高级氧化-PRB修复填埋场复合污染地下水的可行性

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Abstract The complex contamination of COD, NH₄⁺, and Mn²⁺ in the groundwater of a landfill site in Hangzhou was investigated in this study. A combination of heterogeneous Fenton oxidation and a permeable reactive barrier (PRB) was applied. Three different catalytic oxidation catalyst combinations—activated carbon (AC), biochar (BC), and BC+Fe₃O₄—were designed and used as active filling materials in the oxidation layer of the PRB, followed by a downstream zeolite adsorption layer. Results from batch and column tests showed that 47% of COD was directly pre-oxidized by H₂O₂. COD in the oxidation layer was reduced through the combined effects of catalytic oxidation and adsorption. The transport of Mn²⁺ was influenced by the ash content released from porous carbon materials, resulting in initial precipitation followed by dissolution and subsequent adsorption. Functional groups on the surfaces of AC and BC, such as -OH and -COOH, were involved in the reaction. In the adsorption layer, NH₄⁺ and Mn²⁺ were exchanged with zeolite ions, leading to changes in the zeolite framework structure. The functional groups -NH and -OH on the zeolite surface were also involved in thorough adsorption. The series combination of the BC+Fe₃O₄ oxidation layer and the zeolite adsorption layer, with a length ratio of 1:3, was found to exhibit higher removal rates for all three contaminants, the latest PRB breakthrough time (i.e., when the effluent concentration was reduced to 10% of the influent concentration and exceeded the limit), and the highest utilization efficiency at breakthrough, making it the optimal process.

Key words： permeable reactive barrier (PRB) advanced oxidation complex contaminants landfill contaminated groundwater

Received: 20 February 2024

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X703

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	YOU Yu-qing
	HAO Na
	ZHAN Liang-tong
	SONG Xue

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YOU Yu-qing,HAO Na,ZHAN Liang-tong等. A feasibility study on the remediation of complex contaminated groundwater in landfill sites using advanced oxidation-permeable reactive barrier (PRB) approach[J]. CHINA ENVIRONMENTAL SCIENCECE, 2024, 44(10): 5620-5629.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2024/V44/I10/5620

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