碳气凝胶的制备及其对极性农药的吸附性能

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Abstract The wood pulp fibers were pretreated with the mechanical ball-milling combined with TEMPO oxidation technology, and then were applied to prepare the carbon aerogels under the high-temperature pyrolysis. The morphology, element composition, special surface area, pore structure and surface functional groups of carbon aerogels were all analyzed, and their adsorption properties were evaluated by cationic imidacloprid (IMI) and anionic 2,4-D. The results showed that modification with mechanical ball-milling combined with TEMPO oxidation could significantly increase the contents of pores, surface C=O functional groups, and polarity of carbon aerogels, and reduce their layer thickness and aromaticity. Their highest specific surface area was over 2631m²/g. The adsorption isotherms of IMI and 2,4-D on carbon aerogels could be well described by the Freundlich model. The main adsorption mechanism of IMI on carbon aerogels was cation/p/π-π electron donor-acceptor interactions, hydrogen bonding, pore filling, electrostatic attraction, while the adsorption of anionic 2,4-D on prepared carbon aerogels was mainly restrained by the electrostatic repulsion. The maximal adsorption capacity of IMI and 2,4-D of the prepared carbon aerogels were 437mg/g and 286mg/g, respectively. Therefore, carbon aerogels modified with the mechanical ball-milling combined with TEMPO oxidation technology had the great potential in the field of adsorption removal of organic pollutants in water.

Key words： mechanical ball-milling TEMPO oxidation carbon aerogels adsorption polar pesticide

Received: 22 September 2020

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X703

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	SONG Dong-bao
	XUE Bing
	HUANG Peng
	ZHANG Peng
	SUN Hong-wen

Cite this article:

SONG Dong-bao,XUE Bing,HUANG Peng等. Carbon aerogels: Preparation and adsorption properties to polar pesticides[J]. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(5): 2170-2178.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2021/V41/I5/2170

