|
|
|
| Rare earth elements in the upper reaches of Yarlung Zangbo river |
| LIU Xin-ting1,2, HE Wen-cheng2,3, PENG Hui2,3, XIAO Shang-bin2,3, LI Jia2,3 |
1. Hubei Three Gorges Polytechnic, Yichang 443000, China;
2. Engineering Research Center of Eco-environment in Three Gorges Reservoir Region, Ministry of Education, Yichang 443002, China;
3. College of Hydraulic and Environmental Engineering, China Three Gorges University, Yichang 443002, China |
|
|
|
|
Abstract The Contents and distribution patterns of rare earth elements and characteristic parameters of Ce and Eu in water and sediments of the upper reaches of the Yarlung Zangbo River were studied to explore its geochemical characteristics and influencing factors. The results showed that the average content of dissolved rare earth elements in water was 19.28ng/L, and the average content of rare earth elements in sediments was 190.8mg/kg. The rare earth elements in water are rich in heavy rare earth elements (LaN/YbN<1), while sediments with enrichment of light rare earth elements (LaN/YbN>1). Affected by rock weathering, Ce in water is a negative anomaly, or Ce in sediment is no anomaly and weak negative anomaly. Under the influence of water-rock interaction on the migration and transformation of rare earth elements in the water-sediment system, Eu in water shows a positive anomaly, and Eu in sediment shows a negative anomaly. Due to the difference in weathering process caused by different source rock types, the rare earth elements in the source and river sections show obvious spatial heterogeneity.
|
|
Received: 08 November 2022
|
|
|
|
|
|
[1] Tachikawa K, Piotrowski A M, Bayon G. Neodymium associated with foraminiferal carbonate as a recorder of seawater isotopic signatures[J]. Quaternary Science Reviews, 2014,88:1-13.
[2] Borrego J, Carro B, Lopez-Gonzalez N, et al. Effect of acid mine drainage on dissolved rare earth elements geochemistry along a fluvial-estuarine system:the Tinto-Odiel Estuary (SW Spain)[J]. Hydrology Research, 2012,43(3):262-274.
[3] Gerasimova L G, Nikolaev A I, Maslova M V, et al. Utilization of waste containing rare-earth elements[J]. Theoretical Foundations of Chemical Engineering, 2010,44(5):818-821.
[4] Wang Z L, Liu C Q. Geochemistry of rare earth elements in the dissolved, acid-soluble and residual phases in surface waters of the Changjiang Estuary[J]. Journal of Oceanography, 2008,64(3):407-416.
[5] 樊连杰,裴建国,卢 丽,等.桂林寨底地下河系统中地下水稀土元素含量及分异特征[J]. 中国稀土学报, 2018,36(2):247-256. Fan L J, Pei J G, Lu L, et al. Concentrations and patterns of rare earth elements in groundwater from Zhaidi underground River in Guilin[J]. Journal of the Chinese Society of Rare Earths, 2018,36(2):247-256.
[6] Larsen W, Liu X M,. Rare earth element behavior in springs and streams on a basaltic island:San Cristóbal, Galápagos[J]. Applied Geochemistry, 2021,131:105004.
[7] Song Y H, Choi M S. REE geochemistry of fine-grained sediments from major rivers around the Yellow Sea[J]. Chemical Geology, 2009,266(3/4):328-342.
[8] Smith C, Liu X M. Spatial and temporal distribution of rare earth elements in the Neuse River, North Carolina[J]. Chemical Geology, 2018,488:34-43.
[9] 董俐香,江用彬,张海英,等.黄山景观流域溶解态稀土元素地球化学特征[J]. 中国稀土学报, 2017,35(2):283-293. Dong L X, Jiang Y B, Zhang H Y, et al. Geochemistry of dissolved Rare Earth Elements in watershed at Northern Mount Huangshan Landscape[J]. Journal of the Chinese Society of Rare Earths, 2017, 35(2):283-293.
[10] Liu X R, Liu W S, Tang Y T, et al. Effects of in situ leaching on the origin and migration of rare earth elements in aqueous systems of South China:Insights based on REE patterns, and Ce and Eu anomalies[J]. Journal of Hazardous Materials, 2022,435:128959.
