|
|
|
| Effect of exhaust gas from sintering machines on the concentration of dioxin in soil around a steel plant |
| SUN Bo-fei1, BO Xin2, ZHANG Shang-xuan3, DIAO Xiao-jun2, KAN Hui4, CHENG Ji5, LIU Meng6, WU Peng-cheng7, ZHOU Tian2, HU Xiao-bo1 |
1. Hebei Zhengrun Environmental Technology Co., Ltd., Shijiazhuang 050000, China;
2. The Appraisal Center for Environment and Engineering, Ministry of Environmental Protection, Beijing 100012, China;
3. CISDI Chongqing Environmental Consulting CO., Ltd., Chongqing 400013, China;
4. Academy of Environmental Planning and Design, Nanjing University, Nanjing 210093, China;
5. Trinity Consultants China Office, Hangzhou 310012, China;
6. CSD Water Service Co., Ltd., Beijing 100192, China;
7. Capital University Of Economics And Business, Beijing 100070, China |
|
|
|
|
Abstract In order to investigate the influence of dioxins emitted from iron-steel sintering machines on soil pollution, both monitored data by a steel plant in Hebei Province in 2016 and CALPUFF simulations are used to design a method to estimate the amount of sintering-emitted dioxins that is deposited in the surrounding soil. Results show that the toxicity equivalency quantity (TEQ) of dioxin in exhaust gas from the sintering machines of this steel plant is 0.017~0.025ng-TEQ/Nm3. The emission factor is 0.044~0.081ug-TEQ/t. The concentration of dioxins in three soil samples ranges from 0.82 to 2.4ng/kg, which is consistent with the simulated results by CALPUFF (1.46~3.44ng/kg).
|
|
Received: 27 April 2017
|
|
|
|
|
|
| [1] |
苍大强,魏汝飞,张玲玲,等.钢铁工业烧结过程二噁英的产生机理与减排研究进展[J]. 钢铁, 2014,49(8):1-8.
|
| [2] |
郑明辉,孙阳昭,刘文彬.中国二噁英类持久性有机污染物排放清单研究[M]. 北京:中国环境科学出版社, 2008:10-34.
|
| [3] |
余刚,杨小玲,黄俊.中国二噁英类持久性有机污染物减排控制战略研究[M]. 北京:中国环境科学出版社, 2008:2-3.
|
| [4] |
耿静.二恶英类的控制政策及效果分析[M]. 北京:冶金工业出版社, 2011:65-77.
|
| [5] |
吕亚辉,黄俊,余刚,等.中国二噁英排放清单的国际比较研究[J]. 环境污染与防治, 2008,30(6):71-74.
|
| [6] |
Liu G, Zheng M, Jiang G, et al. Dioxin analysis in China[J]. Trends in analytical chemistry, 2013,46:178-188.
|
| [7] |
黄启飞.重点行业二噁英控制技术手册Ⅱ[M]. 北京:中国环境科学出版社, 2015:18-27.
|
| [8] |
赵春丽,吴铁,伯鑫,等.钢铁行业履行斯德哥尔摩公约对策建议[J]. 环境保护, 2014,8:43-45.
|
| [9] |
Basham J, Whitwell I. Dispersion modeling of dioxin releases from the waste incinerator at Avonmouth, Bristol, UK[J]. Atmospheric Environment, 1999,33(27):3405-3416.
|
| [10] |
Nathalie F,Jeanfrançois V, Eric L, et al. Dispersion modeling as a dioxin exposure indicator in the vicinity of a municipal solid waste incinerator:A validation study[J]. Environmental Science and Technology, 2006,40(7):2149-2155.
|
| [11] |
Trinh H. Validation of the AERMOD air dispersion model:application to congener-specific dioxin deposition from an incinerator in midland, Michigan[J]. Organohalogen Compounds, 2009,71:992-995.
|
| [12] |
齐丽,李楠,任玥,等.北京地区典型二噁英(PCDDs)及多氯联苯(PCBs)的长距离传输潜力-基于TaPL3模型的应用研究[J]. 环境化学, 2013,32(7):1149-1157.
|
| [13] |
李煜婷,金宜英,刘富强. AERMOD模型模拟城市生活垃圾焚烧厂二噁英类物质扩散迁移[J]. 中国环境科学, 2013,33(6):985-992.
|
| [14] |
姚宇坤,赵秋月,孙家仁,等.烟气与环境空气中二恶英的测定与数值模拟[J]. 工业安全与环保, 2014,40(11):78-81.
|
| [15] |
Meng F, Zhang B, Gbor P, et al. Models for gas/particle partitioning, transformation and air/water surface exchange of PCBs and PCDD/Fs in CMAQ[J]. Atmospheric Environment, 2007,41(39):9111-9127.
|
| [16] |
张珏,孟凡,何友江,等.长江三角洲地区大气二噁英类污染物输送-沉降模拟研究[J]. 环境科学研究, 2011,24(12):1394-1402.
|
| [17] |
Li Y, Jiang G, Wang Y, et al. Concentrations, profiles and gas-particle partitioning of polychlorinated dibenzo-p-dioxins and dibenzofurans in the ambient air of Beijing, China[J]. Atmospheric Environment, 2008,42(9):2037-2047.
|
| [18] |
Ding L, Li Y, Wang P, et al. Seasonal trend of ambient PCDD/Fs in Tianjin City, northern China using active sampling strategy[J]. Journal of Environmental Sciences, 2012,24(11):1966-1971.