[1]	孙红文,應光国.环境中的新兴污染物研究[J]. 环境化学, 2018, 37(8):1681-1682. Sun H W, Ying G G. Research on emerging pollutants in the environment[J]. Environmental Chemistry, 2018,37(8):1681-1682.
[2]	Sharma V K, Feng M. Water depollution using metal-organic frameworks-catalyzed advanced oxidation processes:A review[J]. Journal of Hazardous Materials, 2019,372(15):3-16.
[3]	Zhang X Y, Miao X D, Xiang W, et al. Ball milling biochar with ammonia hydroxide or hydrogen peroxide enhances its adsorption of phenyl volatile organic compounds (VOCs)[J]. Journal of Hazardous Materials, 2020,403:123540.
[4]	Zhang P, Liu A J, Huang P, et al. Sorption and molecular fractionation of biochar-derived dissolved organic matter on ferrihydrite[J]. Journal of Hazardous Materials, 2020,392:122260.
[5]	Zhang P, Sun H W, Ren, C, et al. Sorption mechanisms of neonicotinoids on biochars and the impact of deashing treatments on biochar structure and neonicotinoids sorption[J]. Environmental Pollution, 2018,234:812-820.
[6]	龙昊宇,黄彬彬,翁白莎,等.MnO2@Fe3O4/石墨烯复合材料对水中Pb(Ⅱ)的吸附[J]. 中国环境科学, 2020,40(7):2888-2900. Long H Y, Huang B B, Weng B S, et al. Adsorption properties of MnO2@Fe3O4/reduced graphene oxide composites for Pb(Ⅱ) from water solution[J]. China Environmental Science, 2020,40(7):2888-2900.
[7]	吴利瑞,张蓝心,于飞,等.氨基化碳纳米管/石墨烯气凝胶对甲醛吸附研究[J]. 中国环境科学, 2015,35(11):3251-3256. Wu L R, Zhang L X, Yu F, et al. Facile composite of amino carbon nanotubes/graphene:preparation and adsorption for gaseous formaldehyde[J]. China Environmental Science, 2015,35(11):3251-3256.
[8]	Lee J H, Park S J. Recent advances in preparations and applications of carbon aerogels:A review[J]. Carbon, 2020,163:1-18.
[9]	Sam D K, Sam E K, Lv X, et al. Application of biomass-derived nitrogen-doped carbon aerogels in electrocatalysis and supercapacitors[J]. Chemelectrochem, 2020,7(18):3695-3712.
[10]	Sun H, Xu Z, Gao C, et al. Multifunctional, ultra-flyweight, synergistically assembled carbon aerogels[J]. Advanced Materials, 2013,25(18):2554-2560.
[11]	Chen W, Zhang Q, Uetani K, et al. Sustainable carbon aerogels derived from nanofibrillated cellulose as high-performance absorption materials[J]. Advanced Materials Interfaces, 2016,3(10):1-9.
[12]	Wu Z, Zhao D. Ordered mesoporous materials as adsorbents[J]. Chemical Communications, 2011,47(12):3332-3338.
[13]	Yin Z, Zhu J, He Q, et al. Graphene-based materials for solar cell applications[J]. Advanced Energy Materials, 2014,4(1):1-19.
[14]	Cai J, Kimura S, Wada M, et al. Nanoporous cellulose as metal nanoparticles support[J]. Biomacromolecules, 2009,10(1):87-94.
[15]	杨陈,林燕萍,李永贵.纳米纤维素材料研究进展[J]. 化工新型材料, 2020,48(10):232-235. Yang C, Lin Y P, Li Y G. Research on advance in nanocellulose material[J]. New Chemical Materials, 2020,48(10):232-235.
[16]	Bondeson D, Mathew A, Oksman K. Optimization of the isolation of nanocrystals from microcrystalline cellulose by acid hydrolysis[J]. Cellulose, 2006,13(2):171-180.
[17]	Hokkanen S, Bhatnagar A, Sillanpaa M. A review on modification methods to cellulose-based adsorbents to improve adsorption capacity[J]. Water Research, 2016,91:156-173.
[18]	Zhang N, Zang, G L, Shi C, et al. A novel adsorbent TEMPO-mediated oxidized cellulose nanofibrils modified with PEI:Preparation, characterization, and application for Cu(Ⅱ) removal[J]. Journal of Hazardous Materials, 2016,316:11-18.
[19]	吴清林,梅长彤,韩景泉,等.纳米纤维素制备技术及产业化现状[J]. 林业工程学报, 2018,3(1):1-9. Wu Q L, Mei C T, Han J Q, et al. Preparation technology and industrialization status of nanocellulose[J]. Journal of Forestry Engineering, 2018,3(1):1-9.
[20]	邱文龙,王仲孚,黄琳娟.2,2,6,6-四甲基哌啶氧自由基氧化糖类物质伯羟基研究进展[J]. 化学通报, 2007,70(1):29-33. Qiu W L, Wang Z F, Huang L J. Progress on 2,2,6,6-Tetramethylpiperineoxyl-mediated Oxidation of the Primary Alcohol of Carbohydrate[J]. Chemistry, 2007,70(1):29-33.
[21]	戴磊,龙柱,张丹.TEMPO氧化纤维素纳米纤维的制备及应用研究进展[J]. 材料工程, 2015,43(8):84-91. Dai L, Long Z, Zhang D. Research progress in preparation and application of TEMPO-oxidized cellulose nanofibers[J]. Journal of Materials Engineering, 2015,43(8):84-91.
[22]	张欢,戴宏杰,陈媛,等.离子液体-球磨法制备柠檬籽纤维素纳米纤丝及其结构表征[J]. 食品科学, 2020:1-12. Zhang H, Dai H J, Chen Y, et al. Preparation and structure characterization of lemon seed cellulose nanofibrils based on ionic liquid-ball milling method[J]. Food Science, 2020:1-12.
