硫酸盐还原菌作用下铁矾渣的还原溶解和相转化

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Abstract The reduction and phase transformation of jarosite residues were investigated by measuring the solute parameters, phase transformation and microbial community evolution during the reduction process with the mixed microbial community dominated by SRB, obtained by domestication. The results showed that under the action of SRB, the content of SO₄^2- in the residues continuously decreased, the solution pH slightly increased, the oxidation-reduction potential (ORP) continuously lowered, the Fe²⁺ magnified significantly, while Pb²⁺ and Zn²⁺ were only slightly dissolved. The sulfate minerals such as jarosite and gypsum in the residues were gradually reduced by the SRB community, thus resulting in their disappearance, and the characteristic peaks of secondary minerals such as markinite(FeS) and vivianite (Fe₃(PO₄)₂(H₂O)₈) appeared. The relative abundance of SRB increased, and gradually SRB became the dominant strains in the culture system, But the genus in which SRB was predominantly present had evolved from citrobacter to desulfofarcimen. These results demonstrate the feasibility of SRB to be used to reduce jarosite residues and further convert metals into sulfide, provide a theoretical basis for the recovery of valuable metals in the residues by the biological-sulfide flotation.

Key words： Jarosite residues sulfate-reducing bacteria reductive dissolution secondary minerals sulfide

Received: 09 November 2022

PACS:	X131
	X172

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	ZHOU Yi-chen
	YANG Hui-fen
	SONG Ying-liang
	SUN Qi-wei
	GAO Pu
	SONG Zhen-Guo
	YANG Hang

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ZHOU Yi-chen,YANG Hui-fen,SONG Ying-liang等. Reductive dissolution and phase transformation of jarosite residues by SRB[J]. CHINA ENVIRONMENTAL SCIENCECE, 2023, 43(S1): 170-178.

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http://www.zghjkx.com.cn/EN/ OR http://www.zghjkx.com.cn/EN/Y2023/V43/IS1/170

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