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Study on the formation mechanism of an ozone pollution event in Northeast Qinghai |
DOU Xiao-yan1, GAO Hai-peng1, CHEN Ke1, ZHANG Zhi-jun1, XU Xun1, LI Ming-ge2, TAO Jing-hua2, CHEN Liang-fu2,3 |
1. State Environmental Protection Key Laboratory of Tibetan Plateau Eco-Environmental Monitoring and Assessment, Qinghai Key Laboratory of Eco-Environmental Monitoring and Assessment, Qinhai Eco-environmental Monitoring Center, Xining 810007, China; 2. State Key Laboratory of Remote Sensing Science, Aerospace Information Research Institute Chinese Academy of Sciences, Beijing 100101, China; 3. University of Chinese Academy of Sciences, Beijing 100049, China |
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Abstract Based on surface observation, satellite and reanalysis data, an ozone pollution process from July 25th to August 3 rd, 2021 in northeast Qinghai was analyzed. The results showed that the ozone concentration of each site gradually increased since July 26 th. A large-scale persistent regional pollution evolved from July 30 th to August 2 nd, with the regional averaged ozone concentration 20.9% higher than the monthly average. On the one hand, the surface radiation of the region was strong during this period, the temperature rose significantly, and the average increase of the sites exceeded 10℃, which is conducive to photochemical reactions of the ozone production. At the same time, the surface diffusion conditions were poor due to the continuous weak wind speed, causing the accumulation of pollutants. On the other hand, the region was mainly controlled by strong downdraft on the upper air and decreased relative humidity at surface from July 26 th to 31 st. The ozone concentration increased significantly, with the concentration exceeding 170μg/m3 at 55.7% of the sites in the peak of pollution. The obvious effect of ozone vertical transport from the top of troposphere to near surface is the immediate cause of ozone pollution of the region.
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Received: 30 November 2022
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[1] Sicard P, Anav A, De Marco A, et al. Projected global ground-level ozone impacts on vegetation under different emission and climate scenarios [J].Atmospheric Chemistry and Physics, 2017,17(19): 12177-12196. [2] Avnery S, Mauzerall D L, Liu J F, et al. Global crop yield reductions due to surface ozone exposure: 1. Year 2000 crop production losses and economic damage [J].Atmospheric Environment, 2011,45(13): 2284-2296. [3] Lefohn A S, Malley C S, Simon H, et al. Responses of human health and vegetation exposure metrics to changes in ozone concentration distributions in the European Union, United States, and China [J].Atmospheric Environment, 2017,152:123-145. [4] 曾贤刚,阮芳芳,姜艺婧.中国臭氧污染的空间分布和健康效应[J].中国环境科学, 2019,39(9):4025-32. Zeng X G, Ruan F F, Jiang Y J. Spatial distribution and health effects of ozone pollution in China [J].China Environmental Science, 2019, 39(9):4025-4032. [5] Bell M L, Goldberg R, Hogrefe C, et al. Climate change, ambient ozone, and health in 50US cities [J].Climatic Change, 2007,82(1/2): 61-76. [6] Wang Y, Gao W, Wang S, et al. Contrasting trends of PM2.5 and surface ozone concentrations in China from 2013 to 2017[J].National Science Review, 2020,7(8):1331-1339. [7] Li K, Jacob D J, Shen L, et al. Increases in surface ozone pollution in China from 2013to 2019: anthropogenic and meteorological influences [J].Atmospheric Chemistry and Physics, 2020,20(19):11423-11433. [8] Wang T, Xue L K, Brimblecombe P, et al. Ozone pollution in China: A review of concentrations, meteorological influences, chemical precursors, and effects [J].Science of the Total Environment, 2017,575: 1582-1596. [9] Gong C, Liao H, Yue X, et al. Impacts of ozone-vegetation interactions on ozone pollution episodes in North China and the Yangtze River Delta [J].Geophysical Research Letters, 2021,48(12). [10] Jacob D J, Winner D A. Effect of climate change on air quality [J].Atmospheric Environment, 2009,43(1):51-63. [11] 肖致美,李鹏,孔君,等.天津市持续高温强光照天气下臭氧污染差异性[J].中国环境科学, 2023,43(7):3322-3330. Xiao Z M, Li P, Kong J, et al. Difference of ozone pollution under the continuous high temperature and strong sunlight weather in Tianjin [J].China Environmental Science, 2023,43(7):3322-3330. [12] Jeong J I, Park R J. Effects of the meteorological variability on regional air quality in East Asia [J].Atmospheric Environment, 2013, 69:46-55. [13] Fix M J, Cooley D, Hodzic A, et al. Observed and predicted sensitivities of extreme surface ozone to meteorological drivers in three US cities [J].Atmospheric Environment, 2018,176:292-300. [14] 李飞,孔少杰,屈志光,等.中国臭氧时空分异及热点城市群气象关联特征[J].