合成树脂行业挥发性有机物排放成分谱及影响

马怡然; 高松; 王巧敏; 崔虎雄; 吴诗剑; 伏晴艳; 段玉森; 吴健; 焦正

PDF(530 KB)

中国环境科学 ›› 2020, Vol. 40 ›› Issue (8) : 3268-3274.

大气污染与控制

合成树脂行业挥发性有机物排放成分谱及影响

马怡然¹, 高松², 王巧敏³, 崔虎雄², 吴诗剑², 伏晴艳², 段玉森², 吴健¹, 焦正¹

作者信息 +

Source profiles and impact of volatile organic compounds in the synthetic resin industry

MA Yi-ran¹, GAO Song², WANG Qiao-min³, CUI Hu-xiong², WU Shi-jian², FU Qing-yan², DUAN Yu-seng², WU Jian¹, JIAO Zheng¹

Author information +

文章历史 +

摘要

使用SUMMA罐采集华东地区5类典型合成树脂企业有组织排口样品，通过气相色质联用技术（GC-MS）定量分析106种VOCs，计算了合成树脂行业排放量、排放系数和不确定性，分析了VOCs的排放特征和臭氧生成潜势，建立了5类合成树脂VOCs排放成分谱.结果表明：合成树脂企业VOCs排放量为346~3467kg/a，5类合成树脂排放系数为0.06~1.24g/kg，其中涂料树脂（CR）类企业排放量和排放系数均最大.芳香烃、含氧烃（OVOCs）和卤代烃是合成树脂行业VOCs排放基本组分，累计占比范围是73.2%~98.3%.涂料树脂、酚醛树脂（PF）、聚氨酯（PU）、共聚物树脂（ABS）和聚碳酸酯（PC）特征污染物分别为：甲基异丁基酮、苯、甲苯、苯乙烯和二氯甲烷.合成树脂企业臭氧生成潜势（OFP）为22.7~202.5mg/m³，源反应性（SR）为0.3~4.6g/g，CR类企业OFP和SR均最大.合成树脂行业SR处于各行业平均水平.芳香烃、OVOCs和烯炔烃是合成树脂行业的主要光化学活性组分，累计OFP贡献率为64.1%~100.0%，苯、甲苯、甲基异丁基酮、乙烯、苯乙烯是合成树脂行业关键活性物种.研究显示，合成树脂行业VOCs治理应管控芳香烃和OVOCs的排放，重视污染物恶臭问题和卤代烃溶剂的危害，减排VOCs排放量大、臭氧生成能力强的CR类企业.

Abstract

Gas samples were collected with SUMMA canisters from five typical synthetic resin enterprises located in East China. A total of 106 volatile organic compounds (VOCs) in samples were determined by gas chromatography-mass spectrometry (GC-MS). The total emissions and emission coefficients of the synthetic resin industry were calculated, the uncertainty was also analyzed. The emission characteristics were described, and ozone formation potential (OFP) of VOCs were analyzed and the source profiles of five synthetic resins were established. The results showed that the VOCs emissions of synthetic resin enterprises were 346~3467kg/a, and the emission coefficients of five synthetic resins ranged from 0.06 to 1.24g/kg. Among them, the coating resin (CR) enterprises had the largest emission and emission coefficients. Aromatic hydrocarbons, oxygenated hydrocarbons (OVOCs) and halogenated hydrocarbons were characteristic components of VOCs in the synthetic resin industry, the cumulative concentration ranged from 73.2% to 98.3%. The main VOCs pollutants from coating resin (CR), phenol resin (PF), polyurethane (PU), acrylonitrile-butadiene-styrene copolymer (ABS) and polycarbonate (PC) were methyl isobutyl ketone, benzene, toluene, styrene and dichloromethane, respectively. The ozone formation potential (OFP) of the synthetic resin enterprises ranged from 22.7 to 202.5mg/m³, and the source reactivity (SR) ranged from 0.3 to 4.6g/g. The OFP and SR of CR enterprises were the largest in five synthetic resins. The SR of the synthetic resin industry was at an average level among industries. Aromatic hydrocarbons, OVOCs and alkynes were the main active components in the synthetic resin industry, with a total contribution to the OFP ranging from 64.1% to 100.0%. The major contributors of synthetic resin industry were benzene, toluene, methyl isobutyl ketone, ethylene, and styrene. Our study showed that VOCs pollution control in the synthetic resin industry should focus on aromatic hydrocarbons and OVOCs, extra attention should be paid to the of pollutant odors and halogenated hydrocarbon solvents, and especially to CR enterprises with large VOCs emissions and OFP.

