Effect of combined cooling and heating methods on low-temperature drying of municipal dewatered sludge
FANG Xing, LI Zhi-hua, YANG Cheng-jian
1. Key Laboratory of Northwest Water Resource, Environment and Ecology, Ministry of Education, Shaanxi Key Laboratory of Environmental Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
This work was to explore the feasibility of drying municipal dewatered sludge by combined cooling and heating methods, and to reveal the influence of the freezing operation on the drying of dewatered sludge at low temperatures. The experimental sludge samples were collected in a municipal wastewater treatment plant after mechanically dewatering. The influence of freezing operation was studied with scanning electron microscopy (SEM) and flow cytometry. In addition, the influence of different freezing temperatures and time on the characteristics of the drying process for the dewatered sludge were also investigated, as well as the effect of combined cooling and heating methods on the dewatered sludge with different moisture contents and cake thickness. It was found that the freezing operation could increase the micropores inside the sludge samples. When the temperature was reduced to -30℃, the death rate of cells exhibited 15.5%, which was 9.7 times higher than that under unfrozen condition. With the drying temperature set at 60℃, as well as freezing temperatures at -10℃, -20℃ and -30℃, respectively, the drying effect was strengthened and the drying rates were improved by 25.0%, 33.3% and 29.2%, correspondingly. Especially, after freezing for 6 hours, the drying rate of the sludge sample reached the highest value, which had the weight of 5g ±0.1g, the cake thickness of 3mm and the diameter of 50mm. It was also found that the decrease in moisture content might weaken the strengthening effect, which was even lost when the content reduced to 45%. The increase of sludge cake thickness might decline the drying rate as well, which exhibited the values of 33.3%, 31.3% and 30.4% at the thickness of 5mm, 10mm and 15mm, respectively. In a word, this work might provide a valuable reference for the development of the sludge drying process using a heat pump with the combined cooling and heating methods.
方兴, 李志华, 杨成建. 冷热联用对市政脱水污泥低温干燥的影响[J]. 中国环境科学, 2020, 40(6): 2546-2553.
FANG Xing, LI Zhi-hua, YANG Cheng-jian. Effect of combined cooling and heating methods on low-temperature drying of municipal dewatered sludge. CHINA ENVIRONMENTAL SCIENCECE, 2020, 40(6): 2546-2553.
Hong J, Xu C, Hong J, et al.Life cycle assessment of sewage sludge co-incineration in a coal-based power station [J].Waste Management, 2013,33(9):1843-1852.
[2]
Jin L, Zhang G, Tian H.Current state of sewage treatment in china [J].Water Research, 2014,66:85-98.
[3]
郭俊元,文小英,贾晓娟,等.磁性壳聚糖改善污泥脱水性能的研究[J].中国环境科学, 2019,39(7):2944-2952. Guo J Y, Wen X Y, Jia X J, et al.Preparation of magnetic chitosan and improvement of dewatering performance of sludge [J].China Environmental Science, 2019,39(7):2944-2952.
[4]
Ma W, Du G, Li J, et al.Supercritical water pyrolysis of sewage sludge [J].Waste Management, 2017,59:371-378.
[5]
Liu X, Chang F, Wang C, et al.Pyrolysis and subsequent directcombustion of pyrolytic gases for sewage sludge treatment in china [J].Applied Thermal Engineering, 2017,128.
[6]
张晨,李杨杨,董黎明,等.预加热对柠檬酸脱水污泥冬季生物干化的影响[J].中国环境科学, 2019,39(7):2928-2937. Zhang C, Li Y Y, Dong L M, et al.Effect of pre-heating on bio-drying of citric acid dewatered sludge in winter [J].China Environmental Science, 2019,39(7):2928-2937.
[7]
Kulikowska D.Kinetics of organic matter removal and humification progress during sewage sludge composting [J].Waste Management, 2016,49:196-203.
[8]
郭思宇,彭永臻,李夕耀,等.热处理对剩余污泥中温厌氧消化的影响[J].中国环境科学, 2017,37(6):2106-2113. Guo S Y, Peng Y Z, Li X Y, et al.Effect of thermal hydrolysis pretreatment on mesophilic anaerobic digestion of excess sludge [J].China Environmental Science, 2017,37(6):2106-2113.
[9]
Nazari L, Yuan Z, Santoro D, et al.Low-temperature thermal pre-treatment of municipal wastewater sludge: Process optimization and effects on solubilization and anaerobic degradation [J].Water Research, 2017,113:111-123.
[10]
Deng W, Su Y.Experimental study on agitated drying characteristics of sewage sludge under the effects of different additive agents [J].J Environ Sci (China), 2014,26(7):1523-1529.
[11]
Ali I, Abdelkader L, El Houssayne B, et al.Solar convective drying in thin layers and modeling of municipal waste at three temperatures [J].Applied Thermal Engineering, 2016,108:41-47.
[12]
Horttanainen M, Deviatkin I, Havukainen J.Nitrogen release from mechanically dewatered sewage sludge during thermal drying and potential for recovery [J].Journal of Cleaner Production, 2017,142: 1819-1826.