中国环境科学, 2023,43(4):1539-1549. Li F, Kong S J, Qu Z G, et al. Spatiotemporal differentiation of ozone pollution in Chinese cities and meteorological correlation among the identified hot urban agglomeration during 2018 to 2020[J].China Environmental Science, 2023,43(4):1539-1549. [15] Kavassalis S C, Murphy J G. Understanding ozone-meteorology correlations: A role for dry deposition [J].Geophysical Research Letters, 2017,44(6):2922-2931. [16] Zhang H, Wang Y, Hu J, et al. Relationships between meteorological parameters and criteria air pollutants in three megacities in China [J].Environmental Research, 2015,140:242-254. [17] 刘微,康平,张小玲,等.青藏高压系统对川渝春夏臭氧污染的影响机制[J].中国环境科学, 2021,41(4):1511-1520. Liu W, Kang P, Zhang X L, et al. Mechanism of Qinghai-Tibet high pressure system on spring and summer ozone pollution over Sichuan-Chongqing area [J].China Environmental Science, 2021, 41(4):1511-1520. [18] Liao Z, Gao M, Sun J, et al. The impact of synoptic circulation on air quality and pollution-related human health in the Yangtze River Delta region [J].Science of the Total Environment, 2017,607:838-846. [19] Zhou D, Ding A, Mao H, et al. Impacts of the East Asian monsoon on lower tropospheric ozone over coastal South China [J].Environmental Research Letters, 2013,8(4):044011. [20] 张莹,许建敏,汪瑶,等.京津冀地区2015~2020年臭氧持续污染事件特征、气象影响及潜在源区分析[J].中国环境科学, 2023, 43(6):2714-2721. Zhang Y, Xu J M, Wang Y, et al. Characteristics, meteorological impacts and potential sources of persistent ozone pollution events in Beijing-Tianjin-Hebei Region during 2015~2020[J].China Environmental Science, 2023,43(6):2714-2721. [21] Ni R, Lin J, Yan Y, et al. Foreign and domestic contributions to springtime ozone over China [J].Atmospheric Chemistry and Physics, 2018,18(15):11447-11469. [22] Zhang J, Li D, Bian J, et al. Deep stratospheric intrusion and Russian wildfire induce enhanced tropospheric ozone pollution over the northern Tibetan Plateau [J].Atmospheric Research, 2021,259:105662. [23] Lin M, Fiore A M, Cooper O R, et al. Springtime high surface ozone events over the western United States: Quantifying the role of stratospheric intrusions [J].Journal of Geophysical Research: Atmospheres, 2012,117(D21). 2011AGUFM.A41C0099F. [24] Li D, Vogel B, Müller R, et al. High tropospheric ozone in Lhasa within the Asian summer monsoon anticyclone in 2013: influence of convective transport and stratospheric intrusions [J].Atmospheric Chemistry and Physics, 2018,18(24):17979-17994. [25] 马静,燕莹莹,孔少飞,等.武汉军运会前后臭氧及其前体物的特征和来源[J].中国环境科学, 2022,42(7):3023-3032. Ma J, Yan Y Y, Kong S F, et al. Characteristics and sources of ozone and its precursors around the Wuhan Military Games [J].China Environmental Science, 2022,42(7):3023-32. [26] Li K, Jacob D J, Liao H, et al. Anthropogenic drivers of 2013~2017 trends in summer surface ozone in China [J].Proceedings of the National Academy of Sciences of the United States of America, 2019, 116(2):422-427. [27] 曹晓云,祁栋林,肖建设,等.基于卫星观测的青海高原对流层臭氧时空分布特征研究[J].环境科学学报, 2021,41(5):1640-1648. Cao X Y, Qi D L, Xiao J S, et al. Temporal and spatial distribution characteristics of tropospheric ozone in Qinghai Plateau based on satellite observations [J].Acta Scientiae Circumstantiae, 2021,41(5): 1640-1648. [28] 周秀骥,李维亮,陈隆勋,等.青藏高原地区大气臭氧变化的研究[J].气象学报, 2004,(5):513-527. Zhou X J, Li W L, Chen L X, et al. Study of ozone change over Tibetan Plateau [J].Acta Meteorologica Sinica, 2004,(5):513-527. [29] 谈昌蓉,郭晓宁,陈奇,等.西宁近地面臭氧特征及其影响因素[J].干旱气象, 2019,37(1):31-39. Tan C R, Guo X N, Chen Q, et al. Study on surface ozone characteristics and its influencing factors in Xining [J].Journal of Arid Meteorology, 2019,37(1):31-39. [30] 王彩红,张惠芳,尼霞次仁,等.青藏高原典型城市拉萨市近地面臭氧污染特征[J].中国环境监测, 2017,33(4):159-66. Wang C H, Zhang H F, Ni X C R, et al. The pollution characteristics of surface ozone in Lhasa-Typical City over the Tibetan Plateau [J].Environmental Monitoring in China, 2017,33(4):159-166. [31] Yin X, Kang S, De Foy B, et al. Surface ozone at Nam Co in the inland Tibetan Plateau: variation, synthesis comparison and regional representativeness [J].Atmospheric Chemistry and Physics, 2017,17(18):11293-11311. [32] Barrero M A, Orza J A, Cabello M, et al. Categorisation of air quality monitoring stations by evaluation of PM(10) variability [J].Science of the Total Environment, 2015,524-525:225-236. [33] Song C, Wu L, Xie Y, et al. Air pollution in China: Status and spatiotemporal variations [J].Environmental Pollution, 2017,227: 334-347. [34] GB 3095-2012环境空气质量标准[S].GB 3095-2012 Ambient air quality standards [S]. [35] Hoskins B J, Mcintyre M E, Robertson A W. On the use and significance of isentropic potential vorticity maps [J].Quarterly Journal of the Royal Meteorological Society, 1985,111(470):877-946. [36] Appenzeller C, Holton J R, Rosenlof K H. Seasonal variation of mass transport across the tropopause [J].Journal of Geophysical Research-Atmospheres, 1996,101(D10):15071-15078. [37] Baray J L, Ancellet G, Taupin F G, et al. Subtropical tropopause break as a possible stratospheric source of ozone in the tropical troposphere [J].Journal of Atmospheric and Solar-Terrestrial Physics, 1998,60(1): 27-36. |
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