典型工业废水中全氟化合物处理技术研究进展

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摘要通过分析镀铬、农药、纺织等行业对PFCs的应用及排放情况，总结了各类工业废水的特点及分布，综述了近年来国内外研究学者针对半导体废水、镀铬废水等实际工业废水中PFCs去除技术的研究进展，分析了吸附法、高级氧化法等处理技术应用于实际废水中的机理及利弊，以期为今后PFCs实际废水处理研究发展提供了理论基础.

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	张春晖
	刘育
	唐佳伟
	王文倩
	唐元晖
	许斌
	邓建军
	贾广如
	王健
	魏巍
	杨林浩

关键词 ：全氟类化合物, 工业废水, 吸附, 高级氧化技术

Abstract：This paper firstly analyzes the application and discharge of PFCs in the industries of chromium plating, pesticide, textile, et al., and then summarizes the characteristics and distribution of various industrial wastewater. Subsequently, the research progress of PFCs removal technology in practical industrial wastewater including chromium plating wastewater and semiconductor wastewater was reviewed. Mechanism, advantages and disadvantages of various technologies including adsorption and advanced oxidation in practical wastewater treatment are analyzed. This work provides theoretical basis and suggestions for the future development of PFCs wastewater treatment.

Key words： perfluorinated compounds industrial wastewater adsorption advanced oxidation technology

收稿日期: 2020-07-08

PACS:

X703

基金资助:国家水体污染控制与治理科技重大专项（2017ZX07402001）；国家重点研发计划（2018YFC0406400）

通讯作者: 张春晖,教授,ZCHcumtb@hotmail.com E-mail: ZCHcumtb@hotmail.com

作者简介: 张春晖(1973-),男,河北省景县人,教授,博士,主要研究方向为水污染控制工程.发表论文40余篇.

引用本文:

张春晖, 刘育, 唐佳伟, 王文倩, 唐元晖, 许斌, 邓建军, 贾广如, 王健, 魏巍, 杨林浩. 典型工业废水中全氟化合物处理技术研究进展[J]. 中国环境科学, 2021, 41(3): 1109-1118. ZHANG Chun-hui, LIU Yu, TANG Jia-wei, WANG Wen-qian, TANG Yuan-hui, XU Bin, DENG Jian-jun, JIA Guang-ru, WANG Jian, WEI Wei, YANG Lin-hao. Progress of research on treatment technology of perfluorinated compounds in typical industrial wastewater. CHINA ENVIRONMENTAL SCIENCECE, 2021, 41(3): 1109-1118.

链接本文:

http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2021/V41/I3/1109

[1]	Sagiv S K, Rifas-Shiman S L, Webster T F, et al. Sociodemographic and perinatal predictors of early pregnancy per-and polyfluoroalkyl substance (PFAS) concentrations[J]. Environmental ence & Technology, 2015,49(19):11849-11855.
[2]	祝凌燕,林加华.全氟辛酸的污染状况及环境行为研究进展[J]. 应用生态学报, 2008,19(5):1149-1157. Zhu L, Lin J. Pollution trend and environmental behavior of perfluorooctanoic acid:A review.[J]. Chinese Journal of Applied Ecology, 2008,19(5):1149-1157.
[3]	Wang Z, Dewitt J C, Higgins C P, et al. A never-ending story of per-and polyfluoroalkyl substances (pfass)[J]. Environmental ence and Technology, 2017,51(5):2508-2518.
[4]	史亚利,潘媛媛,王杰明,等.全氟化合物的环境问题[J]. 化学进展, 2009,21(Z1):369-376. Shi Y, Pan Y, Wang J, et al. Perfluorinated chemicals related environmental problems[J]. Progress in Chemistry, 2009,21(Z1):369-376.
[5]	Zushi Y, Takeda T, Masunaga S. Existence of nonpoint source of perfluorinated compounds and their loads in the Tsurumi River basin, Japan[J]. Chemosphere, 2008,71(8):1566-1573.
[6]	Hansen K J, Johnson H O, Eldridge J S, et al. Quantitative characterization of trace levels of PFOS and PFOA in the Tennessee River[J]. Environmental Science & Technology, 2002,36(8):1681-1685.
[7]	金一和,刘晓,秦红梅,等.我国部分地区自来水和不同水体中的PFOS污染[J]. 中国环境科学, 2004,24(2):166-169. Jin Y, Liu X, Qin H, et al. The status quo of perfluorooctane sulfonate (PFOS) pollution in tap water and different waters in partial areas of China[J]. China Environmental Science, 2004,24(2):166-169.
[8]	Mak Y L, Taniyasu S, Yeung L W Y, et al. Perfluorinated compounds in tap water from china and several other countries[J]. Environmental Science & Technology, 2009,43(13):4824-4829.
[9]	童锡臻,石宝友,解岳,等.改性活性炭对水中PFOS的吸附去除研究[J]. 环境科学, 2012,33(9):3132-3138. Tong X, Shi B, Xie Y, et al. Adsorption of perfluorooctane sulfonate (PFOS) onto modified activated carbons[J]. Environmental Science, 2012,33(9):3132-3138.
[10]	孙博,马军.离子交换树脂对水中全氟羧酸的吸附去除[J]. 水处理技术, 2017,(1):22-26. Sun B, Ma J. Removal of perfluorocarboxylic acids from water by anion exchange resins[J]. Technology of Water Treatment, 2017,(1):22-26.
[11]	王涛,李烨,马文瑾,等. PMIA中空纤维纳滤膜去除饮用水中的PFOS[J]. 水处理技术, 2015,(7):103-108. Wang T, Li Y, Ma W, et al. Removal of perfluorooctane sulfonate (PFOS) from drinking water using pmia hollow fiber nanofiltration membrane[J]. Technology of Water Treatment, 2015,(7):103-108.
[12]	卓琼芳,韩姣,虢清伟,等.电化学氧化PFOA阳极材料筛选及其机制研究[C]//2015年中国环境科学学会学术年会论文集. Zhuo Q, Han J, Yi Q, et al. Screening of PFOA anode materials for electrochemical oxidation and its mechanism[C]//Proceedings of the 2015 Annual Conference of the Chinese Society of Environmental Sciences.
[13]	李明洁.二氧化钛和铂掺二氧化钛光催化降解全氟辛酸的机制研究[D]. 南宁:广西大学, 2014. Li M. Photocatalytic degradation of perfluorooctanoic acid (PFOA) by TiO2 and Pt doped TiO2[D]. Nanning:Guangxi University, 2014.
[14]	Zhang L, Liu J, Hu J, et al. The inventory of sources, environmental releases and risk assessment for perfluorooctane sulfonate in China[J]. Environmental Pollution, 2012,165:193-198.
[15]	吴广龙,余立风,胡乐,等.我国削减并逐步替代全氟辛烷磺酸盐(PFOS)的策略与建议[J]. 生态毒理学报, 2012,(5):17-22. Wu G, Yu L, Hu L, et al. Strategies for eliminating production and substituting perfluorooctane sulfonate (PFOS) in china[J]. Asian Journal of Ecotoxicology, 2012,(5):17-22.
[16]	樊陆欢,项平,洪岚.江苏省PFOS生产使用现状分析[J]. 低碳世界, 2017,(6):24-25. Fan L, Xiang P, Hong L. Present situation analysis of perfluorooctane sulfonate (PFOS) production and use in jiangsu province[J]. Low Carbon World, 2017,(6):24-25.
