Adsorption breakthrough of binary VOCs on polymeric resins

YU Yan-song; WU Liu-yan; LIU Hui-juan; LONG Chao

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China Environmental Science ›› 2020, Vol. 40 ›› Issue (5) : 1982-1990.

Air Pollution Control

Adsorption breakthrough of binary VOCs on polymeric resins

YU Yan-song, WU Liu-yan, LIU Hui-juan, LONG Chao

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Abstract

In this work, adsorption breakthrough curves of single component and binary n-pentane and cyclohexane on hypercrosslinked polymeric resin (H-resin) and macroporous polymeric resin (M-resin) were investigated, respectively. The results showed that adsorption of n-pentane and cyclohexane on two polymeric resins was mainly based on the dispersion force. Polymeric resins exhibited the higher adsorption capacity for cyclohexane, which had a higher molar polarization. For adsorption of binary n-pentane and cyclohexane on H-resin, the phenomenon of "roll-up" (C/C₀>1for n-pentane) was observed in the breakthrough curves since H-resin had stronger adsorption affinity to cyclohexane than to n-pentane. Moreover, the higher the concentration of cyclohexane was, the more significant the "roll-up" was. In addition, the competition phenomenon became insignificant with increasing the adsorption temperature from 30 to 50℃. However, co-adsorption was always observed for binary adsorption of n-pentane and cyclohexane on M-resin because M-resin, whose pore was mainly distributed in the region of macropore and mesopore, had similar adsorption affinity to cyclohexane and n-pentane.

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adsorption resin / breakthrough curve / competitive adsorption / volatile organic compounds

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YU Yan-song, WU Liu-yan, LIU Hui-juan, LONG Chao. Adsorption breakthrough of binary VOCs on polymeric resins[J]. China Environmental Science. 2020, 40(5): 1982-1990

