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Effects of the dosage and dosing methods of CaO2 on the production of short-chain fatty acids produced during anaerobic fermentation of waste activated sludge |
GUI Xiao-shan, XU Chuang, WANG Ze-qian, PING Qian, LI Yong-mei |
State Key Laboratory of Pollution Control and Resources Reuse, College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China |
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Abstract CaO2 was added under mesophilic conditions for the pretreatment of waste activated sludge (WAS) obtained from wastewater treatment plants (WWTP). The effects of CaO2 dosage and dosing methods on the acidification and methane production during anaerobic fermentation were evaluated. The aim was to find the optimum dosage and dosing method of CaO2 for obtaining short chain fatty acids (SCFAs) from WAS. The results indicated that at (35±1)℃, CaO2 addition could remarkably increase pH of the supernatant, thus accelerating the release of organic matters. Given the constant dosage, the once-and-for-all dosing of CaO2 could enhance the solubilization of WAS and the accumulation of SCFAs much more effectively than multiple dosing of CaO2. When CaO2 was dosed at 0.2g/g VSS for once, the acetic acid concentration witnessed its highest level (169mg COD/g VSS) on day 7 and accounted for 71.0% of the total SCFAs, eclipsing all the other acids. Compared with the once-and-for-all dosing method, multiple dosing of CaO2 resulted in less accumulation of SCFA due to weaker inhibition of methane production.
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Received: 09 October 2017
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[1] |
代学民,王霞,马云霞,等.浅谈活性污泥法的发展和演变[J]. 河北建筑工程学院学报, 2004,22(2):25-27.
|
[2] |
裴晓梅,余志亚,朱洪光.我国厌氧发酵处理城市污水剩余污泥研究进展[J]. 中国沼气, 2008,26(1):25-29.
|
[3] |
周爱娟.预处理促进剩余污泥发酵制取短链脂肪酸的效能及机制研究[D]. 哈尔滨:哈尔滨工业大学, 2014.
|
[4] |
张万钦,戚丹丹,吴树彪,等.不同预处理方式对污泥厌氧发酵的影响[J]. 农业机械学报, 2014,45(9):187-198.
|
[5] |
Chen Y, Jiang S, Yuan H, Zhou Q, Gu G. Hydrolysis and acidification of waste activated sludge at different pHs[J]. Water Research, 2007,41(3):683-689.
|
[6] |
张玲玲,陈立,郭兴芳,等.南北方污水处理厂进水水质特性分析[J]. 给水排水, 2012,48(1):45-49.
|
[7] |
Northup A, Cassidy D. Calcium peroxide (CaO2) for use in modified Fenton chemistry[J]. Journal of Hazardous Materials, 2008,152(3):1164-1170.
|
[8] |
Zhang A, Li Y. Removal of phenolic endocrine disrupting compounds from waste activated sludge using UV, H2O2, and UV/H2O2 oxidation processes:Effects of reaction conditions and sludge matrix[J]. Science of The Total Environment, 2014, 493:307-323.
|
[9] |
Li Y, Wang J, Zhang A, Wang L. Enhancing the quantity and quality of short-chain fatty acids production from waste activated sludge using CaO2 as an additive[J]. Water Research, 2015,83:84-93.
|
[10] |
国家环境保护总局《水和废水监测分析方法》编委会.水和废水监测分析方法(第四版)[M]. 中国环境科学出版社, 2002.
|
[11] |
Wang J, Li Y. Synergistic pretreatment of waste activated sludge using CaO2 in combination with microwave irradiation to enhance methane production during anaerobic digestion[J]. Applied Energy, 2016,183:1123-1132.
|
[12] |
Jin Y, Li H, Mahar R B, Wang Z, Nie Y. Combined alkaline and ultrasonic pretreatment of sludge before aerobic digestion[J]. Journal of Environmental Sciences, 2009,21(3):279-284.
|
[13] |
Xiao B, Liu C, Liu J, Guo X. Evaluation of the microbial cell structure damages in alkaline pretreatment of waste activated sludge[J]. Bioresource Technology, 2015;196(Supplement C):109-115.
|
[14] |
Neyens E, Baeyens J, Creemers C. Alkaline thermal sludge hydrolysis[J]. Journal of Hazardous Materials, 2003,97(1-3):295-314.
|
[15] |
Tokumura M, Katoh H, Katoh T, et al. Solubilization of excess sludge in activated sludge process using the solar photo-Fenton reaction[J]. J. Hazard. Mat., 2009,162(2/3):1390-1396.
|
[16] |
Yu G-H, He P-J, Shao L-M, He P-P. Toward understanding the mechanism of improving the production of volatile fatty acids from activated sludge at pH 10.0[J]. Water Research, 2008, 42(18):4637-4644.
|
[17] |
Erden G, Filibeli A. Ozone oxidation of biological sludge:Effects on disintegration, anaerobic biodegradability, and filterability[J]. Environmental Progress & Sustainable Energy, 2011,30(3):377-383.
|
[18] |
Luo J, Feng L, Chen Y. Stimulating short-chain fatty acids production from waste activated sludge by nano zero-valent iron[J]. Journal of Biotechnology, 2014,187:98-105.
|
[19] |
Wang Y, Wei Y, Liu J. Effect of H2O2 dosing strategy on sludge pretreatment by microwave-H2O2 advanced oxidation process[J]. Journal of Hazardous Materials, 2009,169(1-3):680-684.
|
[20] |
Liu Y, Li X, Kang X, et al Short chain fatty acids accumulation and microbial community succession during ultrasonic-pretreated sludge anaerobic fermentation process:Effect of alkaline adjustment[J]. International Biodeterioration& Biodegradation, 2014,94(36):128-133.
|
[21] |
肖本益,刘俊新.不同预处理方法对剩余污泥性质的影响研究[J]. 环境科学, 2008,29(2):2327-2331.
|
|
|
|