水钠锰矿界面铁矿物形成对Sb迁移转化的影响

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Abstract The effects of the formation of iron minerals at the interface of birnessite (MnO₂) on the environmental behavior of antimony (Sb) were systematically studied in this paper. Many nanoparticles and abundant pore structure was found on the obtained Fe-Mn binary oxide (Fe-MnO₂). HRTEM and XRD analysis indicated that the nanoparticles anchored on MnO₂ was ferrihydrite. The iron minerals formed on MnO₂ enhanced adsorption performance for Sb(III) and Sb(V). The adsorption capacities of Sb(III) and Sb(V) by Fe-MnO₂ were 397.4 and 247.7mg/g, respectively, which was much higher than that of MnO₂ for Sb(III) and Sb(V) immobilization (342.0 and 71.8mg/g). The chemical bond complexation was the dominant mechanism for Sb(III) and Sb(V) immobilization. The electrostatic adsorption played an important role in Sb(V) immobilization. The ferrihydrite made a significant contribution for reducing the mobility of Sb. MnO₂ played the critical role in the transformation of Sb(III) to Sb(V). This study not only reveals the formation mechanism of Fe-Mn binary oxide, but also helps to further understand the migration and transformation behavior of Sb in the environment.

Key words： birnessite iron minerals formation antimony migration transformation

Received: 28 August 2024

PACS:

X53

Corresponding Authors: 陈梅青,副教授,cmq@gdut.edu.cn E-mail: cmq@gdut.edu.cn

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	LI Wan-xia
	CHEN Mei-qing
	LIU Yi-an
	WU Ping-xiao

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LI Wan-xia,CHEN Mei-qing,LIU Yi-an等. The influence of the formation of iron minerals at the interface of birnessite on the migration and transformation of Sb[J]. CHINA ENVIRONMENTAL SCIENCECE, 2025, 45(3): 1341-1350.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2025/V45/I3/1341

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