References

[1] 黄维秋,吕成,郭淑婷,等.油气排放及回收的研究进展[J]. 石油学报(石油加工), 2019,35(2):421-432. Huang W Q, Lv C, Guo S T, et al. Research progress on oil vapor emission and recovery[J]. Acta Petrolei Sinica (Petroleum Processing Section), 2019,35(2):421-432.
[2] 陈永坤.几种油气回收处理技术的介绍和比较[J]. 广东化工, 2017,44(8):118-119. Chen Y K. Introduction and comparison of several oil gas recovery and treatment technologies[J]. Guangdong Chemical Industry, 2017, 44(8):118-119.
[3] 张晓露,鞠峰,栾辉,等.轻烃类VOCs在活性炭上的动态吸附行为[J]. 化工环保, 2018,38(4):437-444. Zhang X L, Ju F, Luan H, et al. Dynamic adsorption behavior of light hydrocarbon VOCs on activated carbon[J]. Environmental Protection of Chemical Industry, 2018,38(4):437-444.
[4] 李士生,刘宇喆,焦婷,等.活性炭孔结构及表面特性对油气吸附性能的影响[J]. 炭素技术, 2019,38(3):25-28. Li S S, Liu Y Z, Jiao T, et al. Influences of pore structure and surface properties of activated carbon on adsorption behavior of gasoline vapors[J]. Carbon Techniques, 2019,38(3):25-28.
[5] Zhang X, Gao B, Creamer A E, et al. Adsorption of VOCs onto engineered carbon materials:A review[J]. Journal of Hazardous Materials, 2017,338:102-123.
[6] 赵海洋,卢晗锋,姜波,等.挥发性有机物在活性炭纤维上的吸附和电致热脱附[J]. 中国环境科学, 2016,36(7):1981-1987. Zhao H Y, Lu H F, Jiang B, et al. Adsorption and electro-thermal desorption of VOCs on activated carbon fibers[J]. China Environmental Science, 2016,36(7):1981-1987.
[7] Wang G, Dou B, Zhang Z, et al. Adsorption of benzene, cyclohexane and hexane on ordered mesoporous carbon[J]. Journal of Environmental Sciences, 2015,30(4):65-73.
[8] 孙政.活性炭对有机气体的选择性吸附研究[D]. 长沙:中南大学, 2011. Sun Z. Research on selective adsorption of VOCs on activated carbon[D]. Changsha:Central South University, 2011.
[9] Lillo-Rodenas M A, Fletcher A J, Thomas K M, et al. Competitive adsorption of a benzene-toluene mixture on activated carbons at low concentration[J]. Carbon, 2006,44(8):1455-1463.
[10] Ouzzine M, Romero-Anaya A J, Lillo-Rodenas M A, et al. Spherical activated carbons for the adsorption of a real multicomponent VOC mixture[J]. Carbon, 2019,148:214-223.
[11] Azambre B, Westermann A, Finqueneisel G, et al. Adsorption and desorption of a model hydrocarbon mixture over HY zeolite under dry and wet conditions[J]. The Journal of Physical Chemistry C, 2015, 119(1):315-331.
[12] Ramanathan K, Koch C K, Oh S H. Kinetic modeling of hydrocarbon adsorbers for gasoline and ethanol fuels[J]. Chemical Engineering Journal, 2012,207-208:175-194.
[13] 张婷.活性炭在油气回收的应用研究[D]. 北京:北京化工大学, 2017. Zhang T. The application of activated carbon in oil and gas recovery[D]. Beijing:Beijing University of Chemical Technology, 2017.
[14] Long C, Yu W H, Li A M. Adsorption of n-hexane vapor by macroporous and hypercrosslinked polymeric resins:Equilibrium and breakthrough analysis[J]. Chemical Engineering Journal, 2013,221:105-110.
[15] Ghafari M, Atkinson J D. Impact of styrenic polymer one-step hyper-cross-linking on volatile organic compound adsorption and desorption performance[J]. Journal of Hazardous Materials, 2018, 351(5):117-123.
[16] 黄海凤,顾勇义,殷操,等.高分子树脂与介孔分子筛吸附-脱附VOCs性能对比[J]. 中国环境科学, 2012,32(1):62-68. Huang H F, Gu Y Y, Yin C, et al. The adsorption-desorption performance of VOCs onto polymer resin and mesoporous molecular sieves[J]. China Environmental Science, 2012,32(1):62-68.
[17] Liu H J, Yu Y S, Shao Q, et al. Porous polymeric resin for adsorbing low concentration of VOCs:Unveiling adsorption mechanism and effect of VOCs' molecular properties[J]. Separation and Purification Technology, 2019,228:116-126.
[18] Jia L, Ma J, Shi Q, et al. Prediction of adsorption equilibrium of VOCs onto hyper-cross-linked polymeric resin at environmentally relevant temperatures and concentrations using inverse gas chromatography[J]. Environmental Science & Technology, 2017,51(1):522-530.
[19] Zhou B, Sun B, Qiu W, et al. Adsorption/desorption of toluene on a hypercrosslinked polymeric resin in a highly humid gas stream[J]. Chinese Journal of Chemical Engineering, 2019,27(4):863-868.
[20] Shi Q Y, Yang X Y, Wu L Y, et al. Binary adsorption equilibrium and breakthrough of toluene and cyclohexane on macroporous and hypercrosslinked polymeric resins[J]. Microporous and Mesoporous Materials, 2018,271:73-82.
[21] 杨新玉,史秋怡,龙超.吸附树脂吸附多组分VOCs的动力学特性及预测[J]. 中国环境科学, 2019,39(5):1830-1837. Yang X Y, Shi Q Y, Long C. Adsorption kinetics and prediction of multicomponent VOCs on polymeric resins[J]. China Environmental Science, 2019,39(5):1830-1837.
[22] Jia L, Yu W, Long C, et al. Adsorption equilibrium and dynamics of gasoline vapors onto polymeric adsorbents[J]. Environmental Science and Pollution Research, 2014,21(5):3756-3763.
[23] Yoon Y H, Nelson J H. Application of Gas Adsorption Kinetics-II. A theoretical model for respirator cartridge service life and its practical applications[J]. AIHAJ, 1984,45(8):517-524.
[24] Zhao Y, Feng Y, Zhang X. Selective adsorption and selective transport diffusion of CO₂-CH₄binary mixture in coal ultramicropores[J]. Environmental Science & Technology, 2016,50(17):9380-9389.
[25] 傅献彩,沈文霞,姚天扬,等.物理化学[M]. 北京:高等教育出版社, 2006. Bo X C, Shen W X, Yao T Y, et al. Physical chemistry[M]. Beijing:Higher Education Press, 2006.
[26] 赵振国.吸附作用应用原理[M]. 北京:化学工业出版社, 2005. Zhao Z G. Application principle of adsorption[M]. Beijing:Chemical Industry Press, 2005.
[27] 近藤精一,石川达雄,安部郁夫,等.吸附科学[M]. 北京:化学工业出版社, 2006. Kondo S, Ishikawa T, Abe I, et al. Adsorption Science[M]. Beijing:Chemical Industry Press, 2006.