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Characteristics of organic carbon (OC) and elemental carbon (EC) under different pollution levels of PM2.5 during winter in Shenyang |
ZHANG Yu-xiu1, REN Wan-hui2, WANG Jia-he1, SU Zong-zong2, ZHANG Rui-fang1, YU Xing-na1 |
1. Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters, Nanjing University of Information Science and Technology, Nanjing 210044, China; 2. Shenyang Ecological Environment Monitoring Center of Liaoning Province, Shenyang 110000, China |
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Abstract The organic carbon (OC) and elemental carbon (EC) in PM2.5 were measured by organic carbon/elemental carbon analyzer from December 2018 to January 2019 in Shenyang. The pollution characteristics of carbon components under different pollution levels were studied. The pollution of carbon component was serious in winter of Shenyang, and the total carbon aerosol (TCA) accounted for 36.3%~42.8% of PM2.5 at different pollution levels. The average mass concentrations of PM2.5, OC and EC were 148.6, 29.6 and 6.6μg/m3 in moderate/heavy pollution days respectively, which were 3.1~3.3times of those in clean days. The diurnal variations of PM2.5, OC and EC showed a high value in the morning and evening and low in the afternoon. At any time, the concentrations of PM2.5, OC and EC showed as moderate/heavy pollution> light pollution> clean days. The OC/EC ratios under different pollution levels were all higher than 2. The OC/EC ratio of pollution days ranged from 2.1 to 25.3, which indicated that coal combustion and vehicle exhaust emissions were the main sources of OC and EC in pollution days. The secondary organic carbon (SOC) increased with pollution levels, with the concentration of 2.9, 6.5 and 10.6μg/m3 in clean, light pollution and moderate/heavy pollution days, respectively. The backward trajectory simulation showed that the pollution days in winter of Shenyang were mainly affected by air masses from the northward and northwest directions.
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Received: 23 November 2020
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