Preparation of carbonized melamine sponge for photo assisted heavy oil adsorption
LIN Zi-mei1, LOU Guo-sheng2, KANG Yao-ming3, LIU Hui-e1, CHEN Shuang1, YANG Xiang-yi1
1. College of Chemical Engineering, China University of Petroleum, Qingdao 266580, China; 2. 91286 Troops, Qingdao 266021, China; 3. Golmud Refinery of PetroChina Qinghai Oilfield, Golmud 816000, China
Abstract:Carbonized melamine sponge (HMS) was prepared by calcining of melamine sponge (MS) in argon atmosphere. The carbonization effect of HMS was analyzed by SEM, XPS and FI-IR. The density, hydrophilicity, porosity, absorption spectra and compression resilience of the sponge before and after carbonization were measured. The results showed that MS was partly carbonized into HMS, with the hydrophobicity enhanced, the lipophilicity unchanged, and the porosity slightly reduced. HMS exhibited excellent light absorption and mechanical properties. The saturated adsorption volume of HMS sponge on light oil was 92.20cm3/g. Under 1sun irradiation (1kW/m2), the temperature of HMS sponge rose rapidly, which effectively reduced the viscosity of heavy oil in contact with its bottom surface and sped up the adsorption rate of heavy oil, with the adsorption capacity reaching about 99.1g/g. When HMS sponge repeatedly adsorbed heavy oil for 10times, its saturated adsorption capacity on heavy oil could maintain at higher than 81.00g/g. These characteristics made HMS sponge a promising high-efficiency, energy-saving and reusable oil spill adsorbent.
林子媚, 娄国生, 康耀明, 刘会娥, 陈爽, 杨相宜. 碳化三聚氰胺海绵制备及其光热重油吸附研究[J]. 中国环境科学, 2022, 42(7): 3184-3192.
LIN Zi-mei, LOU Guo-sheng, KANG Yao-ming, LIU Hui-e, CHEN Shuang, YANG Xiang-yi. Preparation of carbonized melamine sponge for photo assisted heavy oil adsorption. CHINA ENVIRONMENTAL SCIENCECE, 2022, 42(7): 3184-3192.
朱林超,王东光,顾佳鹏.海上石油的泄漏与防治[J].山东化工, 2018,47(23):88-89. Zhu L C, Wang D G, Gu J P. Offshore oil spills and prevention[J]. Shandong Chemical Industry, 2018,47(23):88-89.
[2]
帅异莹.舟山海域石油烃污染调查及相关石油烃降解微生物的应用研究[D].杭州:浙江大学, 2019:139. Shuai Y Y. Investigation of petroleum hydrocarbon pollution in Zhoushan sea area and application of related petroleum hydrocarbon degrading microorganisms[D]. Hangzhou:Zhejiang University, 2019:139.
[3]
韩辉.重油在胶州湾沉积物上的吸附解吸行为及其影响因素研究[D].青岛:中国海洋大学, 2011:72. Han H. Study on the adsorption and desorption behavior of heavy oil on sediments in Jiaozhou Bay and its influencing factors[D]. Qingdao:Ocean University of China, 2011:72
[4]
Yamada, Yasuhira. The cost of oil spills from tankers in relation to weight of spilled oil[J]. Marine Technology and Sname News, 2009, 46(4):219-228.
[5]
赵召.墨西哥湾漏油事件:前所未有的生态灾难[J].生命世界, 2010,22(7):38-43. Zhao Z. Oil spill in the gulf of mexico:an unprecedented ecological disaster[J]. Life World, 2010,22(7):38-43.
[6]
殷建平,任隽妮.从康菲漏油事件透视我国的海洋环境保护问题[J].理论导刊, 2012,33(4):91-92. Yin J P, Ren J N. Marine environmental protection issues in China from the perspective of ConocoPhillips oil spill[J]. Journal of Socialist Theory Guide, 2012,33(4):91-92.