[11] 樊连杰,邹胜章,解庆林,等.云南鹤庆盆地岩溶地下水稀土元素地球化学特征[J]. 中国稀土学报, 2021,30(5):805-815. Fan L J, Zou S Z, Jie Q L, et al. Rare Earth Element Geochemical Characteristics of Karst Groundwater in Heqing Basin, Yunnan Province[J]. Journal of the Chinese Society of Rare Earths, 2021, 30(5):805-815.
[12] Kaczor-Kurzawa D, Wysocka I, Porowski A, et al. The occurrence and distribution of rare earth elements in mineral and thermal waters in the Polish Lowlands[J]. Journal of Geochemical Exploration, 2022,237:106984.
[13] Grawunder A, Lonschinski M, Händel M, et al. Rare earth element patterns as process indicators at the water-solid interface of a post-mining area[J]. Applied Geochemistry, 2018,96:138-154.
[14] Conradie J, Schoch A. Rare earth element geochemistry of an anorthosite-diorite suite, Namaqua mobile belt, South Africa[J]. Earth and planetary science letters, 1988,87(4):409-422.
[15] Mora A, Moreau C, Moquet J S, et al. Hydrological control, fractionation, and fluxes of dissolved rare earth elements in the lower Orinoco River, Venezuela[J]. Applied Geochemistry, 2020,112:104462.
[16] Slukovskii Z, Guzeva A, Dauvalter V. Rare earth elements in surface lake sediments of Russian arctic:Natural and potential anthropogenic impact to their accumulation[J]. Applied Geochemistry, 2022,142 (0883-2927):305-325.
[17] 严宇鹏,刘 佳,刘心庭,等.雅鲁藏布江上游干支流夏季水化学特征及来源解析[J]. 中国环境科学, 2022,42(20):815-825. Yan Y P, Liu J, Liu X T, et al. Hydrochemical characteristics and sources of the upper Yarlung Zangbo River in summer[J]. China Environmental Science, 2022,42(20):815-825.
[18] Wu Y, Fang H, He G, et al. Climate-driven changes in hydrological and hydrodynamic responses in the Yarlung Tsangpo River[J]. Journal of Hydrology, 2021,598(2-4):126267.
[19] Haque S, Ali M, Islam A, et al. Changes in flow and sediment load of poorly gauged Brahmaputra river basin under an extreme climate scenario[J]. Journal of Water and Climate Change, 2021,12(3):937-954.
[20] Ren W, Yao T, Xie S. Water stable isotopes in the Yarlungzangbo headwater region and its vicinity of the southwestern Tibetan Plateau[J]. Tellus B:Chemical and Physical Meteorology, 2016,68(1):30397.
[21] Yan Y N, Zhang J W, Zhang W, et al. Spatiotemporal variation of hydrogen and oxygen stable isotopes in the Yarlung Tsangpo River basin, southern Tibetan Plateau[J]. Frontiers in Earth Science, 2021,9:757094.
[22] Liu J, Lu G, Yang H, et al. Ecological impact assessment of 110micropollutants in the Yarlung Tsangpo River on the Tibetan Plateau[J]. Journal of Environmental Management, 2020,262:110291.
[23] Li Z, Liu J, Guo H. Plateau River research:ecological risk assessment of surface sediments in the Yarlung Tsangpo River[J]. Environmental Science and Pollution Research, 2020,27(6):6126-6138.
[24] 高志友,王小丹,尹 观.雅鲁藏布江径流水文规律及水体同位素组成[J]. 地理学报, 2007,(9):1002-1007. Gao Z Y, Wang X D, Yin H, Hydrological rule and isotopic composition of water bodies in Yarlung Zangbo River[J]. Acta Geographica Sinica, 2007,(9):1002-1007.
[25] 李占玲,徐宗学,巩同梁.雅鲁藏布江流域径流特性变化分析[D]. 2008,(2):353-361. Li Z L, Xu Z X, Gong T L, Characteristics of runoff variation in the Yarlung Zangbo River basin[D]. 2008,(2):353-361.
[26] Oster G. Phosphorus in the environment:Its chemistry and biochemistry[J]. Environmental Research, 1979,19(2):516-517.
[27] Osman A G M, Kloas W. Water quality and heavy metal monitoring in water, sediments, and tissues of the African catfish Clarias Gariepinus (Burchell, 1822) from the river Nile, Egypt[J]. J. Environ. Prot. Ecol. 2010,1(4):389.
