Analysis of recognition and transmission path for organic nitrogen and phosphorus pollutants in representative cities section of lower Yangtze River
YU Ming-xing1, SU Hai1, LI Ming-yang1, WU Xiao-jian2, ZHANG Kai2, MA Pan2,3, MA Yu-ning2,3, HU Guan-jiu4
1. Ecological Environment Monitoring and Scientific Research Center, Ecology and Environment Supervision and Administration Bureau of Yangtze Valley, Ministry of Ecology and Environment of the People's Republic of China, Wuhan 430010, China; 2. Focused Photonics(Hangzhou), Inc., Hangzhou 310052, China; 3. College of Environmental & Resource Sciences, Zhejiang University, Hangzhou 310012, China; 4. Jiangsu Provincial Environmental Monitoring Center, Nanjing 210019, China
Abstract：The study investigated water samples from eight sampling sites along the main urban river path, tributaries, and the merger of ditch gates of the lower course of the Yangtze basin. The profiles, sources and transport pathways of nitrogen, phosphorus, and related organic pollutants in the selected part of the river were analyzed using high-throughput non-targeted screening technology combined with multivariate statistical analysis. A total of sixty organic pollutants were identified in the research area including eleven organic nitrogen compounds, such as aminomethanesulphonic acid, carbamide, and benzonitrile, and two organic phosphorus compounds, 4-hydroxyphenylphosphonic acid and trimethyl thiophosphate. Most of the discharges were from the production of pharmaceuticals and pesticides, the daily use of pharmaceuticals and personal care products, and the manufacturing of raw and auxiliary materials. The chemicals travelled down the watershed via three routes, dominated by inorganic phosphorus transport with certain amount of organonitrogen involved, dominated by organonitrogen transport with certain amount of organophosphorus involved, or dominated by the transport of organonitrogen in combine with organophosphorus compounds. The inflow of the screened organics was predominantly influenced by hydrological factors and consistent with the water flow direction. The source apportionment from upstream inflow and regional input needs to be considered as well.
余明星, 苏海, 李名扬, 吴效俭, 张凯, 马攀, 马煜宁, 胡冠九. 长江下游典型城市江段有机氮磷识别及传输路径[J]. 中国环境科学, 2023, 43(7): 3604-3615.
YU Ming-xing, SU Hai, LI Ming-yang, WU Xiao-jian, ZHANG Kai, MA Pan, MA Yu-ning, HU Guan-jiu. Analysis of recognition and transmission path for organic nitrogen and phosphorus pollutants in representative cities section of lower Yangtze River. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(7): 3604-3615.
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