[7]
Brette F, Machado B, Cros C, et al. Crude oil impairs cardiac excitation-contraction coupling in fish[J]. Science, 2014,343(2):772-776.
[8]
Xin L, Wang Y S, Hong W Y, et al. Research progress and application prospect of high oil-absorbing resins[J]. Applied Mechanics and Materials, 2012,209-211:1199-1202.
[9]
景旭东,林海琳,阎杰.秸秆纤维素吸油材料的研究进展[J].材料导报, 2015,29(19):50-54. Jing X, Lin H, Yan J. Research progress of straw cellulose oil-absorption materials[J]. Materials Reports, 2015,29(19):50-54.
[10]
范廷玉,李文洁,彭丹,等.漆酶改性玉米秸秆髓的制备及其吸油特性[J].中国环境科学, 2020,40(9):3810-3820. Fan T Y, Li W J, Peng D, et al. Preparation of laccase modified corn straw pulp and its oil absorption characteristics[J]. China Environmental Science, 2020,40(9):3810-3820.
[11]
Wu Z Y, Li C, Liang H W, et al. Carbon nanofiber aerogels for emergent cleanup of oil spillage and chemical leakage under harsh conditions[J]. Scientific Reports, 2014,4:4079.
[12]
尚培娜.温度对导热油粘度影响规律的研究[D].株州:湖南工业大学, 2016:62. Shang P N. Study on the influence of temperature on the viscosity of thermal oil[D]. Hunan:Hunan University of Technology, 2016:62.
[13]
Ioana S. Rheological properties of mineral oil[J]. Journal of Science and Arts, 2011,4(17):487-490.
[14]
Oluwafunmilayo A A, Samue E A, Ayobami O A. A laboratory study of the effect of temperature on densities and viscosities of binary and ternary blends of soybean oil, soy biodiesel and petroleum diesel oil[J]. Advances in Chemical Engineering, 2012,2(4):444-452.
[15]
Knezevic D, Savic V. Mathematical modelling of changing of dynamic viscosity, as a function of temperature and pressure,of mineral oils for hydraulic systems[J]. Mechanical Engineering, 2006,4(1):27-34.
[16]
Zhang X F, Song L, Chen X, et al. Zirconium ion modified melamine sponge for oil and organic solvent cleanup[J]. J Colloid Interface Sci, 2020,566:242-247.
[17]
叶锐,张路,付豪,等.蜜胺泡绵的吸放水性研究与应用[J].塑料工业, 2015,43(7):86-88. Ye R, Zhang L, Fu H, et al. Research and application of water absorption-desorption of melamine foams[J]. China Plastics Industry, 2015,43(7):86-88.
[18]
Yang Y, Deng Y, Tong Z, et al. Multifunctional foams derived from poly (melamine formaldehyde) as recyclable oil absorbents[J]. Journal of Materials Chemistry A, 2014,2(26):9994-9999.
[19]
Liu T T, Zhao G, Zhang W, et al. The preparation of superhydrophobic graphene/melamine composite sponge applied in treatment of oil pollution[J]. Journal of Porous Materials, 2015,22(6):1573-1580.
[20]
Wang X Z, Liu D, Cheng G, et al. Solar heating assisted rapid cleanup of viscous crude oil spills using reduced graphene oxide-coated sponges[J]. Science China Technological Sciences, 2020,63(8):1487-1496.
[21]
Ye X, Chen Z, Ai S, et al. Effect of pyrolysis temperature on compression and thermal properties of melamine-derived carbon foam[J]. Journal of Analytical&Applied Pyrolysis, 2019,142(Sep.):104619.1-104619.6.
[22]
韩畅.一种排水法测量固体体积的装置:中国,CN204788551U[P]. 2015. Han Chang. A device for measuring solid volume by drainage method, China, CN204788551U[P]. 2015.
[23]
Ye X, Chen Z, Ai S, et al. Effect of pyrolysis temperature on compression and thermal properties of melamine-derived carbon foam[J]. Journal of Analytical&Applied Pyrolysis, 2019,142(Sep.):104619.1-104619.6.
