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Adsorption characteristic of organic combined pollutants on the surface of groundwater aquifer |
LI Hui1, DENG Qiang2 |
1. Key Laboratory of Groundwater Contamination Remediation, China Geological Survey, The Institute of Hydrogeology and Environmental Geology, Chinese Academy of Geological Science, Shijiazhuang 050061, China;
2. College of Water Resource and Environment, Hebei Geology University, Shijiazhuang 050031, China |
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Abstract To definite the adsorption characteristics of chlorohydrocarbon and aromatic hydrocarbon combined pollutants in groundwater aquifer, adsorption tests were carried out with toluene, benzene, 1,2-dichloropropane, 1,2,3-chemical propane (TCP) as typical pollutants. The results showed that the adsorption process could be described by linear model of Henry with distribution coefficient (Kp) of 0.38, 0.41, 0.73 and 1.00kg/L, respectively, which indicated that the order of adsorption strength of the pollutants is toluene > benzene > 1, 2-dichloropropane > TCP. Furthermore, it was observed that benzene obviously increased the adsorption of toluene in fine sand and toluene decreased the adsorption of benzene conversely; 1, 2-dichloropropane restrained the adsorption of TCP, however, the effect of TCP on the adsorption of 1, 2-dichloropropane was not significant. As for different type of pollutants, the adsorption capacity of TCP in aquifer medium increased with the concentration of toluene; When the initial concentration of toluene was lower than 2mg/L, the TCP acted as a stimulus for the adsorption of toluene, on the contrary, TCP acted as an inhibitor for the adsorption of toluene in aquifer medium.
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Received: 18 February 2018
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[1] |
高存容,王俊桃.我国69个城市地下水有机污染特征研究[J]. 地球学报, 2011,32(5):581-591.
|
[2] |
有机污染组分特征及其环境指示效应[J]. 中国环境科学, 2013,33(6):1025-1032.
|
[3] |
石建省,王昭,张兆吉,等.华北平原地下水有机污染特征初步分析[J]. 生态环境学报, 2011,20(11):1695-1699.
|
[4] |
张兆吉,费宇红,张连胜,等.华北平原地下水污染调查评价[C]//2009年度中国地质科技新进展和地质找矿新成果资料汇编.北京:中国地质教育出版社, 2009.
|
[5] |
Lin M Q, Ning, X A, An T C, et al. Degradation of polycyclicaromatic hydrocarbons (PAHs)in textile dyeing sludge withultrasound and Fenton processes:Effect of system parametersand synergistic effect study[J]. Journal of Hazardous Materials, 2016,305:7-16.
|
[6] |
何娇,孔火良,高彦征.表面改性秸秆生物质环境材料对水中PAHs的吸附性能[J]. 中国环境科学, 2011,31(1):50-55.
|
[7] |
罗冰,李荣飞,李诗殷,等.三氯乙烯在砂土和壤土中吸附的热力学研究[J]. 中国环境科学, 2013,33(S1):93-97.
|
[8] |
田华,刘哲,赵璐,等.土壤中多环芳烃菲的自然降解特性[J]. 环境工程学报, 2015,9(8):4055-4060.
|
[9] |
何江涛,史敬华,崔卫华,等.浅层地下水中氯代烃污染天然生物降解的判别依据[J]. 地球科学-中国地质大学学报, 2004,29(3):357-362.
|
[10] |
卢杰,李梦红,潘嘉芬.有机氯代烃污染地下水环境的治理与修复[J]. 山东理工大学学报(自然科学版), 2008,22(4):27-30.
|
[11] |
Chiou C T, Schmedding D W, Manes M. Partitioning of organic compounds in octanol-watersystems[J]. Environmental Science and Technology, 1983,17:227-229.
|
[12] |
Xia G S, Ball W P. Adsorption-partitioning uptake of nine low-polarity organic chemicals ona natural sorbent[J]. Environmental Science and Technology, 1999,33(2):262-269.
|
[13] |
Liu S J. A mathematical model for competitive adsorptions[J]. Separation and Purification Technology, 2015,144:80-89.