[28] 王中刚,于学元.稀土元素地球化学[J]. 北京:稀土元素地球化学, 1989,38(5):553-558. Wang G Z, Yu X G. geochemistry of rare earth elements[J]. Beijing:geochemistry of rare earth elements, 1989,38(5):553-558.
[29] Shou Y Y, Jung H S, Man S C, et al. The rare earth element compositions of the Changjiang (Yangtze) and Huanghe (Yellow) river sediments[J]. Earth and Planetary Science Letters:A Letter Journal Devoted to the Development in Time of the Earth and Planetary System, 2002,201(2):407-419.
[30] White A. Effects of climate on chemical weathering in watersheds underlain by grantoid rocks[J]. Mineralogical Magazine, 1994,58(2):967-968.
[31] 骆检兰,刘长明,郭定良,等.洞庭湖流域地表水溶解态微量元素的地球化学特征[J]. 地球与环境, 2013,41(1):82-89. Luo Y L, Liu C M, Guo D L, et al. Geochemical characteristics of dissolved trace metals in the Dongting Lake basin[J]. Earth and Environment, 2013,41(1):82-89.
[32] 王思梦,李 军,李 勇,等.贵州阿哈湖溶解态稀土的垂向分布及形态特征[J]. 中国稀土学报, 2016,34(4):494-503. Wang S M, Li J, Li Y, et al. Vertical distributions and speciation of dissolved Rare Earth Elements in Aha Lake[J]. Journal of the Chinese Society of Rare Earths, 2016,34(4):494-503.
[33] 李祥辉,王成善,李亚林,等.西藏仲巴地区曲嘎组的拆解[J]. 地质通报, 2014,33(5):614-628. Li X H, Wang C S, Li Y L, et al. The disaggregation of the Permian Quga Formation in Zhongba area, south western Tibet. Geological Bulletin of China, 2014,33(5):614-628.
[34] 张计东,范永贵,刘思林,等.雅鲁藏布江南带白垩纪地层划分及特征[J]. 中国地质调查, 2016,3(4):19-28. Zhang J D, Fan Y G, Liu S L, et al. Division and characteristics of the Cretaceous formation in southern Yarlung Zangbo suture zone in Tibet[J]. Geological Bulletin of China, 2016,3(4):19-28.
[35] Sklyarova. Rare earth elements in tributaries of Lake Baikal (Siberia, Russia)[J]. Applied Geochemistry:Journal of the International Association of Geochemistry and Cosmochemistry, 2017,82:164-176.
[36] 刘菁钧,赖子娟,邓凤玉,等.黄河甘宁蒙段表层沉积物中重金属元素含量及其形态分析(英文)[J]. 光谱学与光谱分析, 2015,35(10):2963-2969. Liu Q J, Guo Z J, Deng F Y, et al. Heavymetals contents speciation in suface sediments from Gansu, Ning xia and inner Mongolia sections of Yellow River of China[J]. Spectroscopy and Spectral Analysis, 2015, 35(10):2963-2969.
[37] Xu Z, Han G. Rare earth elements (REE) of dissolved and suspended loads in the Xijiang River, South China[J]. Applied Geochemistry:Journal of the International Association of Geochemistry and Cosmochemistry, 2009,408(19):24-30.
[38] Radomskaya V I, Radomskii S M, Kulik E N, et al. Geochemical Features of Rare-Earth Elements in Surface and Subsurface Waters in the Field of the Albynskoe Gold-Bearing Placer, Amur Oblast[J]. Water Resources, 2017,44(2):284-296.
[39] 彭超超.苏州地表水中溶解态稀土元素和微量元素组成特征与来源分析[D]. 贵州:贵州大学, 2020. Peng C C. The composition characteristics and source analysis of dissolved rare earth elements and trace elements in surface water of Suzhou[D]. GuiZhou:GuiZhou University, 2020.
[40] Han G, Liu C. Dissolved rare earth elements in river waters draining karst terrains in Guizhou Province, China[J]. 2007,13(1):95-107.
[41] 季根源,江思宏,张龙升,等.大兴安岭南段毛登高分异碱长花岗岩成岩时代与地球化学特征[J]. 岩石学报, 2022,38(3):855-882. Ji G Y, Jiang S H, Zhang L S, et al. Chronology and geochemical characteristics of the highly fractionated alkali feldspar granite from the Maodeng deposit in the southern Great Xing'an Range[J]. Acta Petrologica Sinica, 38(3):855-882.