导出引用

马怡然, 高松, 王巧敏, 崔虎雄, 吴诗剑, 伏晴艳, 段玉森, 吴健, 焦正. 合成树脂行业挥发性有机物排放成分谱及影响[J]. 中国环境科学. 2020, 40(8): 3268-3274

MA Yi-ran, GAO Song, WANG Qiao-min, CUI Hu-xiong, WU Shi-jian, FU Qing-yan, DUAN Yu-seng, WU Jian, JIAO Zheng. Source profiles and impact of volatile organic compounds in the synthetic resin industry[J]. China Environmental Science. 2020, 40(8): 3268-3274

中图分类号： X131.1 X51

参考文献

[1] Zheng J, Shao M, Che W, et al. Speciated VOC emission inventory and spatial patterns of ozone formation potential in the Pearl River Delta, China[J]. Environmental Science & Technology, 2009,43(22):8580-8586.
[2] 唐孝炎,张远航,邵敏.大气环境化学[M].北京:高等教育出版社, 2006:116-123. Tang X Y, Zhang Y H, Shao M. Atmospheric chemistry[M]. Beijing:Higher Education Press, 2006:116-123.
[3] 席劲瑛,武俊良,胡洪营,等.工业VOCs排放源废气排放特征调查与分析[J].中国环境科学, 2010,30(11):1558-1562. Xi J Y, Wu J L, Hu H Y, et al. Investigation of industrial VOCs emission sources and analysis for their emitting characteristics[J]. China Environmental Science, 2010,30(11):1558-1562.
[4] 周阳,姚立英,张丽娜,等.基于大气化学机制的天津市重点行业VOCs化学物种谱研究[J].中国环境科学, 2018,38(7):2451-2460. Zhou Y, Yao L Y, Zhang L N, et al. Research on VOCs chemical species profile of major industries based on chemical mechanisms in Tianjin[J]. China Environmental Science, 2018,38(7):2451-2460.
[5] 林旭,朱彬,安俊琳,等.南京北郊VOCs对臭氧和二次有机气溶胶潜在贡献的研究[J].中国环境科学, 2015,35(4):976-986. Lin X, Zhu B, An J L, et al. Potential contribution of secondary organic aerosols and ozone of VOCs in the Northern Suburb of Nanjing[J]. China Environment Science, 2015,35(4):976-986.
[6] Zheng J, Yu Y, Mo Z W, et al. Industrial sector-based volatile organic compound (VOC) source profiles measured in manufacturing facilities in the Pearl River Delta, China[J]. Science of the Total Environment, 2013,456:127-136.
[7] 张露露,蒋卫兵,张元勋,等.上海市青浦区大气挥发性有机化合物的特征[J].中国环境科学, 2015,35(12):3550-3561. Zhang L L, Jiang W B, Zhang Y X, et al. The characteristics of ambient volatile organic compounds (VOCs) in Qingpu Shanghai, China[J]. China Environment Science, 2015,35(12):3550-3561.
[8] 王秀夷,宋文迪,方大为,等. UV固化聚氨酯丙烯酸酯的制备与性能研究[J].涂料工业, 2019,49(3):25-32. Wang X Y, Song W D, Fang D W, et al. Preparation and properties of UV-Curable PUA/EA blend emulsions[J]. Paint & Coatings Industry, 2019,49(3):25-32.
[9] Geyer R, Jambeck J R, Law K L. Production, use, and fate of all plastics ever made[J]. Science Advances, 2017,3(7):1-5.
[10] 杨桂英.国内外合成树脂市场现状及发展趋势[J].当代石油石化, 2019,27(4):12-18. Yang G Y. The Current and Future Synthetic Resin Market At Home and Abroad[J]. Petroleum & Petrochemical Today, 2019,27(4):12-18.
[11] GB 31572-2015合成树脂工业污染物排放标准[S]. GB 31572-2015 Emission standard of pollutants for synthetic resin industry[S].