|
| [19] |
Ren Z, Zhang B, Lu P, et al. Characteristics of air pollution by polychlorinated dibenzo-p-dioxins and dibenzofurans in the typical industrial areas of Tangshan City, China[J]. Journal of Environmental Sciences, 2011,23(2):228-235.
|
| [20] |
Shi X L, Yu W, Fei X, et al. PBCDD/F formation from radical/radical cross-condensation of 2-Chlorophenoxy with 2-Bromophenoxy, 2,4-Dichlorophenoxy with 2,4-Dibromophenoxy, and 2,4,6-Trichlorophenoxy with 2,4,6-Tribromophenoxy[J]. Journal of Hazardous Materials, 2015,295:104-111.
|
| [21] |
Shi X L, Zhang R M, Zhang H J, et al. Influence of water on the homogeneous gas-phase formation mechanism of polyhalogenated dioxins/furans from chlorinated/brominated phenols as precursors[J]. Chemosphere, 2015,137:142-145.
|
| [22] |
刘淑芬,田洪海,任玥,等.我国二噁英污染水平和环境归趋模拟[J]. 环境科学研究, 2010,23(3):261-265.
|
| [23] |
吴宇澄,骆永明,滕应,等.土壤中二噁英的污染现状及其控制与修复研究进展[J]. 土壤, 2006,38(5):509-516.
|
| [24] |
黄伟芳,吴群河.二噁英污染土壤修复技术的研究进展[J]. 广州环境科学, 2006,21(1):29-33.
|
| [25] |
王堃,滑申冰,田贺忠,等.2011年中国钢铁行业典型有害重金属大气排放清单[J]. 中国环境科学, 2015,35(10):2934-2938.
|
| [26] |
伯鑫,赵春丽,吴铁,等.京津冀地区钢铁行业高时空分辨率排放清单方法研究[J]. 中国环境科学, 2015,35(8):2554-2560.
|
| [27] |
Wang L, Lu Y, He G, et al. Factors influencing polychlorinated dibenzo-p-dioxin and polychlorinated dibenzofuran (PCDD/F) emissions and control in major industrial sectors:Case evidence from Shandong Province, China[J]. Journal of Environmental Sciences, 2014,26(7):1513-1522.
|
| [28] |
Tian B, Huang J, Wang B, et al. Emission characterization of unintentionally produced persistent organic pollutants from iron ore sintering process in China[J]. Chemosphere, 2012,89(4):409-415.
|
| [29] |
Die Q, Nie Z, Liu F, et al. Seasonal variations in atmospheric concentrations and gas-particle partitioning of PCDD/Fs and dioxin-like PCBs around industrial sites in Shanghai, China[J]. Atmospheric Environment, 2015,119:220-227.
|
| [30] |
Huang T, Tian C, Zhang K, et al. Gridded atmospheric emission inventory of 2, 3, 7, 8-TCDD in China[J]. Atmospheric Environment, 2015,108:41-48.
|
| [31] |
Basham J, Whitwell I. Dispersion modeling of dioxin releases from the waste incinerator at Avonmouth, Bristol, UK[J]. Atmospheric Environment, 1999,33(27):3405-3416.
|
| [32] |
Nathalie F, Jeanfrançois V, Eric L, et al. Dispersion modeling as a dioxin exposure indicator in the vicinity of a municipal solid waste incinerator:A validation study[J]. Environmental Science and Technology, 2006,40(7):2149-2155.
|
| [33] |
Li Y M, Pu W, Lei D, et al. Atmospheric distribution of polychlorinated dibenzo-p-dioxins, dibenzofurans and dioxin-like polychlorinated biphenyls around a steel plant Area, Northeast China[J]. Chemosphere, 2010,79(79):253-258.
|
| [34] |
HJ77.2-2008环境空气和废气二噁英类的测定同位素稀释高分辨气相色谱-高分辨质谱法[s].
|
| [35] |
HJ/T397-2007固定源废气监测技术规范[s].
|
| [36] |
HJ 77.4-2008土壤和沉积物二噁英类的测定同位素稀释高分辨气相色谱-高分辨质谱法[s].
|
| [37] |
伯鑫,丁峰,徐鹤,等.大气扩散CALPUFF模型技术综述[J]. 环境监测管理与技术, 2009,21(3):9-13.
|
| [38] |
伯鑫. CALPUFF模型技术方法与应用[M]. 北京:中国环境出版社, 2016:1-6.
|
| [39] |
伯鑫,王刚,温柔,等.京津冀地区火电企业的大气污染影响[J]. 中国环境科学, 2015,35(2):364-373.
|
| [40] |
伯鑫,王刚,田军,等. AERMOD模型地表参数标准化集成系统研究[J]. 中国环境科学, 2015,35(9):2570-2575.
|
| [41] |
Wang L C, Lee W J, Tsai P J, et al. Emissions of polychlorinated dibenzo-p-dioxins and dibenzofurans from stack flue gases of sinter plants[J]. Chemosphere, 2003,50(9):1123-1129.
|
| [42] |
俞勇梅,李咸伟,何晓蕾,等.铁矿石烧结过程二噁英类排放机制及其控制技术[M]. 北京:冶金工业出版社, 2014:10-34.
|
| [43] |
GB28662-2012钢铁烧结、球团工业大气污染物排放标准[s].
|
| [44] |
巩宏平,田洪海,周志广,等.钢铁企业排放的烟气及厂区土壤中二噁英类污染研究[J]. 环境保护科学, 2007,33(5):8-10.
|
| [45] |
周志广,田洪海,刘爱民,等.北京市农业区不同使用类型土壤中二噁英类分析[J]. 环境化学, 2010,29(1):18-24.
|
|
|
|
