生物质灰滤材磷素吸附性能研究

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Abstract A new block filter material with well-developed pores and stable chemical properties was prepared from a biomass ash by short-term and high-temperature sintering. The phosphorus adsorption properties, as well as the kinetics and thermodynamic behaviors, of this material were investigated in this paper. The results of the static adsorption experiments show that the biomass ash filter achieved higher phosphorus adsorption per unit under conditions of higher initial phosphorus concentration, higher reaction temperature, longer adsorption time, or lower solid-liquid ratio. Among these parameters, the solid-liquid ratio was the primary controlling parameter affecting phosphorus adsorption by the filter material. The maximum adsorption per unit of the filter material reached 7.72mg/g, when the initial concentration of phosphorus was 90mg/L, the reaction temperature was 55℃, the adsorption time was 1250min, the pH was 3, and the solid-liquid ratio was 1:200(g:mL). The surface of the material exhibited a heterogeneous structure, and its phosphorus adsorption was primarily driven by multilayer physical endothermic adsorption, supplemented by monolayer or multilayer spontaneous chemical adsorption. Under the dynamic adsorption conditions, the phosphorus adsorption capacity of this filter material per unit was 9.8, 22.27 and 27.22 times that of three common commercial filter materials, including coconut shell biochar, ceramsite and natural zeolite, respectively. This indicates excellent adsorption properties, enabling water purification while achieving biomass ash disposal and recycling, making it highly valuable for promotion.

Key words： biomass ash filter media phosphorus adsorption kinetic modeling thermodynamics

Received: 17 October 2024

PACS:

X712

Corresponding Authors: 刘念,责任作者,副教授,newlion@mail.hzau.edu.cn E-mail: newlion@mail.hzau.edu.cn

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	YU Zi-jun
	YU Jia-hang
	ZHU Jun-yi
	HOU Cun
	QU Zhi-chao
	NIU Wen-juan
	AI Ping
	FENG Yao-ze
	LIU Nian

Cite this article:

YU Zi-jun,YU Jia-hang,ZHU Jun-yi等. Phosphorus adsorption performance of biomass ash filter material[J]. CHINA ENVIRONMENTAL SCIENCECE, 2025, 45(4): 2028-2040.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2025/V45/I4/2028

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