|
|
Quantitative source apportionment of groundwater pollution based on PCA-APCS-MLR |
MENG Li1,2, ZUO Rui1,2, WANG Jin-sheng1,2, YANG Jie1,2, TENG Yan-guo1,2, ZHAI Yuan-zheng1,2, SHI Rong-tao1,2 |
1. College of Water Sciences, Beijing Normal University, Beijing 100875, China;
2. Engineering Research Center of Groundwater Pollution Control and Remediation, Ministry of Education, Beijing 100875, China |
|
|
Abstract Totally 43 groundwater samples were sampled in the Hunhe River alluvial fan, which was a typical industrial area in Shenyang at northeastern China and 16 key groundwater components were analyzed. The main factor of groundwater quality was determined by principal component analysis (PCA) based on water quality grade and characteristics pollutants using water chemistry statistics analysis, and the spatial distribution of different pollution sources was described by ArcGIS software. The contribution of different principal factor to groundwater quality was calculated by absolute principal component score multiple linear regression model (APCS-MLR), and verified accuracyof pollution sources apportionment. Results showed that nitrogen, phosphorus and iron exceeded to groundwater quality standardsignificantly, the evolution of groundwater quality was mainly influenced by human activities. Four main pollution factors were:leaching migration with contribution of 34.21%, agricultural pollution with contribution of 20.13%, geological background with contribution of 13.39% and industrial activities with contribution of 8.97%. The contribution of cumulative variance was 75.64%. The industrial production, domestic sewage discharging and agriculture fertilizer pollution were main pollution sources of groundwater, which were distributed in northwestern and southwestern Shenyang. The pollution of leaching and migration and agriculture pollution affected on the groundwater quality significantly, and the predicted results was consistent with the measured concentration, which indicated that the PCA-APCS-MLR model wasof good pertinence for the distribution of pollution sources and it was suitable for source apportionment for groundwater.
|
Received: 27 March 2017
|
|
|
|
|
[1] |
Louis KB, Freitasa C R, David W. Source apportionment of air pollutants in the Greater Auckland Region of New Zealand using receptor models and elemental, 2017,8(1):101-113.
|
[2] |
Huang F, Wang X, Lou L, et al. Spatial variation and source apportionment of water pollution inQiantang River (China) using statistical techniques.[J]. Water Research, 2010,44(5):1562-1572.6.
|
[3] |
曹阳,滕彦国,王威,等.金积水源地地下水体重金属空间分布及来源[J]. 环境科学与技术, 2013,36(11):163-167.
|
[4] |
林承奇,胡恭任,于瑞莲,等.九龙江近岸表层沉积物重金属污染评价及来源解析[J]. 中国环境科学, 2016,36(4):1218-1225.
|
[5] |
左锐,韦宝玺,王金生,等.基于多元统计分析的地下水水源地污染源识别[J]. 水文地质工程地质, 2012,3(6):17-21.
|
[6] |
刘博,肖长来,梁秀娟,等.吉林市城区浅层地下水污染源识别及空间分布[J]. 中国环境科学, 2015,35(2):457-464.
|
[7] |
陈海洋,滕彦国,王金生,等.基于NMF与CMB耦合应用的水体污染源解析方法[J]. 环境科学学报, 2011,31(2):316-321.
|
[8] |
Haji M G, MelessebA M., Reddic L. Water quality assessment and apportionment of pollution sources using APCS-MLR and PMF receptor modeling techniques in three major rivers of South Florida[J]. Science of The Total Environment, 2016,566-567(1):1552-1567.
|
[9] |
瞿明凯,李卫东,张传荣,等.基于受体模型和地统计学相结合的土壤镉污染源解析[J]. 中国环境科学, 2013,33(5):854-860.
|
[10] |
Duan W, He B, Nover D. Water quality assessment and pollution source identification of the eastern Poyang Lake Basin using multivariate statistical methods[J]. Sustainability, 2016,8(2):133-148.
|
[11] |
Thurston G D, SpenglerJ D. A quantitative assessment of source contributions to inhalable particulate matter pollution in metropolitan Boston[J]. Atmospheric Environment, 1985,19(1):9-25.
|
[12] |
杨维,王恩德,李勇,等.浑河冲洪积扇中下游地下水中氮转化与水文地球化学特征的研究[J]. 水文地质工程地质, 2005, 32(2):39-41.
|
[13] |
HJ/T164-2004地下水环境监测技术规范[S]. 2004.
|
[14] |
GB5750-2006生活饮用水标准检验方法[S]. 2004.
|
[15] |
GB/T14848-9地下水质量标准[S]. 2016.
|
[16] |
Yay O D, Alagha O, Tuncel G. Multivariate statistics to investigate metal contamination in surface soil[J]. Journal of Environmental Management, 2008,86(4):581-594.
|
[17] |
Qin R, Y Wu, Z Xu, D Xie, C Zhang. Assessing the impact of natural and anthropogenic activities on groundwater quality in coastal alluvial aquifers of the lower Liaohe River Plain, NE China[J]. Applied Geochemistry, 2013,31(2):142-158..
|
[18] |
张妍,尚金城,于相毅.主成分-聚类复合模型在水环境管理中的应用——以松花江吉林段为例[J]. 水科学进展, 2005,16(4):592-595.
|
[19] |
赵洁,徐宗学,刘星才.辽河河流水体污染源解析[J]. 中国环境科学, 2013,33(5):838-842.
|
[20] |
崔健,都基众,马宏伟,等.基于因子分析的浑河冲洪积扇地浅层地下水水质影响因素辨析[J]. 中国农村水利水电, 2011, 7(4):45-48.
|
[21] |
Chen H, Teng Y, Yue L. Song. Characterization and source apportionment of water pollution in Jinjiang River, China[J]. Environmental Monitoring and Assessment, 2013,185,(11):9639-9650.
|
|
|
|