|
[14] |
Dang S Q, Zhao L, Yang Q, et al.Competitive adsorption mechanism of thiophene with benzene in FAU zeolite:The role of displacement[J]. Chemical Engineering Journal, 2017,328:172-185.
|
[15] |
David F C, Alipio B C, Manuel A E, et al. Competitive adsorption/desorption of tetracycline, oxytetracycline and chlortetracycline on twoacid soils:Stirred flow chamber experiments[J]. Chemosphere, 2015,134(1):361-366.
|
[16] |
Hussein M S, Ahmed M J.Fixed bed and batch adsorption of benzene and toluene from aromatic hydrocarbons on 5A molecular sieve zeolite[J]. Materials Chemistry and Physics, 2016,181:512-517.
|
[17] |
Chen Y D, Jiang Y P, Zhu Y N, et al. Fate and transport of ethanol-blended dissolved BTEXhydrocarbons:a quantitative tracing study of asand tank experiment[J]. Environmental EarthSciences, 2013,70(1):49-56.
|
[18] |
Go J, Stegemann J A. Modelling post-depositional transport of PAHs in aquatic bedsediments using CoReTranS[J]. Journal of Soils and Sediments, 2012,12(10):1541-1548.
|
[19] |
马晋荣,占新华,周立祥,等.表征复合型有机污染场地土壤污染程度的生态指标研究[J]. 南京农业大学学报, 2013,33(4):69-74.
|
[20] |
钱永.1,2,3-三氯丙烷在地下水中的环境行为研究——以某氯代烃有机污染场地为例[D]. 北京:中国地质大学(北京), 2016.
|
[21] |
马月姣,毕二平,陈鸿汉.苯和甲苯在土壤中的吸附行为研究[J]. 岩石矿物学杂志, 2011,30(6):1105-1110.
|
[22] |
王威.浅层地下水中石油类特征污染物迁移转化机理研究[D]. 长春:吉林大学, 2012.
|
[23] |
Endo S, Grathwohl P, Haderlein S B, et al. Compound-specific factors influencing sorption nonlinearity in natural organic matter[J]. Environmental Science and Technology, 2008,42(16):5897-5903.
|
[24] |
Kobayashi T, Shimizu Y, Urano K. Estimation of adsorbed amounts of volatile organic compounds to wet soil based on the properties of the compounds and soils[J]. Science of the Total Environment, 2003, 301(1/3):215-223.
|
[25] |
张晶,何江涛,曲雪妍,等.包气带土壤组成对三氯乙烯的吸附影响[J]. 岩石矿物学杂志, 2010,29(4):439-444.
|
[26] |
童玲,郑西来,李梅,等.土壤对苯系物的吸附行为研究[J]. 西安建筑大学学报(自然科学版), 2007,39(6):856-861.
|
[27] |
张坤峰,何江涛,刘明亮,等.土壤中有机碳含量对三氯乙烯的吸附影响实验[J]. 岩石矿物学杂志, 2009,28(3):649-652.
|
[28] |
Carmo A M, Hundal L S, Thompson M L. Sorption of hydrophobic organic compounds by soil Materials:application of unit equivalent Freundlich coefficients[J]. Environmental Science and Technology, 2000,34(20):4363-4369.
|
[29] |
娄保锋,朱利中,杨坤.苯及其取代物与对硝基苯胺在沉积物上的竞争吸附[J]. 中国环境科学, 2004,24(3):327-331.
|
[30] |
娄保锋.有机污染物在沉积物上的竞争吸附效应及影响因素[D]. 杭州:浙江大学, 2004.
|
[31] |
廖志强,朱杰,罗启仕,等.污染土壤中苯系物的热解吸[J]. 环境化学, 2013,32(4):646-650.
|
[32] |
Sander M, Pignatello J J. Characterization of charcoal adsorption sites for aromatic compounds:Insights drawn from single-solute and Bi-solute competitive experiments. Environmental Science and Technology, 2005,39(6):1606-1615.
|
|
|
|