北京冬季一次重污染过程的污染特征及成因分析

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摘要

为了研究北京冬季重污染过程的污染特征及形成原因,选取2013年1月9~15日一次典型重污染过程,对污染期间气象要素、大气颗粒物组分特征和天气背景场进行综合研究.结果表明,此次大气重污染过程中PM₁₀和PM_2.5平均质量浓度分别为347.7μg/m³和222.4μg/m³,均超过环境空气质量标准(GB3095-2012)中规定的日均二级浓度限值.重污染时段PM_2.5中NH₄⁺、NO₃^-和SO₄²^-质量浓度之和占PM_2.5质量浓度的44.0%,OC/EC的平均比值为5.44,说明二次无机离子和有机物对此次污染过程中PM_2.5贡献较大.稳定的大气环流背景场、高湿度低风速的地面气象条件和低而厚的逆温层导致北京地区大气层结稳定,加上北京三面环山的特殊地形结构,是造成此次大气重污染过程的主要原因.

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关键词 ：重污染, PM_2.5, 化学组分, 污染特征, 北京市

Abstract：

In order to study the characteristics and formation mechanism during a heavy air pollution episode in Beijing during 9~15January in 2013, the weather conditions, chemical characteristics of particulate matter and atmospheric environmental background were analyzed. The results showed that the average daily mass concentrations of PM₁₀ and PM_2.5 were 347.7μg/m³and 222.4μg/m³, respectively, exceeding the corresponding ambient air quality standards (GB3095-2012) of China. During the pollution episode, NH₄⁺, NO₃^- and SO₄²^- made a combined contribution of 44.0% to PM_2.5 concentration. The average ratios of OC/EC were 5.44. This indicates a large contribution from secondary ions and organic matters to PM_2.5. The atmosphere was relatively stable during the study period in Beijing because of the stable atmosphere circulation, the adverse near-ground meteorological conditions of high humidity and low wind speed as well as the lower and deeper inversion layer. The stable atmospheric condition and the land structure surrounded by mountains on three sides in Beijing restrained the dispersion of pollutants, and these were the main causes of this heavy pollution process.

Key words： heavy pollution PM_2.5 chemical composition pollution characteristics Beijing

收稿日期: 2015-06-26

PACS:

X513

基金资助:

国家自然科学基金(91544232);国家环保公益性行业科研专项(201409006);北京市科技计划(Z141100001014002)

通讯作者: 程水源, 教授, chengsy@bjut.edu.cn E-mail: chengsy@bjut.edu.cn

作者简介: 杨孝文(1989-), 男, 北京市人, 博士, 主要从事环境规划管理与污染防治研究.

引用本文:

杨孝文, 周颖, 程水源, 王刚, 王晓琦. 北京冬季一次重污染过程的污染特征及成因分析[J]. 中国环境科学, 2016, 36(3): 679-686. YANG Xiao-wen, ZHOU Ying, CHENG Shui-yuan, WANG Gang, WANG Xiao-qi. Characteristics and formation mechanism of a heavy winter air pollution event in Beijing. CHINA ENVIRONMENTAL SCIENCECE, 2016, 36(3): 679-686.

链接本文:

http://manu36.magtech.com.cn/Jweb_zghjkx/CN/ 或 http://manu36.magtech.com.cn/Jweb_zghjkx/CN/Y2016/V36/I3/679

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