Abstract:Based on the sol-gel transition property of sodium alginate, a kind of composite that: zero valent iron (ZVI) powder was immobilized on the surface of SMZ was prepared so that the composite would have both the adsorption capacity of SMZ and the reducibility of ZVI. The composite was scanned by scanning electron microscope, which indicated that iron powder was uniformly entrapped in a thin calcium-alginate film on the SMZ surface, besides the film did not impede the contact between Cr (VI) and SMZ. The batch experiments aimed to test the capability of removing soluble Cr (VI) by the composite and showed that: removal efficiency of composite, SMZ, ZVI was74.1%,38.4%,9.1%, respectively. The reacted composites was also scanned by X-Ray photoelectron spectrometer (XPS), it revealed that Cr3+, Cr6+ were both on the surface of the composite, which verified the composite owned the adsorption and the reducing ability. The reaction between the composites and Cr (VI) can be expressed by pseudo-second order kinetic model. The changing trend of qe and k was opposite. The composite with a 5.4% iron content showed better performance: its qe was 0.96mg/g, and k was 0.011g/(mg×h). And it still showed good performance when the concentration of Cr (VI) was 70mg/L. It has a qe of 1.29mg/g, and a k of 0.0094g/(mg×h).
杜珮雯, 党宏钰, 张永祥. 改性沸石和铁粉的复合材料处理水中六价铬的研究[J]. 中国环境科学, 2015, 35(5): 1384-1390.
DU Pei-Wen, DANG Hong-Yu, ZHANG Yong-Xiang. Kinetic study for removal of soluble Cr(VI) by prepared surfactant-modified zeolites supported zero-valent iron composite. CHINA ENVIRONMENTAL SCIENCECE, 2015, 35(5): 1384-1390.