[23]	Yue D, Lin X,Wang D, et al. Modulating the defects of graphene blocks by ball-milling for ultrahigh gravimetric and volumetric performance and fast sodium storage[J]. Energy Storage Materials, 2020,30:287-295.
[24]	Pirich C L, Picheth G F, Machado J P E, et al. Influence of mechanical pretreatment to isolate cellulose nanocrystals by sulfuric acid hydrolysis[J]. International Journal of Biological Macromolecules, 2019,130:622-626.
[25]	Zhao H, Kwak J H, Wang Y, et al. Effects of crystallinity on dilute acid hydrolysis of cellulose by cellulose ball-milling study[J]. Energy & Fuels, 2006,20(2):807-811.
[26]	Li S C, Hu B C, Ding Y W, et al. Wood-derived ultrathin carbon nanofiber aerogels[J]. Angewandte Chemie-International Edition, 2018,57(24):7085-7090.
[27]	Saito T, Okita Y, Nge T T, et al. TEMPO-mediated oxidation of native cellulose:Microscopic analysis of fibrous fractions in the oxidized products[J]. Carbohydrate Polymers, 2006,65(4):435-440.
[28]	Isogai A, Saito T, Fukuzumi H. TEMPO-oxidized cellulose nanofibers[J]. Nanoscale, 2011,3(1):71-85.
[29]	黄山,汪楠,张月,等.机械球磨处理对麻竹笋壳膳食纤维理化性质及结构的影响[J]. 食品与发酵工业, 2020,46(5):115-120. Huang S, Wang N, Zhang Y, et al. Effect of mechanical ball milling on physicochemical properties and structure of Dendrocalamus latiflorus shell dietary fiber[J]. Food and Fermentation Industries, 2020,46(5):115-120.
[30]	Sun B, Yuan Y, Li H, et al. Waste-cellulose-derived porous carbon adsorbents for methyl orange removal[J]. Chemical Engineering Journal, 2019,371:55-63.
[31]	Chen J, Yu X, Li C, et al. Removal of tetracycline via the synergistic effect of biochar adsorption and enhanced activation of persulfate[J]. Chemical Engineering Journal, 2020,382:122916.
[32]	Jiang T Y, Jiang J, Xu R K, et al. Adsorption of Pb(Ⅱ) on variable charge soils amended with rice-straw derived biochar[J]. Chemosphere, 2012,89(3):249-256.
[33]	Lee J W, Kidder M, Evans B R, et al. Characterization of biochars produced from cornstovers for soil amendment[J]. Environmental Science & Technology, 2010,44(20):7970-7974.
[34]	Isogai T, Saito T, Isogai A. TEMPO electromediated oxidation of some polysaccharides including regenerated cellulose fiber[J]. Biomacromolecules, 2010,11(6):1593-1599.
[35]	Chen J, Yu X,Li C, et al. Removal of tetracycline via the synergistic effect of biochar adsorption and enhanced activation of persulfate[J]. Chemical Engineering Journal, 2020,382:122916.
[36]	Jiang T Y, Jiang J, Xu R K, et al. Adsorption of Pb(Ⅱ) on variable charge soils amended with rice-straw derived biochar[J]. Chemosphere, 2012,89(3):249-256.
[37]	Lee J W, Kidder M, Evans B R, et al. Characterization of biochars produced from cornstovers for soil amendment[J]. Environmental Science & Technology, 2010,44(20):7970-7974.
[38]	Isogai T, Saito T, Isogai A. TEMPO electromediated oxidation of some polysaccharides including regenerated cellulose fiber[J]. Biomacromolecules, 2010,11(6):1593-1599.
[39]	Yoong L, Chong F K, Dutta B K. Development of copper-doped TiO2 photocatalyst for hydrogen production under visible light[J]. Energy, 2009,34(10):1652-1661.
[40]	Zhang P, Sun H W, Min L J, et al. Biochars change the sorption and degradation of thiacloprid in soil:Insights into chemical and biological mechanisms[J]. Environmental Pollution, 2018,236:158-167.
[41]	Zahoor M, Mahramanlioglu M. Adsorption of imidacloprid on powdered activated carbon and magnetic activated carbon[J]. Chemical & Biochemical Engineering Quarterly, 2011,25(1):55-63.
[42]	Zhao R L, Ma X X, Xu J Q, et al. Removal of the pesticide imidacloprid from aqueous solution by biochar derived from peanut shell[J]. Bioresource, 2018,13(3):5656-5669.
[43]	Liu W, Yang Q, Yang Z L, et al. Adsorption of 2,4-D on magnetic graphene and mechanism study[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2016,509:367-375.
[44]	Amiri M J, Roohi R, Arshadi M, et al. 2,4-D adsorption from agricultural subsurface drainage by canola stalk-derived activated carbon:insight into the adsorption kinetics models under batch and column conditions[J]. Environmental Science and Pollution Research, 2020,27(14):16983-16997.