亚硝酸盐对硫酸根自由基降解卤代酚的影响

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Abstract The influence of nitrite (NO₂-) on the degradation of bromophenol and chlorophenol by sulfate radical (SO₄^•–) oxidation was systematically investigated in this work. Results showed that the presence of NO₂- accelerated the degradation of bromophenol, while posed a weak effect on the degradation of chlorophenol. Meanwhile, NO₂- led to a series of toxic nitrated byproducts. Upon SO₄^•– oxidation, halophenols underwent dehalogenation and the released halides can be further oxidized by SO₄^•– to form reactive halogen species, which rapidly react with some intermediates and the parent compounds to form halogenated byproducts, such as haloform and haloacetic acid. Once NO₂- was co-present, these reactive halogen species can be scavenged by NO₂- to form a strong oxidizing agent, nitryl halide. Then nitryl halide reacts with the parent halophenol, promoting their degradation and resulting in the formation of nitrated byproducts. Besides, NO₂- can be oxidized to nitrogen dioxide radicals (NO₂^·) by SO₄^•–, which further couple with phenoxy radicals generated from the oxidation of halophenols by SO₄^•–, yielding nitrated byproducts as well. Note that, the formation of nitrated byproducts from bromophenol (9.2 μmol/L) was significantly higher than those generated from chlorophenol (5.7μmol/L) with 200 μmol/L NO₂- present. In SO₄^•– oxidation process, bromophenol is more prone to dehalogenation than chlorophenol. Therefore, the influence of NO₂- on the transformation of bromophenol was more drastic than that of chlorophenol by SO₄^•–. These findings reveal potential risks of the application of SO₄^•– oxidation technologies for the remediation of halogenated contaminants in the subsurface environment, and provide new insights into the interaction of nitrogen and halogen in SO₄^•– oxidation processes.

Key words： bromophenol chlorophenol sulfate radicals nitrite nitryl halides nitrated byproducts

Received: 19 November 2023

PACS:

X703.5

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	Articles by authors
	GUI Jing-jing
	LIU Jia-ting
	YANG Pei-zeng
	CHEN Jing
	JI Yue-fei
	LU Jun-he

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GUI Jing-jing,LIU Jia-ting,YANG Pei-zeng等. Influence of nitrite on the degradation of halogenated phenols in sulfate radical oxidation processes[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(6): 3395-3407.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I6/3395

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