[17]	刘超,胡建信,刘建国,等.镀铬企业周边全氟辛烷磺酰基化合物环境风险评价[J]. 中国环境科学, 2008,28(10):950-954. Liu C, Hu J, Liu J, et al. Environmental risk assessment of perfluorooctane sulphonate near chromium plating site[J]. China Environmental Science, 2008,28(10):950-954.
[18]	朱冰春,许天明,孔小林,等.全氟异丙基苯衍生物的合成及其在新农药创制中的应用[J]. 农药, 2009,48(10):712-714. Zhu B, Xu T, Kong X, et al. Synthesis of perfluoroisopropyl benzenes and its application in the discovery of innovative chemicals[J]. Agrochemicals, 2009,48(10):712-714.
[19]	余威,王鹏翔,田亮,等.PFOS受控的公约进展及中国消防行业使用PFOS情况[J]. 消防科学与技术, 2010,(6):61-63. Yu W, Wang P, Tian L, et al. The latest information of the Stockholm Convention and an introduction of the using of PFOS in China fire industry[J]. Fire Science and Technology, 2010,(6):61-63.
[20]	FDMPS, Fire Department of Ministry of Public Security of China[M]. China Fire Services, 2009:420-425.
[21]	夏晓慧,牛增元,姚鹏,等.皮革中全氟化合物检测技术研究进展[J]. 皮革科学与工程, 2019,29(2):36-42. Xia X, Niu Z, Yao P, et al. Progress in the detection technology of perfluorinated compounds in leather[J]. Leather Science and Engineering, 2019,29(2):36-42.
[22]	纪涛.农药废水预处理技术及生化处理效果研究[J]. 中国航班, 2019,(8):103-103. Ji T. A study on the pretreatment technology and biochemical treatment effect of pesticide wastewater[J]. China Flights, 2019,(8):0103-0103.
[23]	游伟民.皮革废水治理技术的研究进展[J]. 皮革与化工, 2009,(2):20-24. You W. Research progress in techniques of tannery wastewater treatment[J]. Leather and Chemicals, 2009,(2):20-24.
[24]	刘路.纺织印染废水处理技术研究现状及进展[J]. 上海工程技术大学学报, 2017,31(2):174-177. Liu L. Research state and progress of textile printing and dyeing wastewater treatment technologies[J]. Journal of Shanghai University of Engineering Science, 2017,31(2):174-177.
[25]	张盼盼.水体中持久性有机污染物PFOS的去除方法研究[D]. 北京:首都经济贸易大学, 2016. Zhang P. Removal of persistent organic pollutants PFOS in water[D]. Beijing:Capital University of Economics and Business, 2016.
[26]	Deng S, Yu Q, Huang J, et al. Removal of perfluorooctane sulfonate from wastewater by anion exchange resins:Effects of resin properties and solution chemistry[J]. Water Research, 2010,44(18):5188-5195.
[27]	Punyapalakul P, Suksomboon K, Prarat P, et al. Effects of surface functional groups and porous structures on adsorption and recovery of perfluorinated compounds by inorganic porous silicas[J]. Separation Science & Technology, 2013,48(5):775-788.
[28]	Tang C Y, Fu Q S, Gao D, et al. Effect of solution chemistry on the adsorption of perfluorooctane sulfonate onto mineral surfaces[J]. Water Research, 2010,44(8):2654-2662.
[29]	Chen X, Xia X, Wang X, et al. A comparative study on sorption of perfluorooctane sulfonate (PFOS) by chars, ash and carbon nanotubes[J]. Chemosphere, 2011,83(10):1313-1319.
[30]	Du Z, Deng S, Bei Y, et al. Adsorption behavior and mechanism of perfluorinated compounds on various adsorbents-A review[J]. Journal of Hazardous Materials, 2014,274:443-454.
[31]	Du Z, Deng S, Liu D, et al. Efficient adsorption of PFOS and F53B from chrome plating wastewater and their subsequent degradation in the regeneration process[J]. Chemical Engineering Journal, 2016, 290(15):405-413.
[32]	孙博.离子交换与吸附及活化过硫酸盐氧化去除水中全氟有机物[D]. 哈尔滨:哈尔滨工业大学, 2018. Sun B. Removal of perfluorinated compounds in water by anion exchange and adsorption and activated persulfate oxidation[D]. Harbin:Harbin Institute of Technology, 2018.
[33]	Gao Y, Deng S, Du Z, et al. Adsorptive removal of emerging polyfluoroalky substances F-53B and PFOS by anion-exchange resin:A comparative study[J]. Journal of Hazardous Materials, 2016,323:550-557.
