Investigation of SO2 removal enhancement from marine flue gas under scrubber swing condition
LIU Chang1, WANG Ding-zhen1, ZHANG Yong-xin1, ZHAO Zhong-yang1, WU Wei-hong1, SHEN Min-qiang2, DAI Hao-bo3, ZHENG Cheng-hang1, GAO Xiang1
1. National Environmental Protection Coal-fired Air Pollution Control Engineering Technology Center, State Key Laboratory of Clean Energy Utilization, College of Energy Engineering, Zhejiang University, Hangzhou 310027, China; 2. Zhejiang Energy Marine Environmental Technology Co., LTD., Hangzhou 311202, China; 3. Zhejiang Tiandi Environmental Protection Technology Co. Ltd., Hangzhou 311121, China
Abstract:The SO2 removal efficiency of magnesia-based absorbent for different absorber inclined angles was investigated, aiming at desulfurization enhancement of the swing condition of ship absorber under severe sea conditions. The effects of liquid-gas ratio, inlet SO2 concentration, flow gas flow rate, pH value on desulphurization efficiency in scrubber tower were studied. The results showed that the desulfurization efficiency decreased with the increasing of inclined angle and the decreasing of the liquid-gas ratio, and the influence of inclined angle on desulfurization efficiency was more obvious at lower liquid-gas ratio. The desulfurization efficiency increased with the increasing of flue gas flow rate and pH value. For different pH values & inlet SO2 concentrations, the variation range of desulfurization efficiency caused by inclined angles was different. The sieve tray and distribution ring improved the desulfurization efficiency of the absorber under swing condition effectively. When the inclined angle was 15°, the desulfurization efficiency increased by about 3%, while the desulfurization efficiency increased by about 5% at the inclined angle of 10°. When the inclined angle was below 5°, the desulfurization efficiency could be improved by nearly 7%.
Sofiev M, Winebrake J J, Johansson L, et al. Cleaner fuels for ships provide public health benefits with climate tradeoffs[J]. Nature Communications, 2018,9(1):406.
[2]
曾凡涛,吕靖.厦门港船舶排放清单及港口生态效率评价[J]. 中国环境科学, 2020,40(5):2304-2311. Zeng F T, Lv J. Ship emission inventory and valuation of eco-efficiency in Xiamen Port[J]. China Environmental Science, 2020, 40(5):2304-2311.
[3]
任远.应对IMO2015硫排放新规范的减排方案的比较研究[D]. 杭州:浙江大学, 2016. Ren Y. Comparison study on the sulphur abatement solutions in compliance with IMO 2015 sulphur regulations[D]. Hangzhou:Zhejiang University, 2016.
[4]
Shen Z G, Guo S P, Kang W Z, et al. Kinetics and mechanism of sulfite oxidation in the magnesium-based wet flue gas desulfurization process[J]. Industrial & Engineering Chemistry Research, 2012, 51(11):4192-4198.
[5]
张欢,钟鹭斌,陈进生,等.船舶尾气脱硫脱硝技术研究进展[J]. 化工进展, 2016,35(11):3650-3657. Zhang H, Zhong L B, Chen J S, et al. Review on desulfurization and denitration technologies for ship exhaust gas treatment[J]. Chemical Industry and Engineering Progress, 2016,35(11):3650-3657.
[6]
唐晓佳.船舶废气镁基脱硫系统优化研究[D].大连:大连海事大学, 2014. Tang X J. Optimization study on magnesium-base desulphurization system for marine exhaust gases[D]. Dalian:Dalian Maritime University, 2014.
[7]
朱益民,郭琳,唐晓佳,等.镁基-海水法船舶废气脱硫技术性能分析[J]. 环境工程学报, 2016,10(12):7173-7178. Zhu Y M, Guo L, Tang X J, et al. Technical performance analysis of magnesium-base seawater desulfurization system for marine exhaust gas[J]. Chinese Journal of Environmental Engineering, 2016,10(12):7173-7178.
[8]
李晓波,涂世恩,张西兆,等.Ⅰ型镁基混合式船舶烟气脱硫系统试验[J]. 船舶与海洋工程, 2020,36(3):34-39. Li X B, Tu S E, Zhang X Z, et al. Bench test for type I magnesium-based hybrid marine flue gas desulfurization system[J]. Naval Architecture and Ocean Engineering, 2020,36(3):34-39.
