铁锰复合氧化物滤料去除地下水中四环素的效能

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Abstract

In this study, the iron-manganese (Fe-Mn) co-oxide filter media were adopted from a pilot-scale water treatment plant. This plant has been running for 5years continuously. Both the static and continuous flow column experiments were conducted to explore the performance and mechanism of tetracycline removal by the Fe-Mn co-oxide filter media. The results indicated that the removal process followed the quasi-secondary reaction kinetics model. The better removal efficiency could be obtained with increasing the material quantity and initial concentration. When the concentration of coexisting cations reached 0.01mol/L, the inhibition of tetracycline removal could be observed. Nevertheless, Ca²⁺、K⁺ exhibited little effect on the tetracycline removal. Through the continuous flow column experiment and the toxicity evaluation based on luminescent bacteria, it indicated that the Fe-Mn co-oxide filter media had higher tetracycline removal efficiency than that of the original quartz sand filter media, and the acute toxicity was reduced after treatment by the Fe-Mn co-oxide filter media. In addition, the experimental results of mechanism exploration confirmed that the removal of tetracycline by the Fe-Mn co-oxide filter media was a combined process of adsorption and oxidation.

Key words： iron-manganese co-oxide tetracycline kinetic model groundwater acute toxicity

Received: 11 September 2019

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X523

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	Articles by authors
	YAO Xuan
	HUANG Ting-lin
	CHENG Ya
	LI Yu-yang
	SUN Chang-xi

Cite this article:

YAO Xuan,HUANG Ting-lin,CHENG Ya等. Removal of tetracycline in groundwater by iron-manganese co-oxide filter[J]. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(4): 1723-1731.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2020/V40/I4/1723

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