[12] Yuan B, Shao M, Lu S, et al. Source profiles of volatile organic compounds associated with solvent use in Beijing, China[J]. Atmospheric Environment, 2010,44(15):1919-1926.
[13] 王红丽,杨肇勋,景盛翱,等.工艺过程源和溶剂使用源挥发性有机物排放成分谱研究进展[J].环境科学, 2017,38(6):2617-2628. Wang H L, Yang Z X, Jing S H, et al.Volatile organic compounds (VOCs) source profiles of industrial processing and solvent use emissions:A review[J]. Environmental Science, 2017,38(6):2617-2628.
[14] 蔡宗平,蔡慧华,徐家颍,等.塑料行业VOCs排放现状的研究[J].广东化工, 2011,38(6):283-285. Cai Z P, Cai H H, Xu J Y, et al. Study on the emission of VOCs from plastics[J]. Guangdong Chemical Industry, 2011,38(6):283-285.
[15] 王瑞文,张春林,丁航,等.电子制造业塑料件生产过程的挥发性有机物排放特征分析[J].环境科学学报, 2019,39(1):6-14. Wang R W, Zhang C L, Ding H, et al. Emission characteristics of volatile organic compounds (VOCs) from the production processes of plastic parts in electronic manufacturing industry[J]. Acta Scientiae Circumstantiae, 2019,39(1):6-14.
[16] 盛涛,高宗江,高松,等.上海市专项化学品制造行业VOCs排放特征及臭氧生成潜势研究[J].环境科学研究, 2019,32(5):830-838. Sheng T, Gao Z J, Gao S, et al. Emission characteristics and ozone formation potential of VOCs of special chemical manufacturing industry in Shanghai city[J]. Research of Environmental Sciences, 2019,32(5):830-838.
[17] 李霞,苏伟健,黎碧霞,等.佛山市典型铝型材行业表面涂装VOCs排放组成[J].环境科学, 2018,39(12):48-57. Li X, Su W J, Li B X,et al. Source profiles and chemical reactivity of volatile organic compounds from surface coating of aluminum products in Foshan, China[J]. Environmental Science, 2018,39(12):48-57.
[18] Hsu Yi-Chyun, Chen Shan-Kun,Tsai Jiun-Horng, et al Determination of volatile organic profiles and photochemical potentials from chemical manufacture process vents[J]. Journal of the Air & Waste Management Association, 2007,57(6):698-704.
[19] 王伯光,冯志诚,周炎,等.聚氨酯合成革厂空气中挥发性有机物的成分谱[J].中国环境科学, 2009,29(9):914-918. Wang B G, Feng Z C, Zhou Y, et al. VOC components in the air caused by the local polyurethane synthetic leather industries in the Pearl River Delta region[J]. Environmental Science, 2009,29(9):914-918.
[20] 周子航,邓也,谭钦文,等.四川省人为源挥发性有机物组分清单及其臭氧生成潜势[J].环境科学, 2019,40(4):95-108. Zhou Z H, Deng Y, Tan Q W, Speciated VOCs emission inventory and ozone formation potential in Sichuan Province[J]. Environmental Science, 2019,40(4):95-108.
[21] Mo Z, Shao M, Lu S, et al. Process-specific emission characteristics of volatile organic compounds (VOCs) from petrochemical facilities in the Yangtze River Delta, China[J]. Science of the Total Environment, 2015,533:422-431.
[22] 中华人民共和国国家统计局.中国统计年鉴2019[EB/OL]. http://www.stats.gov.cn/tjsj/ndsj/2019/indexch.htm. National Bureau of Statistics of China. China statistical yearbook 2019[EB/OL]. http://www.stats.gov.cn/tjsj/ndsj/2019/indexch.htm.
