Fenton氧化处理焦化废水的工艺优化及有机物降解机制

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摘要采用Fenton反应对焦化废水中污染物进行氧化处理,考察时间、pH值、H₂O₂/COD质量比和Fe²⁺/H₂O₂物质的量比对于焦化废水的降解效果,并采用响应曲面法进行参数优化,同时探究反应中有机物组分的变化规律.结果表明:Fenton氧化对于焦化废水有较好的处理效果,当pH=3.19、m(H₂O₂/COD)为1.72、n(Fe²⁺/H₂O₂)为0.74、反应时间为40min的条件下,COD的去除率达到72.69%.处理后废水的可生化性(B/C)比由0.24提高至0.32.对反应前后焦化废水中有机物进行分析,原水中共有21种有机物,种类复杂多为大分子物质,Fenton出水中有机物种类显著减少为14种.其中,含氮类有机物被完全降解,部分芳香族化合物中的苯环裂解,大部分长链有机物断裂为短链有机物,整体分子量减小.

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	冉玉芳
	徐春
	李鑫鹏
	宫瑶
	冯卫博
	胡家硕
	赵承旺

关键词 ： Fenton氧化, 焦化废水, 响应曲面法, 有机物分析, 机理

Abstract：In this study, Fenton reaction was used to oxidize pollutants in coking wastewater, and the degradation effects of time, pH, H₂O₂/COD mass ratio and Fe²⁺/H₂O₂ molar ratio on coking wastewater were investigated. The response surface method (RSM) was used to optimize parameters, and the change rule of organic compounds in the reaction was explored. The results show that Fenton oxidation has a good treatment effect on coking wastewater. Under the conditions of pH=3.19, m(H₂O₂/COD) 1.72, n(Fe²⁺/H₂O₂) 0.74 and reaction time 40min, the COD removal rate was 72.69%. The B/C ratio of treated wastewater increased from 0.24 to 0.32. According to the analysis of organic matter in coking wastewater before and after the reaction, there were 21 kinds of organic matter in raw water, most of which were macromolecular substances with complex types, while the number of organic matter in Fenton effluent was significantly reduced to 14. Among them, nitrogen-containing organic matter was completely degraded, some aromatic compounds in the benzene ring cracked, most of the long chain organic matter was broken into short chain organic matter, and the overall molecular weight decreased.

Key words： fenton oxidation coking wastewater response surface method organics analysis mechanism

收稿日期: 2023-04-13

PACS:

X703

基金资助:重庆钢铁有限公司技术攻关课题(2234000004)

通讯作者: 冉玉芳,助理工程师,1932568689@qq.com E-mail: 1932568689@qq.com

作者简介: 冉玉芳(1996-),女,重庆酉阳人,助理工程师,学士,主要从事废水处理工艺研究.发表论文2篇.1932568689@qq.com.

引用本文:

冉玉芳, 徐春, 李鑫鹏, 宫瑶, 冯卫博, 胡家硕, 赵承旺. Fenton氧化处理焦化废水的工艺优化及有机物降解机制[J]. 中国环境科学, 2023, 43(12): 6329-6340. RAN Yu-fang, XU Chun, LI Xin-peng, GONG Yao, FENG Wei-bo, HU Jia-shuo, ZHAO Cheng-wang. Process optimization and degradation mechanism of organic matter in Fenton oxidation treatment of coking wastewater. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(12): 6329-6340.

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http://www.zghjkx.com.cn/CN/ 或 http://www.zghjkx.com.cn/CN/Y2023/V43/I12/6329

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