[13]
Li H, Zou S, Li C.Liming pretreatment reduces sludge build-up on the dryer wall during thermal drying [J].Drying Technology, 2012, 30(14):1563-1569.
[14]
Weng H, Dai Z, Ji Z, et al.Release and control of hydrogen sulfide during sludge thermal drying [J].Journal of Hazardous Materials, 2015,296:61-67.
[15]
赵芳,程道来,陈振乾.超声波处理对污泥热风干燥过程的影响[J].农业工程学报, 2015,31(4):272-276. Zhao F, Cheng D L, Chen ZQ.Effect of ultrasonic treatment on hot air drying process of sludge [J].Transactions ofthe Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2015,31(4):272-276.
[16]
Zhang X, Chen M, Huang Y.Isothermal drying kinetics of municipal sewage sludge coupled with additives and freeze-thaw pretreatment [J].Journal of Thermal Analysis & Calorimetry, 2017,128(2):1195-1205.
[17]
Hu K, Jiang JQ, Zhao QL, et al.Conditioning of wastewater sludge using freezing and thawing: Role of curing [J].Water Research, 2011, 45(18):5969-5976.
[18]
魏砾宏,张雄,李润东,等.脱水污泥颗粒等温干燥特性实验研究[J].环境科学学报, 2012,32(7):1631-1636. Wei L H, Zhang X, Li R D, et al.Experimental characterization of isothermal drying of dewatered sewage sludge particle [J].Acta Scientiae Circumstantiae, 2012,32(7):1631-1636
[19]
曹雷,马德刚,白繁义,等.城市污泥的低温热干燥[J].环境工程学报, 2016,10(9):5217-5221. Cao L, Ma D G, Bai F Y, et al.Urban sludge thermo drying under low temperature [J].Chinese Journal of Environmental Engineering, 2016,10(9):5217-5221
[20]
马学文,翁焕新,章金骏.不同形状污泥干燥特性的差异性及其成因分析[J].中国环境科学, 2011,31(5):803-809. Ma X W, Weng H X, Zhang J J.Difference and cause analysis of drying characteristics of different shapes sludge [J].China Environmental Science, 2011,31(5):803-809.
[21]
李朋刚.热泵污泥干燥系统设计及特性研究[D].哈尔滨:哈尔滨工业大学, 2018. Li P G.Research on the design and characteristics of the heat pump sludge drying system [D].Harbin:Harbin Institute of Technology, 2018.
[22]
饶宾期,曹黎.太阳能热泵污泥干燥技术[J].农业工程学报, 2012, 28(5):184-188. Rao B Q, Cao L.Technical research on sludge drying by solar energy and heat pump [J].Transactions ofthe Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2012,28(5):184-188.
[23]
张璧光,李梁,张振涛,等.污泥热泵干燥速率及能耗的实验研究[J].干燥技术与设备, 2007,(5):220-224. Zhang B G, Li L, Zhang Z T, et al.Experimental study on sludge drying rate and energy consumption [J].Drying Technology & Equipment, 2007,(5):220-224.
[24]
Maidment G G, Zhao X, Riffat S B.Combined cooling and heating using a gas engine in a supermarket [J].Applied Energy, 2001,68(4): 321-335.
[25]
Iglesias M, Rodriguez J, Franco D.Monitoring of building heating and cooling systems based on geothermal heat pump in galicia (spain) [J].European Physical Journal Conferences, 2012,33:05004.
[26]
Li T X, Wang R Z, Yan T, et al.Integrated energy storage and energy upgrade, combined cooling and heating supply, and waste heat recovery with solid-gas thermochemical sorption heat transformer [J].International Journal of Heat and Mass Transfer, 2014,76:237-246.
[27]
彭发展,张信荣.利用天然工质的食品加工行业冷热联供技术[J].制冷与空调, 2015,15(12):67-71. Peng F Z, Zhang X R.Combined heating and cooling technology using natural fluids in food processing industry [J].Refrigeration and Air-Conditioning, 2015,15(12):67-71.
Liu J, Ding Y L, Bartlam M, et al.Microbial community analysis of underground drinking water using denaturing gradient gel electrophoresis and flow cytometry technologies [J].Applied Mechanics & Materials, 2014,700:519-524.
[30]
Phalakornkule C, Nuchdang S, Khemkhao M, et al.Effect of freeze-thaw process on physical properties, microbial activities and population structures of anaerobic sludge [J].Journal of Bioscience & Bioengineering, 2017,123(4):474.
[31]
Tuan PA, Sillanpää M.Effect of freeze/thaw conditions, polyelectrolyte addition, and sludge loading on sludge electro-dewatering process [J].Chemical Engineering Journal, 2010,164(1): 85-91.
[32]
Gao W.Freezing as a combined wastewater sludge pretreatment and conditioning method [J].Desalination, 2011,268(1):170-173.
[33]
Tao T, Peng X F, Lee D J, et al.Micromechanics of wastewater sludge floc: Force-deformation relationship at cyclic freezing and thawing [J].298(2):860-868.
[34]
Zhang X Y, Chen M Q.A comparison of isothermal with nonisothermal drying kinetics of municipal sewage sludge [J].Journal of Thermal Analysis & Calorimetry, 2015,123(1):1-9.