[34]	Du Z, Deng S, Chen Y, et al. Removal of perfluorinated carboxylates from washing wastewater of perfluorooctanesulfonyl fluoride using activated carbons and resins[J]. Journal of Hazardous Materials, 2015,286:136-143.
[35]	杜子文.吸附去除废水中全氟化合物及高选择性氟化吸附剂的研究[D]. 北京:清华大学, 2017. Du Z. Adsorptive removal of perfluorinated compounds from industrial wastewater and preparation of highly selective fluorinated adsorbents[D]. Beijing:Tsinghua University, 2017.
[36]	Zhang C, Jiang S, Tang J, et al. Adsorptive performance of coal based magnetic activated carbon for perfluorinated compounds from treated landfill leachate effluents[J]. Transactions of the Institution of Chemical Engineers Process Safety & Environmental Protection Part B, 2018,117:383-389.
[37]	Tang J, Liu Y, Su P, et al. Removal of COD, NH4-N, and perfluorinated compounds from wastewater treatment plant effluent using ZnO-coated activated carbon[J]. Water Science & Technology, 2020,81(11):2459-2470.
[38]	刘洋,胡筱敏,赵研,等.全氟化合物及其替代品的处理技术[J]. 环境化学, 2018,37(8):1860-1868. Liu Y, Hu X, Zhao Y, et al. Treatment techniques for perfluorinated compounds and their alternatives[J]. Environmental Chemistry, 2018, 37(8):1860-1868.
[39]	Hang X, Chen X, Luo J, et al. Removal and recovery of perfluorooctanoate from wastewater by nanofiltration[J]. Separation & Purification Technology, 2015,145(5):120-129.
[40]	Steinle-Darling E, Reinhard M. Nanofiltration for trace organic contaminant removal:structure, solution, and membrane fouling effects on the rejection of perfluorochemicals[J]. Environmental Science & Technology, 2008,42(14):5292-5297.
[41]	王钦,南碎飞,窦梅.纳滤法处理低浓度全氟辛酸铵废水的研究[J]. 高校化学工程学报, 2008,(4):142-147. Wang Q, Nan S, Dou M. Experimental investigation on nanofiltration treatment of waste water containing low concentration ammonium perfluorooctanoate[J]. Journal of Chemical Engineering of Chinese Universities, 2008,(4):142-147.
[42]	李垣皓,林秋风,罗峰,等.全氟有机化合物污染近况及去除技术探讨[J]. 水处理技术, 2018,(9):7-11. Li Y, Lin Q, Dou M, et al. Removal technology and current situation of perfluorotyped organic compounds pollution[J]. Technology of Water Treatment, 2018,(9):7-11.
[43]	高士奇,孙力平,张浩,等.运用GC/MS对反渗透工艺过程水中痕量有机物的去除效果考查[J]. 中国建设信息:水工业市场, 2009,(12):60-63. Gao S, Sun L, Zhang H, et al. Analysis of trace organic compounds removal effect in RO process by GC/MS[J]. Information of China Construction. Water-Industry Market, 2009,(12):60-63.
[44]	Tang C, Fu Q, Robertson A, et al. Use of reverse osmosis membranes to remove perfluorooctane sulfonate (PFOS) from semiconductor wastewater[J]. environmental science & technology, 2006,40(23):7343-7349.
[45]	南碎飞,王斐,王钦,等.纳滤和泡沫分离联合处理含全氟辛酸铵废水的研究[J]. 高校化学工程学报, 2009,(4):167-172. Nan S, Wang F, Wang Q, et al. Process integration of nanofiltration and foam separation for disposal of waste water with low concentration ammonium perfluorooctanoate[J]. Journal of Chemical Engineering of Chinese Universities, 2009,(4):167-172.
[46]	Tsai Y T, Lin Y C, Weng Y H, et al. Treatment of perfluorinated chemicals by electro-microfiltration[J]. Environmental Science & Technology, 2010,44(20):7914-7920.
[47]	Trojanowicz M, Bojanowska-Czajka A, Bartosiewicz I, et al. Advanced oxidation/reduction processes treatment for aqueous perfluorooctanoate (PFOA) and perfluorooctanesulfonate (PFOS)-A review of recent advances[J]. Chemical Engineering Journal, 2018, 336:170-199.
[48]	Chaplin B P. Critical review of electrochemical advanced oxidation processes for water treatment applications[J]. Environmental Science:Processes & Impacts, 2014,16(6):1182-1203.