[23] 张辛铖.水性丙烯酸涂料的改性及应用研究进展[J].广东化工, 2018,45(12):131-133. Zhang X C. Progress in modification and application of waterborne acrylic coatings[J]. Guangdong Chemical Industry, 2018,45(12):131-133.
[24] 徐璐,王一业,张金辉,等.本体聚合ABS树脂研究进展[J].工程塑料应用, 2019,47(3):134-139,143. Xu L, Wang Y Y, Zhang J H, et al. Research progress of bulk polymerized ABS resin[J]. Engineering Plastics Application, 2019, 47(3):134-139,143.
[25] HJ 759-2015环境空气挥发性有机物的测定罐采样/气相色谱-质谱法[S]. HJ 759-2015 Ambient air determination of volatile organic compounds-collected by specially-prepared canistersand analyzed by gas chromatography-mass spectrometry[S].
[26] HJ 734-2014固定污染源废气挥发性有机物的测定固相吸附-热脱附/气相色谱-质谱法[S]. HJ 734-2014 Fixed source pollution-determination of volatile organic compounds-stationary phase adsorption-thermal desorption/gas chromatography-mass spectrometry[S].
[27] 吴健,高松,陈曦,等.涂料制造行业挥发性有机物排放成分谱及影响[J].环境科学, 2020,41(4):1582-1588. Wu J, Gao S, Chen X, et al. Source profiles and impact of volatile organic compounds in the coating manufacturing industry[J]. Environmental Science, 2020,41(4):1582-1588.
[28] 中华人民共和国生态环保部.大气挥发性有机物源排放清单编制技术指南(试行)[EB/OL]. http://www.mee.gov.cn/gkml/hbb/bgg/201408/W020140828351293705457.pdf. Ministry of Ecology and Environment of the People's Republic of China. Technical guidelines for developing the atmospheric volatile organic compounds emission inventory (Trial)[EB/OL]. http://www.mee.gov.cn/gkml/hbb/bgg/201408/W020140828351293705457.pdf.
[29] Yue T T, Yue X, Chai F H, et al. Characteristics of volatile organic compounds (VOCs) from the evaporative emissions of modern passenger cars[J]. Atmospheric Environment, 2017,151:62-69.
[30] Carter W P. Development of a condensed SAPRC-07chemical mechanism[J]. Atmospheric Environment, 2010,44(40):5324-5335
[31] 毕静利,孙彩虹,张艳君,等.气相色谱法测定聚碳酸酯中的二氯甲烷[J].化学分析计量, 2018,27(5):102-104. Bi J L, Sun C H, Zhang Y J, et al. Determination of dichloromethane in polycarbonate by gas chromatography[J]. Chemical Analysis and Meterage, 2018,27(5):102-104.
[32] 刘文文,方莉,郭秀锐,等.京津冀地区典型印刷企业VOCs排放特征及臭氧生成潜势分析[J].环境科学, 2019,40(9):3942-3948. Liu W W, Fang L, Guo X R, et al. Emission characteristics and ozone formation potential of VOCs in printing enterprises in Beijing-Tianjin-Hebei[J]. Environmental Science, 2019,40(9):3942-3948.
[33] 景盛翱,王红丽,朱海林,等.典型工业源VOCs治理现状及排放组成特征[J].环境科学, 2018,39(9):3090-3095. Jing S H, Wang H L, Zhu H L, et al. Treatment status and emission characteristics of volatile organic compounds from typical industrial sources[J]. Environmental Science, 2018,39(9):3090-3095.