 2min, the fast stirring speed was 160r/min, the slow stirring time was 20min, and the slow stirring speed was 50r/min. The removal performance of Cu-EDTA by DTAPAM was favorable for the initial Cu(Ⅱ) concentration of 25mg/L at pH 5.0~7.0, and the highest removal rate of Cu(II) reached 99.07% at pH 7.0. When the coordination ratio between EDTA and Cu(II) was 1:1, it had the ideal removal efficiency for Cu-EDTA with DTAPAM at different initial Cu(II) concentrations. The characterization results show that the chelation reaction should occur between Cu(II) and dithiocarboxylic groups (—CSS^-) on the molecular chain of DTAPAM. At pH 2.0~9.0, the logarithm values of the chelation stability constant for DTAPAM-Cu were in the range of 13.09~13.71. For the removal mechanism of Cu-EDTA by DTAPAM, Cu(II) was replaced from Cu-EDTA by DTAPAM due to coordination competition, and the flocs were formed though chelation reaction between Cu(II) and DTAPAM. In addition, the adsorption bridging and net sweeping among flocs played a major role in the flocculation, which promoted the settlement of the flocs and improved the removal rate of Cu(II).

导出引用

张航, 王刚, 周雅琦, 马玉. 重金属絮凝剂DTAPAM去除水中Cu-EDTA的条件优化和机理[J]. 中国环境科学. 2023, 43(2): 532-543

ZHANG Hang, WANG Gang, ZHOU Ya-qi, MA Yu. Condition optimization and mechanism of heavy metal flocculant DTAPAM in the removal of Cu-EDTA from water[J]. China Environmental Science. 2023, 43(2): 532-543

中图分类号： X703

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