[49]	Sirés I, Brillas E, Oturan M, et al. Electrochemical advanced oxidation processes:today and tomorrow. A review[J]. Environmental ence & Pollution Research, 2014,21(14):8336-8337.
[50]	Zhang C, Tang J, Peng C, et al. Degradation of perfluorinated compounds in wastewater treatment plant effluents by electrochemical oxidation with Nano-ZnO coated electrodes[J]. Journal of Molecular Liquids, 2016,221:1145-1150.
[51]	Schaefer C E, Andaya C, Urtiaga A, et al. Electrochemical treatment of perfluorooctanoic acid (PFOA) and perfluorooctane sulfonic acid (PFOS) in groundwater impacted by aqueous film forming foams (AFFFs)[J]. Journal of Hazardous Materials, 2015,295(15):170-175.
[52]	Schaefer C E, Andaya C, Burant A, et al. Electrochemical treatment of perfluorooctanoic acid and perfluorooctane sulfonate:Insights into mechanisms and application to groundwater treatment[J]. Chemical Engineering Journal, 2017,317(1):424-432.
[53]	Beatriz G, Sonia G, Nazely D, et al. Efficient electrochemical degradation of poly-and perfluoroalkyl substances (PFASs) from the effluents of an industrial wastewater treatment plant[J]. Chemical Engineering Journal, 2017,322:196-204.
[54]	Mattia P, Małgorzata S, Barbara K, et al. Electrochemical oxidation of PFOA and PFOS in landfill leachates at low and highly boron-doped diamond electrodes[J]. Journal of Hazardous Materials, 2020.
[55]	Qian Y, Guo X, Zhang Y, et al. Perfluorooctanoic acid degradation using uv-persulfate process:modeling of the degradation and chlorate formation[J]. Environmental Science & Technology, 2016,50(2):772-781.
[56]	Lin Y C, Panchangam S C, Chang C Y, et al. Removal of perfluorooctanoic acid and perfluorooctane sulfonate via ozonation under alkaline condition[J]. Journal of Hazardous Materials, 2012,243:272-277.
[57]	Li P, Zhi D, Zhang X, et al. Research progress on the removal of hazardous perfluorochemicals:A review[J]. Journal of Environmental Management, 2019,250(15).
[58]	Cheng J, Vecitis C D, Park H, et al. Sonochemical degradation of perfluorooctane sulfonate (PFOS) and perfluorooctanoate (PFOA) in landfill groundwater:environmental matrix effects[J]. Environmental Science & Technology, 2008,42(21):8057-8063.
[59]	Liang S, Pierce Jr. R, Lin H, et al. Electrochemical oxidation of PFOA and PFOS in concentrated waste streams[J]. Remediation the Journal of Environmental Cleanup Costs Technologies & Techniques, 2018,28:127-134.
[60]	王凯,郭昌胜,张远,等.不同微生物处理工艺对全氟化合物的去除效果[J]. 环境科学研究, 2015,28(1):110-116. Wang K, Guo C, Zhang Y, et al. Removal efficiency of perfluorinated compounds with different microbial treatment techniques[J]. Research of Environmental Sciences, 2015,28(1):110-116.
[61]	范庆,邓述波,周琴,等.城市污水处理厂中全氟化合物的存在及去除效果研究[J]. 环境污染与防治, 2011,33(1):43-48. Fan Q, Deng S, Zhou Q, et al. Occurrence and removal of perfluorinated compounds in municipal wastewater treatment plants[J]. Environmental Pollution & Control, 2011,33(1):43-48.
[62]	Qu Y, Zhang C, Li F, et al. Photo-reductive defluorination of perfluorooctanoic acid in water[J]. Water Research, 2010,44(9):2939-2947.
[63]	Bao Y, Huang J, Cagnetta G, et al. Removal of F-53B as PFOS alternative in chrome plating wastewater by UV/Sulfite reduction[J]. Water Research, 2019,163:114907.
[64]	黄俊.全氟化合物的检测方法开发及在污水处理中的残留特征[D]. 哈尔滨:哈尔滨工业大学, 2010. Huang J. Analysis of perfluorinated compounds and evaluation of their fate in wasterwater treatment plant[D]. Harbin:Harbin Institute of Technology, 2010.