[24]
Gao H L, Zhu Y B, Mao L B, et al. Super-elastic and fatigue resistant carbon material with lamellar multi-arch microstructure[J]. Nature Communications, 2016,7(1):1-8.
[25]
Zhang Y, Zhang Q, Zhang R, et al. A superhydrophobic and elastic melamine sponge for oil/water separation[J]. New Journal of Chemistry, 2019,43:6343-6349.
[26]
史炜,杨伟,李忠明,等.负泊松比材料研究进展[J].高分子通报, 2003,15(6):48-57. Shi W, Yang W, Li Z M, et al. Research progress on negative poisson ratio materials[J]. Polymer Bulletin, 2003,15(6):48-57.
[27]
刘会娥,黄扬帆,马雁冰,等.石墨烯基气凝胶对有机物的饱和吸附能力[J].化工学报, 2019,70(1):280-289. Liu H E, Huang Y F, Ma Y B, et al. Saturated adsorption capacity of graphene-based aerogels on organic matter[J]. CIESC Journal, 2019,70(1):280-289.
[28]
Cho E C, Chang-Jian C W, Hsiao Y S, et al. Interfacial engineering of melamine sponges using hydrophobic TiO2nanoparticles for effective oil/water separation[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016,67:476-483.
[29]
Liu Q, Meng K, Ding K, et al. A superhydrophobic sponge with hierarchical structure as an efficient and recyclable oil absorbent[J]. Chempluschem, 2015,80(9):1435-1439.
[30]
Chen X, Weibel J A, Garimella S V. Continuous oil-water separation using polydimethylsiloxane-functionalized melamine sponge[J]. Industrial&Engineering Chemistry Research, 2016,55(12):3596-3602.
[31]
Dan L, Tong T, Yha B. Solar heated graphene-melamine foam for absorbing oil and organic solvents-ScienceDirect[J]. Energy Procedia, 2019,158:490-496.
[32]
Mirhosseinian N S, Anbia M, Salehi S. Preparation and characterization of superhydrophobic melamine and melaminederived carbon sponges modified with reduced graphene oxide-TiO2 nanocomposite as oil absorbent materials[J]. Journal of Materials Science, 2020,55(4):1536-1552.
[33]
Zhang C, Wu M B, Wu B H, et al. Solar-driven self-heating sponges for highly efficient crude oil spill remediation[J]. Journal of Materials Chemistry, A. Materials for energy and sustainability, 2018,6(19):8880-8885.
[34]
Wu X, Lei Y, Li S, et al. Photothermal and Joule heating-assisted thermal management sponge for efficient cleanup of highly viscous crude oil[J]. Journal of Hazardous Materials, 2021,403:124090.
[35]
Zhao P, Yao Q, Zhou G, et al. Green preparation of nonflammable carbonized asphalt-melamine sponges as recyclable oil absorbents[J]. Materials Chemistry and Physics, 2019,226:235-243.
[36]
周明,许春建,余国琮.吸附剂的蒸馏脱附再生方法:中国, CN1065813A[P]. 1992-11-04. Zhou M, Xu C J, Yu G Q. Distillation and desorption regeneration method of adsorbent:China, CN1065813A[P]. 1992-11-04.
[37]
沈万慈,王鲁宁,郑永平,等.一种油污染吸附剂的制备及其回收再生方法:中国, CN1579615[P]. 2005-02-16. Shen W C, Wang L N, Zheng Y P, et al. Preparation of oil pollution adsorbent and regeneration method thereof:China, CN1579615[P]. 2005-02-16.
[38]
黄扬帆.乳液法制备石墨烯基气凝胶及其吸附性能研究[D].青岛:中国石油大学(华东), 2018:36-37. Huang Y F. Preparation of graphene-based aerogel by emulsion method and its adsorption performance[D]. Qingdao:China University of Petroleum (East China), 2018:36-37.