[42] 王志山,郑刘根,董祥林,等.临涣采煤沉陷区地表水稀土元素地球化学特征[J]. 中国稀土学报, 2019,37(5):617-624. Wang Z S, Zheng L G, Dong X L, et al. Geochemistry of Rare Earth Elements in surface water from the Linhuan coal mining subsidence[J]. ournal of the Chinese Society of Rare Earths, 2019,37(5):617-624.
[43] Hissler C, Stille P. Stages of weathering mantle formation from carbonate rocks in the light of rare earth elements (REE) and Sr-Nd-Pb isotopes[J]. journal of materials engineering, 2007,25:10848.
[44] Takahashi Y, Hayasaka Y, Morita K, et al. Transfer of rare earth elements (REE) from manganese oxides to phosphates during early diagenesis in pelagic sediments inferred from REE patterns, X-ray absorption spectroscopy, and chemical leaching method[J]. Geochemical Journal, 2015,49(6):653-674.
[45] Elderfield H, Upstill-Goddard R, E S. The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters[J], 1990,54(4):971-991.
[46] Hood E W. Ecological controls on the source and character of dissolved organic matter in an alpine watershed, Green Lakes Valley, Colorado Front Range[M]. Applied Geochemistry, 2001,35(1):131-142.
[47] 陈晓薇,陈秀玲,周笑笑,等.霍童溪表层沉积物稀土元素特征及其物源示踪分析[J]. 地球环境学报, 2021,12(5):526-539. Chen X W, Chen X L, Zhou X X, et al. Characteristics and trace analysis of Rare Earth Elements in surface sediment of Huotong River[J]. Journal of Earth Environment, 2021,12(5):526-539.
[48] 汤秋鸿,兰 措,苏凤阁,等.青藏高原河川径流变化及其影响研究进展[J]. 科学通报, 2019,64(27):2807-2821. Tang Q H, Lan C, Sun F G, et al. Streamflow change on the Qinghai-Tibet Plateau and its impacts[J]. Chinese Science Bulletin, 2019, 64(27):2807-2821.
[49] 张立成,章 申,董文江.长江河源区水环境地球化学[M]. 北京:中国环境科学出版社, 1992:61-199. Zhang L C, Zhang S, Dong W J. Water Environmental Geochemistry in Source Region of Yangtze River[M]. Beijing:China environmental science publishing house, 1992:61-199.
[50] 张 镭,黄建平,梁捷宁,等.气候变化对黄河流域的影响及应对措施[J]. 科技导报, 2020,38(17):42-51. Zhang L, Huang J P, Liang J N, et al. Impact of climate change on the Yellow River basin and respons[J]. Science Technology Review, 2020, 38(17):42-51.
[51] 刘茂涵,刘海燕,张卫民,等.鄱阳湖流域赣江北支水体和沉积物中稀土元素的含量和分异特征[J]. 现代地质, 2022,36(2):389-405. Liu M H, Liu H Y, Zhang W M, et al. REE concentration and fractionation in waters and sediments from the Northern Branch of Ganjiang river, Poyang Lake Catchment[J]. Geoscience, 2022,36(2):389-405.
[52] Ponnurangam A, Bau M, Brenner M, et al. Mussel shells of Mytilus edulis as bioarchives of the rare earth elements and yttrium distribution in seawater and the potential impact of pH and temperature on the partitioning behaviour[J]. Copernicus GmbH, 2016:13(3):751-760.
[53] Immerzeel W. Historical trends and future predictions of climate variability in the Brahmaputra basin[J]. International Journal of Climatology:A Journal of the Royal Meteorological Society, 2008, 28(2):243-254.
[54] 史 展,陶和平,刘淑珍,等.基GIS的三江源区冻融侵蚀评价与分析[J]. 农业工程学报, 2012,28(19):214-221. Shi Z, Tao H P, Liu S Z, et al. Research of freeze-thaw erosion in the Three-River-Source area based on GIS[J]. Transactions of the Chinese Society of Agricultural Engineering, 2012,28(19):214-221.
[55] 施雅风.2050年前气候变暖冰川萎缩对水资源影响情景预估[J]. 冰川冻土, 2001,12(4):333-341. Shi Y F. Estimation of the Water Resources Affected by Climatic Warming and Glacier Shrinkage before 2050 in West China[J]. Journal of Glaciology and Geocryology, 2001,12(4):333-341. |
|
|
|