[9]
郝阳.镁基-海水法船用废气脱硫效率研究[D]. 大连:大连海事大学, 2011. Hao Y. Removal efficiency of magnesium base-seawater desulfurization for marine flue gas[D]. Dalian:Dalian Maritime University, 2011.
[10]
赵良庆,潘利祥,史利芳,等.镁法烟气脱硫副产物生产硫酸镁工艺研究[J]. 环境工程, 2014,32(2):91-94. Zhao L Q, Pan L X, Shi L F, et al. Research on the production of magnesium sulfate by desulfurization by-product of magnesium oxide[J]. Environmental Engineering, 2014,32(2):91-94.
[11]
Qu L T, Li C T, Li C, et al. Evaluation of ultralow emission performance of magnesium oxide (MgO) wet flue gas desulfurization unit for coal-fired units[J]. IOP Conference Series:Earth and Environmental Science, 2019,267(6):062045.
[12]
Guo R T, Pan W G, Zhang X B, et al. Dissolution rate of magnesium hydrate for wet flue gas desulfurization[J]. Fuel, 2011,90(1):7-10.
[13]
钟毅,高翔,王惠挺,等.基于CFD技术的湿法烟气脱硫系统性能优化[J]. 中国电机工程学报, 2008,28(32):18-23. Zhong Y, Gao X, Wang H T, et al. Performance optimization of wet flue gas desulphurization system based on CFD technology[J]. Proceedings of The Chinese Society for Electrical Engineering, 2008, 28(32):18-23.
[14]
鞠铠阳,李威,王欣,等.基于CFD技术的镁法脱硫塔入口烟道流场优化分析[J]. 东北电力大学学报, 2017,37(1):29-33. Ju K Y, Li W, Wang X, et al. Optimization on the entry section of magnesium desulfurization scrubber based on CFD[J]. Journal of Northeast Dianli University (Natural Science Edition), 2017,37(1):29-33.
[15]
刘全.镁基船舶废气脱硫塔内流场及反应过程研究[D]. 大连:大连海事大学, 2017. Liu Q. Research on flow field and reactions in magnesium-based marine exhaust gases desulphurization tower[D]. Dalian:Dalian Maritime University, 2017.
[16]
周密.镁法船用废气脱硫塔仿真优化研究[D]. 镇江:江苏科技大学, 2019. Zhou M. Research on simulation optimization of magnesium process marine waste gas desulfurization tower[D]. Zhenjiang:Jiangsu University of Science and Technology, 2019.
[17]
徐宏建,张超,葛红花.镁法烟气脱硫工艺的实验室模拟及其优化[J]. 上海电力学院学报, 2010,26(2):145-147,156. Xu H J, Zhang C, Ge H H. Simulation and optimation of processes of magnesia flue gas desulfurization[J]. Journal of Shanghai University of Electric Power, 2010,26(2):145-147,156.
[18]
马洁,杨鹏,李国斌.高海情下船舶运动规律及减摇技术仿真研究[J]. 船舶工程, 2006,28(2):24-28. Ma J, Yang P, Li G B. Simulation study of ship's movement regularity and anti-rolling technology under high-wave-level environment[J]. Ship Engineering, 2006,28(2):24-28.
[19]
闫超星,张翼,刘成洋,等.喷淋液滴在空气环境下的运动特性[J]. 原子能科学技术, 2020,54(1):66-71. Yan C X, Zhang Y, Liu C Y, et al. Motion characteristic of spray droplet in air environment[J]. Atomic Energy Science and Technology, 2020,54(1):66-71.
[20]
郭瑞堂,高翔,王君,等.液柱塔内流场和SO2吸收的CFD模拟和优化[J]. 浙江大学学报(工学版), 2007,41(3):494-498,503. Guo R T, Gao X, Wang J, et al. CFD simulation and optimization of flow field and SO2 absorption in impinging stream scrubber[J]. Journal of Zhejiang University (Engineering Science), 2007,41(3):494-498,503.