琥珀酸改性天然竹纤维吸附镉/铅的行为机制

Abstract
Figure/Table
References
Related Citation (15)

Download: PDF (1126 KB) HTML (1 KB)
Export: BibTeX | EndNote (RIS)

Abstract After pretreatments of alkalization and acidification, the natural bamboo fibers underwent esterification reaction with succinic acid to produce modified bamboo fibers. Infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) analysis indicated that, after modification, the electronegative carboxyl and ester groups in bamboo fibers increased, and their microstructure changed from dense and flat to wrinkled and porous simultaneously. The adsorption experiments showed that the modified bamboo fibers achieved significantly higher adsorption rates of cadmium (Cd) and lead (Pb) than natural bamboo fibers (up to 47.37% and 44.57%, respectively), and could also be applied to a wider pH value range. The adsorption of Cd and Pb by modified and unmodified bamboo fibers conformed to both Langmuir and Freundlich thermodynamic models.Besides, after modification the maximum adsorption capacity (Q_m) of the bamboo fibers for Cd and Pb increased from 8.9687mg/g and 11.5075mg/g to 26.1780mg/g and 32.3625mg/g respectively, indicating that the modification process of succinic acid increased the adsorption sites of the bamboo fibers, and thus improved their adsorption capacity of Cd/Pb, which can provide a new idea for the modification and upgrading of biosorbent materials.

Key words： succinic acid bamboo fiber esterification modification cadmium lead

Received: 26 January 2024

PACS:

X703.5

Corresponding Authors: 谭峰亮,副教授,tanfl1985@126.com E-mail: tanfl1985@126.com

	Service

	E-mail this article
	Add to my bookshelf
	Add to citation manager
	E-mail Alert
	RSS
	Articles by authors
	ZHANG Xiao-feng
	LI Xiang-yu
	WANG Xin
	HU Jing-xiang
	MA Zhen-yu
	TAN Feng-liang
	HE Lu

Cite this article:

ZHANG Xiao-feng,LI Xiang-yu,WANG Xin等. Behaviors and mechanisms of cadmium/lead adsorption by natural bamboo fibers modified with succinic acid[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(8): 4380-4388.

URL:

http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I8/4380

[1] 余岳溪,刘晓硕,李昂,等.氯改性活性炭吸附单质铅(Pb⁰)的机理[J]. 中国环境科学, 2019,39(5):1847-1853. Yu Y X, Liu X S, Li A, et al. The mechanism of elemental lead (Pb⁰) adsorption on chlorine-embedded activated carbon [J]. China Environmental Science, 2019,39(5):1847-1853.
[2] Qin S, Liu H, Nie Z J, et al. Toxicity of Cd and its competition with mineral nutrients for uptake by plants: A review [J]. Pedosphere, 2020,30(2):168-180.
[3] 吴杨洋,彭祥雯,史可欣,等.Se-Ca联合膳食干预缓解Cd诱导小鼠肝肾毒性[J]. 中国环境科学, 2022,42(3):1379-1384. Wu Y Y, Peng X W, Shi K X, et al. Alleviating cadmium toxicity to liver and kidney of mice with dietary supplementation of selenium and calcium in combination [J]. China Environmental Science, 2022,42(3): 1379-1384.
[4] Ullah F H, Cai L, A J C, et al. Cadmium toxicity in plants: Impacts and remediation strategies [J]. Ecotoxicology and Environmental Safety, 2021,211:111887.
[5] 张凤智,王敦球,曹星沣,等.高锰酸钾改性椰壳生物炭对水中Cd(Ⅱ)和Ni(Ⅱ)的去除性能及机制[J]. 环境科学, 2023,44(6):3279-3286. Zhang F Z, Wang D Q, Cao X F, et al. Removal Performance and Mechanism of Potassium Permanganate Modified Coconut Shell Biochar for Cd(Ⅱ) and Ni(Ⅱ) in Aquatic Environment [J]. Environmental Science, 2023,44(6):3279-3286.
[6] Oar C, Abdeldayem O M, Pugazhendhi A, et al. Current updates and perspectives of biosorption technology: An alternative for the removal of heavy metals from wastewater [J]. Current Pollution Reports, 2020, 6(5):8-27.
[7] 梁莎,冯宁川,郭学益.生物吸附法处理重金属废水研究进展[J]. 水处理技术, 2009,35(3):13-17. Liang S, Feng N C, Guo X Y. Progress of heavy metal wastewater treatment by biosorption [J]. Technology of Water Treatment, 2009,35(3):13-17.
[8] Farahani S, Sepahi A A, Shojaosadati S A, et al. Bio-removal of heavy metalsusing iron-oxidizing bacteria: a novel approach in environmental biotechnology [J]. Iranian journal of pharmaceutical research (IJPR), 2020,19(3):421-429.
[9] Zeng G, He S, Wu J, et al. Adsorption of heavy metal ions copper, cadmium and nickel by microcystis aeruginosa [J]. International Journal of Environmental Research and Public Health (IJERPH), 2022, 19(21):13867.
[10] Chaza T, Mangoma N, Nyakuedzwa T, Ncube T. Valorization of Groundnut Shell Biomass for Biosorption of Hexavalent Chromium from Aqueous Solution [J]. Journal of Sustainable Development, 2023,16(2):72-84.
[11] Malkhede S, Rao Y. Biosorption Behaviour of Groundnut Husk on Removal of Copper (II) from Aqueous Solution [J]. ECS Transactions, 2022,107(1):17871-17889.
[12] Zafar S, Khan M, Elboughdiri N, et al. Adsorption performance of rice husk towards copper ions from wastewater [J]. Desalination and Water Treatment, 2022,285:133-142.
[13] Yusuff A, Lala M, Thompson-Yusuff K, et al. ZnCl₂-modified eucalyptus bark biochar as adsorbent: preparation, characterization and its application in adsorption of Cr(VI) from aqueous solutions [J]. South African Journal of Chemical Engineering, 2022,42(5):138-145.
[14] Anastopoulos I, Ahmed M, Hummadi E. Eucalyptus-based materials as adsorbents for heavy metals and dyes removal from (waste)waters [J]. Journal of Molecular Liquids, 2022,356:118864.
[15] Amari A, Alalwan B, Eldirderi M, et al. Cactus material-based adsorbents for the removal of heavy metals and dyes: a review [J]. Materials Research Express, 2019,7:012002.
[16] Liu X F, Dong X Q, Chang S Q, et al. Remediation of lead- contaminated groundwater by oyster shell powder-peanut shell biochar mixture [J]. Environmental Geochemistry and Health, 2023, 45(12):9599-9619.
[17] 徐汝悦,王子霄,沈禄,等.Cr(Ⅵ)的生物修复技术研究进展[J]. 生物技术通报, 2023,39(6):49-60. Xu R Y, Wang Z X, Shen L, et al. Research Progress in Bioremediation of Cr(VI) [J]. Biotechnology Bulletin, 2023,39(6):49-60.
[18] Tewari A, Bhutada D, Wadgaonkar V. Heavy Metal Remediation from Water/Wastewater Using Bioadsorbents-A Review [J]. Nature Environment and Pollution Technology, 2023,22(4):2039-2053.
[19] Li J, Lian C, Wu J, et al. Morphology, chemical composition and thermal stability of bamboo parenchyma cells and fibers isolated by different methods [J]. Cellulose, 2023,30:2007-2021.
[20] Sahu P, Gupta M. A review on the properties of natural fibres and its bio-composites: Effect of alkali treatment [J]. Proceedings of the Institution of Mechanical Engineers Part L Journal of Materials Design and Applications, 2019,234(1):198-217.
[21] 邓勃.实用原子光谱分析[M]. 北京:化学工业出版社, 2021. Deng B. Practical Atomic Spectroscopy [M]. Beijing: Chemical Industry Press, 2021.
[22] 周同惠,汪尔康,陆婉珍,等.分析化学手册[M]. 北京:化学工业出版社, 1996. Zhou T H, Wang E K, Lu W Z, et al. Handbook of Analytical Chemistry [M]. Beijing: Chemical Industry Press, 1996.
[23] Soleimani F, Aghaie H, Gharib F. Hydrolysis of cadmium cation in different ionic strength [J]. Journal of Physical and Theoretical Chemistry of Islamic Azad University of Iran, 2008,5(2):73-78.
[24] Xiong Y, Kirkes L, Westfall T, et al. A Pitzer Model for Lead Oxide Solubilities in the Presence of Borate to High Ionic Strength [J]. Journal of Solution Chemistry, 2018,47:1905-1925.
[25] 刘秀芸,王刚,雷雨昕,等.巯基改性玉米秸秆对水中Cu(Ⅱ)的吸附特性[J]. 中国环境科学, 2022,42(3):1220-1229. Liu X Y, Wang G, Lei Y X, et al. Adsorption performance and mechanism of mercaptoacetyl corn straw for Cu(Ⅱ) in aqueous solution [J]. China Environmental Science, 2022,42(3):1220-1229.
[26] 孙永鹏,王刚,何扬洋,等.巯基改性小麦秸秆对镉吸附与解吸的性能及机制[J]. 中国环境科学, 2023,43(5):2264-2276. Sun Y P, Wang G, He Y Y, et al. Performance and mechanism of adsorption and desorption for cadmium in aqueous solution with mercaptopropionyl wheat straw [J]. China Environmental Science, 2023,43(5):2264-2276.